skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Metal-organic framework materials with ultrahigh surface areas

Abstract

A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1233374
Patent Number(s):
9,216,939
Application Number:
13/920,828
Assignee:
NORTHWESTERN UNIVERSITY
DOE Contract Number:  
FG02-08ER15967
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Jun 18
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., and Borah, Bhaskarjyoti. Metal-organic framework materials with ultrahigh surface areas. United States: N. p., 2015. Web.
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., & Borah, Bhaskarjyoti. Metal-organic framework materials with ultrahigh surface areas. United States.
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., and Borah, Bhaskarjyoti. Tue . "Metal-organic framework materials with ultrahigh surface areas". United States. https://www.osti.gov/servlets/purl/1233374.
@article{osti_1233374,
title = {Metal-organic framework materials with ultrahigh surface areas},
author = {Farha, Omar K. and Hupp, Joseph T. and Wilmer, Christopher E. and Eryazici, Ibrahim and Snurr, Randall Q. and Gomez-Gualdron, Diego A. and Borah, Bhaskarjyoti},
abstractNote = {A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {12}
}

Patent:

Save / Share:

Works referenced in this record:

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010

  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Luminescent metal–organic frameworks
journal, January 2009

  • Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.
  • Chemical Society Reviews, Vol. 38, Issue 5
  • DOI: 10.1039/b802352m

Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework
journal, January 2012

  • An, Jihyun; Farha, Omar K.; Hupp, Joseph T.
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1618

High and Selective CO 2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores
journal, January 2010

  • An, Jihyun; Geib, Steven J.; Rosi, Nathaniel L.
  • Journal of the American Chemical Society, Vol. 132, Issue 1
  • DOI: 10.1021/ja909169x

Evaluation of the BET Method for Determining Surface Areas of MOFs and Zeolites that Contain Ultra-Micropores
journal, April 2010

  • Bae, Youn-Sang; Yazaydın, A. Özgür; Snurr, Randall Q.
  • Langmuir, Vol. 26, Issue 8
  • DOI: 10.1021/la100449z

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009

  • Britt, D.; Furukawa, H.; Wang, B.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 49, p. 20637-20640
  • DOI: 10.1073/pnas.0909718106

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004

  • Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
  • Nature, Vol. 427, Issue 6974, p. 523-527
  • DOI: 10.1038/nature02311

Solvent-accessible surfaces of proteins and nucleic acids
journal, August 1983


Virial-type thermal equation of gas—solid adsorption
journal, January 1989


Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes
journal, January 2011

  • Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus
  • Chemistry - A European Journal, Vol. 17, Issue 6
  • DOI: 10.1002/chem.201001872

Synthesis of Unsymmetrical 1,1′-Disubstituted Bis(1,2,3-triazole)s Using Monosilylbutadiynes
journal, February 2011

  • Doak, Bradley C.; Scanlon, Martin J.; Simpson, Jamie S.
  • Organic Letters, Vol. 13, Issue 3
  • DOI: 10.1021/ol102852z

Calculating Geometric Surface Areas as a Characterization Tool for Metal−Organic Frameworks
journal, October 2007

  • Düren, Tina; Millange, Franck; Férey, Gérard
  • The Journal of Physical Chemistry C, Vol. 111, Issue 42
  • DOI: 10.1021/jp074723h

Luminescent infinite coordination polymer materials from metal-terpyridine ligation
journal, January 2011

  • Eryazici, Ibrahim; Farha, Omar K.; Compton, Owen C.
  • Dalton Transactions, Vol. 40, Issue 36
  • DOI: 10.1039/c1dt10671f

Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?
journal, June 2012

  • Farha, Omar K.; Wilmer, Christopher E.; Eryazici, Ibrahim
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja302623w

Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
journal, August 2012

  • Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon
  • Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021
  • DOI: 10.1021/ja3055639

Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
journal, August 2010

  • Farha, Omar K.; Hupp, Joseph T.
  • Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175
  • DOI: 10.1021/ar1000617

Hybrid porous solids past, present, future
journal, January 2008

  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005

  • Ferey, G.; Mellot-Draznieks, C.; Serre, C.
  • Science, Vol. 309, Issue 5743, p. 2040-2042
  • DOI: 10.1126/science.1116275

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010


Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks
journal, September 2011

  • Getman, Rachel B.; Bae, Youn-Sang; Wilmer, Christopher E.
  • Chemical Reviews, Vol. 112, Issue 2, p. 703-723
  • DOI: 10.1021/cr200217c

A non-interpenetrated porous metal–organic framework with high gas-uptake capacity
journal, January 2011

  • Han, Dong; Jiang, Fei-Long; Wu, Ming-Yan
  • Chemical Communications, Vol. 47, Issue 35
  • DOI: 10.1039/c1cc12858b

Metal–Organic Frameworks as Efficient Materials for Drug Delivery
journal, September 2006

  • Horcajada, Patricia; Serre, Christian; Vallet-Regí, María
  • Angewandte Chemie International Edition, Vol. 45, Issue 36, p. 5974-5978
  • DOI: 10.1002/anie.200601878

Metal–Organic Frameworks in Biomedicine
journal, September 2011

  • Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek
  • Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268
  • DOI: 10.1021/cr200256v

Hydrogen Storage in Metal-Organic Frameworks
journal, May 2010


Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007

  • Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
  • DOI: 10.1021/ja076877g

Energy Transfer Dynamics in Metal−Organic Frameworks
journal, September 2010

  • Kent, Caleb A.; Mehl, Brian P.; Ma, Liqing
  • Journal of the American Chemical Society, Vol. 132, Issue 37
  • DOI: 10.1021/ja102804s

Route to a Family of Robust, Non-interpenetrated Metal-Organic Frameworks with pto-like Topology
journal, September 2011

  • Klein, Nicole; Senkovska, Irena; Baburin, Igor A.
  • Chemistry - A European Journal, Vol. 17, Issue 46
  • DOI: 10.1002/chem.201101383

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

  • Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
  • Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680
  • DOI: 10.1002/anie.200705020

A Porous Coordination Copolymer with over 5000 m 2 /g BET Surface Area
journal, April 2009

  • Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 131, Issue 12
  • DOI: 10.1021/ja809985t

Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011

  • Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
  • Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
  • DOI: 10.1021/cr200324t

Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Light-Harvesting Metal–Organic Frameworks (MOFs) Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs
journal, October 2011

  • Lee, Chang Yeon; Farha, Omar K.; Hong, Bong Jin
  • Journal of the American Chemical Society, Vol. 133, Issue 40, p. 15858-15861
  • DOI: 10.1021/ja206029a

Monte Carlo simulations of hydrogen storage in carbon nanotubes
journal, September 2002

  • Levesque, D.; Gicquel, A.; Darkrim, F. Lamari
  • Journal of Physics: Condensed Matter, Vol. 14, Issue 40
  • DOI: 10.1088/0953-8984/14/40/318

Docking in Metal-Organic Frameworks
journal, August 2009

  • Li, Qiaowei; Zhang, Wenyu; Miljanic, Ognjen S.
  • Science, Vol. 325, Issue 5942, p. 855-859
  • DOI: 10.1126/science.1175441

Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998

  • Li, Hailian; Eddaoudi, Mohamed; Groy, Thomas L.
  • Journal of the American Chemical Society, Vol. 120, Issue 33, p. 8571-8572
  • DOI: 10.1021/ja981669x

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites
journal, February 2009

  • Lin, Xiang; Telepeni, Irvin; Blake, Alexander J.
  • Journal of the American Chemical Society, Vol. 131, Issue 6
  • DOI: 10.1021/ja806624j

Experimental and Theoretical Studies of Gas Adsorption in Cu 3 (BTC) 2 :  An Effective Activation Procedure
journal, July 2007

  • Liu, Jinchen; Culp, Jeffrey T.; Natesakhawat, Sittichai
  • The Journal of Physical Chemistry C, Vol. 111, Issue 26
  • DOI: 10.1021/jp071449i

Progress in adsorption-based CO 2 capture by metal–organic frameworks
journal, January 2012

  • Liu, Jian; Thallapally, Praveen K.; McGrail, B. Peter
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15221A

Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009

  • Ma, Liqing; Abney, Carter; Lin, Wenbin
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
  • DOI: 10.1039/b807083k

Hydrogen storage in metal–organic frameworks
journal, January 2009

  • Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
  • DOI: 10.1039/b802256a

Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials
journal, January 2009

  • Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L.
  • Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460
  • DOI: 10.1021/ja808853q

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks
journal, February 2008

  • Nouar, Farid; Eubank, Jarrod F.; Bousquet, Till
  • Journal of the American Chemical Society, Vol. 130, Issue 6
  • DOI: 10.1021/ja710123s

The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008

  • O’Keeffe, Michael; Peskov, Maxim A.; Ramsden, Stuart J.
  • Accounts of Chemical Research, Vol. 41, Issue 12, p. 1782-1789
  • DOI: 10.1021/ar800124u

A Highly Porous Metal–Organic Framework: Structural Transformations of a Guest‐Free MOF Depending on Activation Method and Temperature
journal, May 2011

  • Park, Hye Jeong; Lim, Dae‐Woon; Yang, Woo Seung
  • Chemistry – A European Journal, Vol. 17, Issue 26
  • DOI: 10.1002/chem.201003376

Vapor–liquid equilibria of mixtures containing alkanes, carbon dioxide, and nitrogen
journal, July 2001

  • Potoff, Jeffrey J.; Siepmann, J. Ilja
  • AIChE Journal, Vol. 47, Issue 7, p. 1676-1682
  • DOI: 10.1002/aic.690470719

UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations
journal, December 1992

  • Rappe, A. K.; Casewit, C. J.; Colwell, K. S.
  • Journal of the American Chemical Society, Vol. 114, Issue 25, p. 10024-10035
  • DOI: 10.1021/ja00051a040

Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery
journal, October 2011

  • Della Rocca, Joseph; Liu, Demin; Lin, Wenbin
  • Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968
  • DOI: 10.1021/ar200028a

A Framework for Predicting Surface Areas in Microporous Coordination Polymers
journal, April 2010

  • Schnobrich, Jennifer K.; Koh, Kyoungmoo; Sura, Kush N.
  • Langmuir, Vol. 26, Issue 8
  • DOI: 10.1021/la9037292

The current status of hydrogen storage in metal–organic frameworks—updated
journal, January 2011

  • Sculley, Julian; Yuan, Daqiang; Zhou, Hong-Cai
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01240a

Prospects for nanoporous metal-organic materials in advanced separations processes
journal, January 2004

  • Snurr, Randall Q.; Hupp, Joseph T.; Nguyen, SonBinh T.
  • AIChE Journal, Vol. 50, Issue 6, p. 1090-1095
  • DOI: 10.1002/aic.10101

Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011

  • Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
  • Chemical Reviews, Vol. 112, Issue 2, p. 782-835
  • DOI: 10.1021/cr200274s

Synthesis and Hydrogen Storage Properties of Be 12 (OH) 12 (1,3,5-benzenetribenzoate) 4
journal, October 2009

  • Sumida, Kenji; Hill, Matthew R.; Horike, Satoshi
  • Journal of the American Chemical Society, Vol. 131, Issue 42
  • DOI: 10.1021/ja9072707

Tuning Hydrogen Sorption Properties of Metal–Organic Frameworks by Postsynthetic Covalent Modification
journal, January 2010

  • Wang, Zhenqiang; Tanabe, Kristine K.; Cohen, Seth M.
  • Chemistry - A European Journal, Vol. 16, Issue 1
  • DOI: 10.1002/chem.200902158

Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011

  • Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
  • Nature Chemistry, Vol. 4, Issue 2, p. 83-89
  • DOI: 10.1038/nchem.1192

Towards rapid computational screening of metal-organic frameworks for carbon dioxide capture: Calculation of framework charges via charge equilibration
journal, July 2011

  • Wilmer, Christopher E.; Snurr, Randall Q.
  • Chemical Engineering Journal, Vol. 171, Issue 3, p. 775-781
  • DOI: 10.1016/j.cej.2010.10.035

Exceptionally high H2 storage by a metal–organic polyhedral framework
journal, January 2009

  • Yan, Yong; Lin, Xiang; Yang, Sihai
  • Chemical Communications, Issue 9
  • DOI: 10.1039/b900013e

Metal−Organic Polyhedral Frameworks: High H 2 Adsorption Capacities and Neutron Powder Diffraction Studies
journal, March 2010

  • Yan, Yong; Telepeni, Irvin; Yang, Sihai
  • Journal of the American Chemical Society, Vol. 132, Issue 12
  • DOI: 10.1021/ja1001407

A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra
journal, January 2011

  • Yan, Yong; Yang, Sihai; Blake, Alexander J.
  • Chemical Communications, Vol. 47, Issue 36
  • DOI: 10.1039/c1cc13170b

An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
journal, June 2010

  • Yuan, Daqiang; Zhao, Dan; Sun, Daofeng
  • Angewandte Chemie International Edition, Vol. 49, Issue 31, p. 5357-5361
  • DOI: 10.1002/anie.201001009

Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework
journal, November 2011

  • Yuan, Daqiang; Zhao, Dan; Zhou, Hong-Cai
  • Inorganic Chemistry, Vol. 50, Issue 21
  • DOI: 10.1021/ic201744n

Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows
journal, July 2009

  • Zhao, Dan; Yuan, Daqiang; Sun, Daofeng
  • Journal of the American Chemical Society, Vol. 131, Issue 26
  • DOI: 10.1021/ja901109t

Enhanced CO 2 Binding Affinity of a High-Uptake rht -Type Metal−Organic Framework Decorated with Acylamide Groups
journal, February 2011

  • Zheng, Baishu; Bai, Junfeng; Duan, Jingui
  • Journal of the American Chemical Society, Vol. 133, Issue 4
  • DOI: 10.1021/ja110042b