Global to push GA events into
skip to main content

Title: Metal-organic framework materials with ultrahigh surface areas

A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.
Inventors:
; ; ; ; ; ;
Issue Date:
OSTI Identifier:
1233374
Assignee:
NORTHWESTERN UNIVERSITY CHO
Patent Number(s):
9,216,939
Application Number:
13/920,828
Contract Number:
FG02-08ER15967
Resource Relation:
Patent File Date: 2013 Jun 18
Research Org:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Other works cited in this record:

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010
  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009
  • Britt, D.; Furukawa, H.; Wang, B.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 49, p. 20637-20640
  • DOI: 10.1073/pnas.0909718106

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
  • Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
  • Nature, Vol. 427, Issue 6974, p. 523-527
  • DOI: 10.1038/nature02311

Virial-type thermal equation of gas—solid adsorption
journal, January 1989

Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012
  • Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
  • Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
  • DOI: 10.1021/ja3055639

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010
  • Farha, Omar K.; Hupp, Joseph T.
  • Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
  • DOI: 10.1021/ar1000617

Hybrid porous solids past, present, future
journal, January 2008
  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005
  • Ferey, G.; Mellot-Draznieks, C.; Serre, C.
  • Science, Vol. 309, Issue 5743, p. 2040-2042
  • DOI: 10.1126/science.1116275

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks
journal, September 2011
  • Getman, Rachel B.; Bae, Youn-Sang; Wilmer, Christopher E.
  • Chemical Reviews, Vol. 112, Issue 2, p. 703-723
  • DOI: 10.1021/cr200217c

Metal–Organic Frameworks as Efficient Materials for Drug Delivery
journal, September 2006
  • Horcajada, Patricia; Serre, Christian; Vallet-Regí, María
  • Angewandte Chemie International Edition, Vol. 45, Issue 36, p. 5974-5978
  • DOI: 10.1002/anie.200601878

Metal–Organic Frameworks in Biomedicine
journal, September 2011
  • Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek
  • Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268
  • DOI: 10.1021/cr200256v

Hydrogen Storage in Metal-Organic Frameworks
journal, May 2010

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007
  • Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
  • DOI: 10.1021/ja076877g

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008
  • Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
  • Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680
  • DOI: 10.1002/anie.200705020

Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
  • Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
  • DOI: 10.1021/cr200324t

Metal–organic framework materials as catalysts
journal, January 2009
  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Light-Harvesting Metal–Organic Frameworks (MOFs) Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs
journal, October 2011
  • Lee, Chang Yeon; Farha, Omar K.; Hong, Bong Jin
  • Journal of the American Chemical Society, Vol. 133, Issue 40, p. 15858-15861
  • DOI: 10.1021/ja206029a

Docking in Metal-Organic Frameworks
journal, August 2009
  • Li, Qiaowei; Zhang, Wenyu; Miljanic, Ognjen S.
  • Science, Vol. 325, Issue 5942, p. 855-859
  • DOI: 10.1126/science.1175441

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009
  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009
  • Ma, Liqing; Abney, Carter; Lin, Wenbin
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
  • DOI: 10.1039/b807083k

Hydrogen storage in metal–organic frameworks
journal, January 2009
  • Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
  • DOI: 10.1039/b802256a

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009
  • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
  • DOI: 10.1021/ja808853q

The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008
  • O’Keeffe, Michael; Peskov, Maxim A.; Ramsden, Stuart J.
  • Accounts of Chemical Research, Vol. 41, Issue 12, p. 1782-1789
  • DOI: 10.1021/ar800124u

Vapor–liquid equilibria of mixtures containing alkanes, carbon dioxide, and nitrogen
journal, July 2001
  • Potoff, Jeffrey J.; Siepmann, J. Ilja
  • AIChE Journal, Vol. 47, Issue 7, p. 1676-1682
  • DOI: 10.1002/aic.690470719

UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations
journal, December 1992
  • Rappe, A. K.; Casewit, C. J.; Colwell, K. S.
  • Journal of the American Chemical Society, Vol. 114, Issue 25, p. 10024-10035
  • DOI: 10.1021/ja00051a040

Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery
journal, October 2011
  • Della Rocca, Joseph; Liu, Demin; Lin, Wenbin
  • Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968
  • DOI: 10.1021/ar200028a

Prospects for nanoporous metal-organic materials in advanced separations processes
journal, January 2004
  • Snurr, Randall Q.; Hupp, Joseph T.; Nguyen, SonBinh T.
  • AIChE Journal, Vol. 50, Issue 6, p. 1090-1095
  • DOI: 10.1002/aic.10101

Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
  • Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
  • Chemical Reviews, Vol. 112, Issue 2, p. 782-835
  • DOI: 10.1021/cr200274s

Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011
  • Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
  • Nature Chemistry, Vol. 4, Issue 2, p. 83-89
  • DOI: 10.1038/nchem.1192

Towards rapid computational screening of metal-organic frameworks for carbon dioxide capture: Calculation of framework charges via charge equilibration
journal, July 2011
  • Wilmer, Christopher E.; Snurr, Randall Q.
  • Chemical Engineering Journal, Vol. 171, Issue 3, p. 775-781
  • DOI: 10.1016/j.cej.2010.10.035

An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
journal, June 2010
  • Yuan, Daqiang; Zhao, Dan; Sun, Daofeng
  • Angewandte Chemie International Edition, Vol. 49, Issue 31, p. 5357-5361
  • DOI: 10.1002/anie.201001009

Similar records in DOepatents and OSTI.GOV collections: