Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods
Abstract
Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula 1/2{L.sub.2N(.mu.-X).sub.2M'X.sub.2}.sub.2, and reacting MER with the intermediate products to form SSPs of the formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M' is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE.sup.1R.sup.1E.sup.1H and MER with one or more substances having the empirical formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2 or L.sub.2N(.mu.-X).sub.2M'(X).sub.2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.
- Inventors:
- Issue Date:
- Research Org.:
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1248014
- Patent Number(s):
- 9315529
- Application Number:
- 14/474,602
- Assignee:
- Battelle Energy Alliance, LLC (Idaho Falls, ID)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- DOE Contract Number:
- AC07-05ID14517
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Sep 02
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Fox, Robert V., Rodriguez, Rene G., Pak, Joshua J., Sun, Chivin, Margulieux, Kelsey R., and Holland, Andrew W. Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods. United States: N. p., 2016.
Web.
Fox, Robert V., Rodriguez, Rene G., Pak, Joshua J., Sun, Chivin, Margulieux, Kelsey R., & Holland, Andrew W. Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods. United States.
Fox, Robert V., Rodriguez, Rene G., Pak, Joshua J., Sun, Chivin, Margulieux, Kelsey R., and Holland, Andrew W. Tue .
"Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods". United States. https://www.osti.gov/servlets/purl/1248014.
@article{osti_1248014,
title = {Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods},
author = {Fox, Robert V. and Rodriguez, Rene G. and Pak, Joshua J. and Sun, Chivin and Margulieux, Kelsey R. and Holland, Andrew W.},
abstractNote = {Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula 1/2{L.sub.2N(.mu.-X).sub.2M'X.sub.2}.sub.2, and reacting MER with the intermediate products to form SSPs of the formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M' is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE.sup.1R.sup.1E.sup.1H and MER with one or more substances having the empirical formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2 or L.sub.2N(.mu.-X).sub.2M'(X).sub.2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2016},
month = {4}
}
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