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Title: Compositions comprising free-standing two-dimensional nanocrystals


The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.

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Issue Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
OSTI Identifier:
Patent Number(s):
Application Number:
Drexel University (Philadelphia, PA)
DOE Contract Number:  
Resource Type:
Resource Relation:
Patent File Date: 2013 Dec 03
Country of Publication:
United States

Citation Formats

Barsoum, Michel W., Gogotsi, Yury, Abdelmalak, Michael Naguib, and Mashtalir, Olha. Compositions comprising free-standing two-dimensional nanocrystals. United States: N. p., 2015. Web.
Barsoum, Michel W., Gogotsi, Yury, Abdelmalak, Michael Naguib, & Mashtalir, Olha. Compositions comprising free-standing two-dimensional nanocrystals. United States.
Barsoum, Michel W., Gogotsi, Yury, Abdelmalak, Michael Naguib, and Mashtalir, Olha. Tue . "Compositions comprising free-standing two-dimensional nanocrystals". United States.
title = {Compositions comprising free-standing two-dimensional nanocrystals},
author = {Barsoum, Michel W. and Gogotsi, Yury and Abdelmalak, Michael Naguib and Mashtalir, Olha},
abstractNote = {The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {11}


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Works referenced in this record:

High-Quality Thin Graphene Films from Fast Electrochemical Exfoliation
journal, February 2011

  • Su, Ching-Yuan; Lu, Ang-Yu; Xu, Yanping
  • ACS Nano, Vol. 5, Issue 3
  • DOI: 10.1021/nn200025p

The MAX Phases: Unique New Carbide and Nitride Materials
journal, January 2001

  • Barsoum, Michel; El-Raghy, Tamer
  • American Scientist, Vol. 89, Issue 4
  • DOI: 10.1511/2001.4.334

Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
journal, February 2011

Accumulation of miR-155 and BIC RNA in human B cell lymphomas
journal, February 2005

  • Eis, P. S.; Tam, W.; Sun, L.
  • Proceedings of the National Academy of Sciences, Vol. 102, Issue 10, p. 3627-3632
  • DOI: 10.1073/pnas.0500613102

The Mn+1AXn phases: Materials science and thin-film processing
journal, February 2010

  • Eklund, Per; Beckers, Manfred; Jansson, Ulf
  • Thin Solid Films, Vol. 518, Issue 8, p. 1851-1878
  • DOI: 10.1016/j.tsf.2009.07.184

Thermal expansion and stability of Ti2SC in air and inert atmospheres
journal, February 2009

  • Kulkarni, Shrinivas R.; Merlini, Marco; Phatak, Nishad
  • Journal of Alloys and Compounds, Vol. 469, Issue 1-2, p. 395-400
  • DOI: 10.1016/j.jallcom.2008.01.150

The structure of multilayered titania nanotubes based on delaminated anatase
journal, July 2008

  • Mogilevsky, Gregory; Chen, Qiang; Kleinhammes, Alfred
  • Chemical Physics Letters, Vol. 460, Issue 4-6, p. 517-520
  • DOI: 10.1016/j.cplett.2008.06.063

Clay particle engineering: A potential new technology with diverse applications
journal, March 1987

MXene: a promising transition metal carbide anode for lithium-ion batteries
journal, March 2012

  • Naguib, Michael; Come, Jérémy; Dyatkin, Boris
  • Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64
  • DOI: 10.1016/j.elecom.2012.01.002

New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries
journal, October 2013

  • Naguib, Michael; Halim, Joseph; Lu, Jun
  • Journal of the American Chemical Society, Vol. 135, Issue 43
  • DOI: 10.1021/ja405735d

Synthesis of a new nanocrystalline titanium aluminum fluoride phase by reaction of Ti2AlC with hydrofluoric acid
journal, January 2011

  • Naguib, Michael; Presser, Volker; Lane, Nina
  • RSC Advances, Vol. 1, Issue 8
  • DOI: 10.1039/C1RA00390A

Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011

  • Naguib, Michael; Kurtoglu, Murat; Presser, Volker
  • Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
  • DOI: 10.1002/adma.201102306

Two-Dimensional Transition Metal Carbides
journal, January 2012

  • Naguib, Michael; Mashtalir, Olha; Carle, Joshua
  • ACS Nano, Vol. 6, Issue 2
  • DOI: 10.1021/nn204153h

A study of the synthetic methods and properties of graphenes
journal, October 2010

  • Rao, C. N. R.; Subrahmanyam, K. S.; Ramakrishna Matte, H. S. S.
  • Science and Technology of Advanced Materials, Vol. 11, Issue 5
  • DOI: 10.1088/1468-6996/11/5/054502

Carbon nanoscrolls produced from acceptor-type graphite intercalation compounds
journal, November 2007

  • Savoskin, Michael V.; Mochalin, Vadym N.; Yaroshenko, Alexander P.
  • Carbon, Vol. 45, Issue 14, p. 2797-2800
  • DOI: 10.1016/j.carbon.2007.09.031

Vibrational behavior of the M n + 1 A X n phases from first-order Raman scattering ( M = Ti , V , Cr , A = Si , X = C , N )
journal, January 2005

Graphene-based composite materials
journal, July 2006

  • Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B.
  • Nature, Vol. 442, Issue 7100, p. 282-286
  • DOI: 10.1038/nature04969

Lithium Intercalation in Porous Carbon Electrodes
journal, January 1995

A Chemical Route to Carbon Nanoscrolls
journal, February 2003

The Topotactic Transformation of Ti3SiC2 into a Partially Ordered Cubic Ti  (  C 0.67Si0.06 )  Phase by the Diffusion of Si into Molten Cryolite
journal, January 1999

  • Barsoum, M. W.; El‐Raghy, T.; Farber, L.
  • Journal of The Electrochemical Society, Vol. 146, Issue 10, p. 3919-3923
  • DOI: 10.1149/1.1392573

Room-Temperature Deintercalation and Self-Extrusion of Ga from Cr2GaN
journal, May 1999

The MN+1AXN phases: A new class of solids: Thermodynamically stable nanolaminates
journal, January 2000

Microstructure and phase transformation of Ti3AC2 (A = Al, Si) in hydrofluoric acid solution
journal, August 2014

  • Chen, Beibei; Chang, Fangyuan; Yang, Jin
  • Crystal Research and Technology, Vol. 49, Issue 10, p. 813-819
  • DOI: 10.1002/crat.201400189

Low temperature thermal expansion, high temperature electrical conductivity, and mechanical properties of Nb4AlC3 ceramic synthesized by spark plasma sintering
journal, November 2009

  • Hu, Chunfeng; Sakka, Yoshio; Tanaka, Hidehiko
  • Journal of Alloys and Compounds, Vol. 487, Issue 1-2, p. 675-681
  • DOI: 10.1016/j.jallcom.2009.08.036

The corrosion behavior of Ti3SiC2 in common acids and dilute NaOH
journal, June 2003