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Title: Metal-organic framework materials with ultrahigh surface areas

Abstract

A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1233374
Patent Number(s):
9216939
Application Number:
13/920,828
Assignee:
Northwestern University (Evanston, IL)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
F - MECHANICAL ENGINEERING F17 - STORING OR DISTRIBUTING GASES OR LIQUIDS F17C - VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES
DOE Contract Number:  
FG02-08ER15967
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Jun 18
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., and Borah, Bhaskarjyoti. Metal-organic framework materials with ultrahigh surface areas. United States: N. p., 2015. Web.
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., & Borah, Bhaskarjyoti. Metal-organic framework materials with ultrahigh surface areas. United States.
Farha, Omar K., Hupp, Joseph T., Wilmer, Christopher E., Eryazici, Ibrahim, Snurr, Randall Q., Gomez-Gualdron, Diego A., and Borah, Bhaskarjyoti. Tue . "Metal-organic framework materials with ultrahigh surface areas". United States. https://www.osti.gov/servlets/purl/1233374.
@article{osti_1233374,
title = {Metal-organic framework materials with ultrahigh surface areas},
author = {Farha, Omar K. and Hupp, Joseph T. and Wilmer, Christopher E. and Eryazici, Ibrahim and Snurr, Randall Q. and Gomez-Gualdron, Diego A. and Borah, Bhaskarjyoti},
abstractNote = {A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {12}
}

Patent:

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