Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

Goldman, Alan; Ahuja, Ritu; Schinski, William

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Title: Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

Abstract

The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.

Inventors:: Goldman, Alan; Ahuja, Ritu; Schinski, William

Issue Date:: Tue Apr 05 00:00:00 EDT 2016

Research Org.:: Rutgers, The State Univ. of New Jersey, New Brunswick, NJ (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1245597

Patent Number(s):: 9302954

Application Number:: 13/657,723

Assignee:: Rutgers, The State University of New Jersey (New Brunswick, NJ)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/02 - Alkenes
C07C15/02 - Monocyclic hydrocarbons
C07C2531/24 - Phosphines
C07C5/31 - changing the number of rings
C07C5/52 - with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/582 - of unreacted starting or intermediate materials

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DOE Contract Number:: FG02-93ER14353

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Oct 22

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Goldman, Alan, Ahuja, Ritu, and Schinski, William. Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes.  United States: N. p., 2016. 
        Web.

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                    Goldman, Alan, Ahuja, Ritu, & Schinski, William. Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes.  United States.

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                    Goldman, Alan, Ahuja, Ritu, and Schinski, William. Tue .  
        "Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes".  United States.  https://www.osti.gov/servlets/purl/1245597.

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@article{osti_1245597,

  title        = {Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes},

  author       = {Goldman, Alan and Ahuja, Ritu and Schinski, William},

  abstractNote = {The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Apr 05 00:00:00 EDT 2016},

  month        = {Tue Apr 05 00:00:00 EDT 2016}

}

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Works referenced in this record:

Catalytic asymmetric Diels Alder reactions
journal, July 1992

Kagan, Henri B.; Riant, Olivier
Chemical Reviews, Vol. 92, Issue 5
https://doi.org/10.1021/cr00013a013

Comparative studies of dehydrocyclization of n-octane and iso-octane on bifunctional and monofunctional Pt/Al₂O₃ catalysts
journal, February 1993

Ako, Churchill T.; Susu, Alfred A.
Chemical Engineering & Technology, Vol. 16, Issue 1, p. 10-16
https://doi.org/10.1002/ceat.270160103

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed
Science, Vol. 300, Issue 5622, p. 1127-1129
https://doi.org/10.1126/science.1083440

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes
journal, December 2010

Ahuja, Ritu; Punji, Benudhar; Findlater, Michael
Nature Chemistry, Vol. 3, Issue 2
https://doi.org/10.1038/nchem.946

Thermodynamic Properties for Solution of Hydrogen in Palladium-Based Binary Alloys
journal, June 1995

Sakamoto, Y.; Chen, F. L.; Ura, M.
Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 99, Issue 6, p. 807-820
https://doi.org/10.1002/bbpc.19950990605

Highly Effective Pincer-Ligated Iridium Catalysts for Alkane Dehydrogenation. DFT Calculations of Relevant Thermodynamic, Kinetic, and Spectroscopic Properties
journal, October 2004

Zhu, Keming; Achord, Patrick D.; Zhang, Xiawei
Journal of the American Chemical Society, Vol. 126, Issue 40
https://doi.org/10.1021/ja047356l

Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium
journal, September 2001

Dittmeyer, Roland; Höllein, Volker; Daub, Kristian
Journal of Molecular Catalysis A: Chemical, Vol. 173, Issue 1-2, p. 135-184
https://doi.org/10.1016/S1381-1169(01)00149-2

Water-Tolerant Solid Acid Catalysts
journal, October 2002

Okuhara, Toshio
Chemical Reviews, Vol. 102, Issue 10
https://doi.org/10.1021/cr0103569

Periphery-functionalized organometallic dendrimers for homogeneous catalysis
journal, October 1999

van Koten, Gerard; Jastrzebski, Johann T. B. H.
Journal of Molecular Catalysis A: Chemical, Vol. 146, Issue 1-2, p. 317-323
https://doi.org/10.1016/S1381-1169(99)00091-6

Ligand exchanges and selective catalytic hydrogenation in molecular single crystals
journal, June 2010

Huang, Zheng; White, Peter S.; Brookhart, Maurice
Nature, Vol. 465, Issue 7298
https://doi.org/10.1038/nature09085

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Similar Records

Title: Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

Abstract

Citation Formats

Catalytic asymmetric Diels Alder reactions journal, July 1992

Comparative studies of dehydrocyclization of n-octane and iso-octane on bifunctional and monofunctional Pt/Al2O3 catalysts journal, February 1993

Hydrogen Storage in Microporous Metal-Organic Frameworks journal, May 2003

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes journal, December 2010

Thermodynamic Properties for Solution of Hydrogen in Palladium-Based Binary Alloys journal, June 1995

Highly Effective Pincer-Ligated Iridium Catalysts for Alkane Dehydrogenation. DFT Calculations of Relevant Thermodynamic, Kinetic, and Spectroscopic Properties journal, October 2004

Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium journal, September 2001

Water-Tolerant Solid Acid Catalysts journal, October 2002

Periphery-functionalized organometallic dendrimers for homogeneous catalysis journal, October 1999

Ligand exchanges and selective catalytic hydrogenation in molecular single crystals journal, June 2010

Catalytic asymmetric Diels Alder reactions
journal, July 1992

Comparative studies of dehydrocyclization of n-octane and iso-octane on bifunctional and monofunctional Pt/Al₂O₃ catalysts
journal, February 1993

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes
journal, December 2010

Thermodynamic Properties for Solution of Hydrogen in Palladium-Based Binary Alloys
journal, June 1995

Highly Effective Pincer-Ligated Iridium Catalysts for Alkane Dehydrogenation. DFT Calculations of Relevant Thermodynamic, Kinetic, and Spectroscopic Properties
journal, October 2004

Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium
journal, September 2001

Water-Tolerant Solid Acid Catalysts
journal, October 2002

Periphery-functionalized organometallic dendrimers for homogeneous catalysis
journal, October 1999

Ligand exchanges and selective catalytic hydrogenation in molecular single crystals
journal, June 2010