Metal-organic framework materials with ultrahigh surface areas
Abstract
A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.
- Inventors:
- Issue Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1233374
- Patent Number(s):
- 9216939
- Application Number:
- 13/920,828
- Assignee:
- Northwestern University (Evanston, IL)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- FG02-08ER15967
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Jun 18
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., and Borah, Bhaskarjyoti. Metal-organic framework materials with ultrahigh surface areas. United States: N. p., 2015.
Web.
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., & Borah, Bhaskarjyoti. Metal-organic framework materials with ultrahigh surface areas. United States.
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., and Borah, Bhaskarjyoti. Tue .
"Metal-organic framework materials with ultrahigh surface areas". United States. https://www.osti.gov/servlets/purl/1233374.
@article{osti_1233374,
title = {Metal-organic framework materials with ultrahigh surface areas},
author = {Farha, Omar K. and Hupp, Joseph T. and Wilmer, Christopher E. and Eryazici, Ibrahim and Snurr, Randall Q. and Gomez-Gualdron, Diego A. and Borah, Bhaskarjyoti},
abstractNote = {A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {12}
}
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