High capacity anode materials for lithium ion batteries

Lopez, Herman A.; Anguchamy, Yogesh Kumar; Deng, Haixia; Han, Yongbon; Masarapu, Charan; Venkatachalam, Subramanian; Kumar, Suject

Title: High capacity anode materials for lithium ion batteries

Abstract

High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.

Inventors:: Lopez, Herman A.; Anguchamy, Yogesh Kumar; Deng, Haixia; Han, Yongbon; Masarapu, Charan; Venkatachalam, Subramanian; Kumar, Suject

Issue Date:: Thu Nov 19 00:00:00 EST 2015

Research Org.:: Envia Systems, Inc., Newark, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1226230

Patent Number(s):: 9190694

Application Number:: 12/938,951

Assignee:: Envia Systems, Inc. (Newark, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25F - PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25F - PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS
C25F3/12 - of semiconducting materials

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M2004/027 - {Negative electrodes}
H01M2004/028 - {Positive electrodes}
H01M2220/30 - Batteries in portable systems, e.g. mobile phone, laptop
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M4/134 - Electrodes based on metals, Si or alloys
H01M4/364 - {as mixtures}
H01M4/38 - of elements or alloys
H01M4/386 - {Silicon or alloys based on silicon}
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M4/587 - for inserting or intercalating light metals
H01M4/621 - {Binders}
H01M4/622 - {being polymers}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AR0000034

Resource Type:: Patent

Resource Relation:: Patent File Date: 2010 Nov 03

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Lopez, Herman A., Anguchamy, Yogesh Kumar, Deng, Haixia, Han, Yongbon, Masarapu, Charan, Venkatachalam, Subramanian, and Kumar, Suject. High capacity anode materials for lithium ion batteries.  United States: N. p., 2015. 
        Web.

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                    Lopez, Herman A., Anguchamy, Yogesh Kumar, Deng, Haixia, Han, Yongbon, Masarapu, Charan, Venkatachalam, Subramanian, & Kumar, Suject. High capacity anode materials for lithium ion batteries.  United States.

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                    Lopez, Herman A., Anguchamy, Yogesh Kumar, Deng, Haixia, Han, Yongbon, Masarapu, Charan, Venkatachalam, Subramanian, and Kumar, Suject. Thu .  
        "High capacity anode materials for lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1226230.

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@article{osti_1226230,

  title        = {High capacity anode materials for lithium ion batteries},

  author       = {Lopez, Herman A. and Anguchamy, Yogesh Kumar and Deng, Haixia and Han, Yongbon and Masarapu, Charan and Venkatachalam, Subramanian and Kumar, Suject},

  abstractNote = {High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Nov 19 00:00:00 EST 2015},

  month        = {Thu Nov 19 00:00:00 EST 2015}

}

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Works referenced in this record:

Anodes for rechargeable lithium batteries
patent, March 2003

Thackeray, Michael M.; Kepler, Keith D.; Vaughey, John T.
US Patent Document 6,528,208
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6528208

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell
patent, July 1995

Huang, Chen-Kuo; Surampudi, Subbarao; Attia, Alan I.
US Patent Document 5,436,093
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5436093

Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, February 2010

Aramata, Mikio; Miyawaki, Satoru; Fukuoka, Hirofumi
US Patent Document 7,658,863
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7658863

Non-Aqueous Electrolyte Secondary Battery
patent-application, December 2009

Shirane, Takayuki; Inoue, Kaoru; Ugaji, Masaya
US Patent Application 12/064307; 20090317721
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090317721

Composite anode for nonaqueous secondary battery and method for producing the same
patent, July 1996

Mizumoto, Mamoru; Honbo, Hidetoshi; Horiba, Tatsuo
US Patent Document 5,541,022
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5541022

A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment
journal, August 2008

Ito, Atsushi; Li, Decheng; Ohsawa, Yasuhiko
Journal of Power Sources, Vol. 183, Issue 1, p. 344-346
https://doi.org/10.1016/j.jpowsour.2008.04.086

Nonaqueous secondary battery containing silicic material
patent, May 2001

Idota, Yoshio; Matsufuji, Akihiro; Mori, Nobufumi
US Patent Document 6,235,427
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6235427

Metal Halide Coatings On Lithium Ion Battery Positive Electrode Materials And Corresponding Batteries
patent-application, March 2012

Venkatachalam, Subramanian; Karthikeyan, Deepak; Lopez, Herman
US Patent Application 12/888131; 20120070725
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120070725

Electrode material for rechargeable lithium battery, electrode structural body comprising said electrode material, rechargeable lithium battery having said electrode structural body, process for the production of said electrode structural body, and process for the production of said rechargeable lithium battery
patent-application, August 2003

Kosuzu, Takeshi; Kawakami, Soichiro; Asao, Masaya
US Patent Application 10/300305; 20030157407
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030157407

Lithium-ion battery
patent, July 2009

Howard, William G.; Schmidt, Craig L.; Scott, Erik R.
US Patent Document 7,563,541
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7563541

Anode and Secondary Battery
patent-application, August 2009

Wakita, Shinya; Okae, Izaya
US Patent Application 12/368650; 20090214952
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090214952

Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials
patent-application, April 2010

Venkatachalam, Subramanian; Lopez, Herman; Kumar, Sujeet
US Patent Application 12/246814; 20100086853
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100086853

Nanowire battery methods and arrangements
patent, October 2010

Cui, Yi; Chan, Candace
US Patent Document 7,816,031
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7816031

Electrode material for anode of rechargeable lithium battery, electrode structural body using said electrode material, rechargeable lithium battery using said electrode structural body, process for producing said electrode structural body, and process for producing said rechargeable lithium battery
patent-application, August 2005

Kawakami, Soichiro; Asao, Masaya
US Patent Application 11/104440; 20050175901
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050175901

Carbon-Coated Silicon Particle Powder as the Anode Material for Lithium Ion Batteries and Method of Making the Same
patent-application, May 2009

Mao, Zhenhua; Chahar, Bharat
US Patent Application 12/329670; 20090130562
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090130562

Electrode material for lithium secondary battery and electrode structure having the electrode material
patent-application, February 2006

Kawakami, Soichiro; Asao, Masaya; Suzuki, Nobuyuki
US Patent Application 10/541222; 20060040182
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060040182

Porous Silicon Particulates for Lithium Batteries
patent-application, July 2009

Tiegs, Terry N.
US Patent Application 12/321446; 20090186267
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090186267

Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries
journal, August 2005

Kang, S.-H.; Amine, K.
Journal of Power Sources, Vol. 146, Issue 1-2, p. 654-657
https://doi.org/10.1016/j.jpowsour.2005.03.152

Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni_0.17Li_0.2Co_0.07Mn_0.56]O₂
journal, January 2010

Ito, Atsushi; Li, Decheng; Sato, Yuichi
Journal of Power Sources, Vol. 195, Issue 2, p. 567-573
https://doi.org/10.1016/j.jpowsour.2009.07.052

Active Material for Non-Aqueous Electrolyte Secondary Battery and Manufacturing Method Therefore
patent-application, October 2008

Ohzuku, Tsutomu; Yoshizawa, Hiroshi; Nakura, Kensuke
US Patent Application 12/058430; 20080268347
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080268347

Lithium Ion Batteries with Supplemental Lithium
patent-application, May 2012

Amiruddin, Shabab; Venkatachalam, Subramanian; Li, Bing
US Patent Application 12/938073; 20120107680
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120107680

Electrochemical behaviors of silicon based anode material
journal, August 2005

Yoshio, Masaki; Tsumura, Takaaki; Dimov, Nikolay
Journal of Power Sources, Vol. 146, Issue 1-2, p. 10-14
https://doi.org/10.1016/j.jpowsour.2005.03.143

Negative electrode for nonaqueous secondary battery
patent-application, March 2006

Matsushima, Tomoyoshi; Honda, Hitohiko; Sakaguchi, Yoshiki
US Patent Application 11/174645; 20060051677
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060051677

Battery including an electrolyte solution comprising a halogenated carbonate derivative
patent, July 2010

Yamaguchi, Akira; Nakajima, Kaoru; Fujishige, Yusuke
US Patent Document 7,754,389
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7754389

Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, August 2010

Aramata, Mikio; Watanabe, Koichiro; Miyawaki, Satoru
US Patent Document 7,776,473
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7776473

Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries
journal, July 2005

Kim, G.-H.; Kim, J.-H.; Myung, S.-T.
Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1707-A1713
https://doi.org/10.1149/1.1952747

High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions
patent-application, December 2009

Kumar, Sujeet; Buckley, James P.
US Patent Application 12/429438; 20090305131
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090305131

SI/C Composite, Anode Active Materials, and Lithium Battery Including the Same
patent-application, January 2009

Mah, Sang-kook; Kim, Han-su
US Patent Application 12/118972; 20090029256
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090029256

Composite for Anode Material, Anode Materials and Lithium Battery Using the Same
patent-application, July 2009

Mah, Sang-kook; Kim, Han-su
US Patent Application 12/130145; 20090169994
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090169994

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent, September 2010

Aramata, Mikio; Miyawaki, Satoru; Fukuoka, Hirofumi
US Patent Document 7,790,316
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7790316

Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries
journal, September 2009

Cui, Li-Feng; Yang, Yuan; Hsu, Ching-Mei
Nano Letters, Vol. 9, Issue 9, p. 3370-3374
https://doi.org/10.1021/nl901670t

Anode for Lithium Ion Cell
patent-application, November 2008

Jarvis, Christine Ruth
US Patent Application 11/579270; 20080274408
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080274408

Coated Positive Electrode Materials For Lithium Ion Batteries
patent-application, May 2011

Lopez, Herman; Venkatachalam, Subramanian; Kandasamy Karthikeyan, Deepak
US Patent Application 12/616226; 20110111298
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110111298

Method of making activated carbon derived from pitches
patent, June 2001

Peng, Y. Lisa; Williams, Jimmie L.
US Patent Document 6,251,822
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6251822

Negative electrode for rechargeable lithium battery and method for fabrication thereof
patent, November 2007

Fukui, Atsushi; Torimae, Mariko; Kusumoto, Yasuyuki
US Patent Document 7,297,446
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7297446

Electric separator, method for producing the same and the use thereof
patent-application, February 2005

Hennige, Volker; Horpel, Gerhard; Hying, Christian
US Patent Application 10/487245; 20050031942
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050031942

High capacity Li[Li_0.2Ni_0.2Mn_0.6]O₂ cathode materials via a carbonate co-precipitation method
journal, November 2006

Lee, D.-K.; Park, S.-H.; Amine, K.
Journal of Power Sources, Vol. 162, Issue 2, p. 1346-1350
https://doi.org/10.1016/j.jpowsour.2006.07.064

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode
patent-application, October 2001

Tsutsumi, Masami; Horiuchi, Hiroshi; Yamamoto, Tamotsu
US Patent Application 09/840184; 20010031396
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20010031396

High Energy Lithium Ion Secondary Batteries
patent-application, October 2009

Buckley, James P.; Kumar, Sujeet
US Patent Application 12/403521; 20090263707
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090263707

Synthesis of spherical Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ as positive electrode material for lithium-ion battery
journal, February 2006

Kim, Gil-Ho; Myung, Seung-Taek; Kim, Hyun-Soo
Electrochimica Acta, Vol. 51, Issue 12, p. 2447-2453
https://doi.org/10.1016/j.electacta.2005.07.026

Non-aqueous electrolyte secondary battery and making method
patent-application, March 2008

Miyawaki, Satorn; Aramata, Mikio; Kashida, Meguru
US Patent Application 11/898412; 20080070120
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080070120

Negative active material, negative electrode using the same, non-aqueous electrolyte battery using the same, and method for preparing the same
patent-application, February 2004

Funabiki, Atsushi
US Patent Application 10/461187; 20040033419
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040033419

Battery including carbon foam current collectors
patent, December 2005

Kelley, Kurtis C.; Votoupal, John J.
US Patent Document 6,979,513
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6979513

Secondary lithium-ion cell with an auxiliary electrode
patent, January 2002

Meissner, Eberhard
US Patent Document 6,335,115
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6335115

Electrode material, and production method and use thereof
patent-application, February 2006

Nanba, Youichi; Iinou, Satoshi; Masuko, Tsutomu
US Patent Application 10/536443; 20060035149
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060035149

Secondary Battery
patent-application, December 2009

Lim, Wan Mook
US Patent Application 12/417068; 20090325061
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090325061

Method for intercalating alkali metal ions into carbon electrodes
patent, August 1995

Doeff, Marca M.; Ma, Yanping; Visco, Steven J.
US Patent Document 5,443,601
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5443601

Electrochemical characterization of a novel Si–graphite–Li_2.6Co_0.4N composite as anode material for lithium secondary batteries
journal, January 2005

Liu, Y.; Hanai, K.; Horikawa, K.
Materials Chemistry and Physics, Vol. 89, Issue 1, p. 80-84
https://doi.org/10.1016/j.matchemphys.2004.08.032

Anode active material hybridizing carbon nanofiber for lithium secondary battery
patent-application, February 2009

Choi, Im Goo; Jang, Seung Yeon; Choi, Namsun
US Patent Application 12/213830; 20090053608
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090053608

Lithium metal dispersion in secondary battery anodes
patent, March 2004

Gao, Yuan; Burba, III, John L.
US Patent Document 6,706,447
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6706447

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent-application, September 2005

Aramata, Mikio; Miyawaki, Satoru; Fukuoka, Hirofumi
US Patent Application 11/085518; 20050214644
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050214644

Electrical transport in doped multiwalled carbon nanotubes
journal, April 2001

Liu, K.; Avouris, Ph.; Martel, R.
Physical Review B, Vol. 63, Issue 16, Article No. 161404(R)
https://doi.org/10.1103/PhysRevB.63.161404

Negative Electrode for Lithium Ion Secondary Battery and Lithium Ion Secondary Battery
patent-application, September 2008

Kogetsu, Yasutaka; Iwamoto, Kazuya; Yamamoto, Taisuke
US Patent Application 12/036767; 20080213671
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080213671

Very Long Cycling of Lithium Ion Batteries with Lithium Rich Cathode Materials
patent-application, March 2012

Amiruddin, Shabab; Li, Bing; Kumar, Sujeet
US Patent Application 13/213756; 20120056590
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120056590

Anode Active Material, Method of Preparing the Same, Anode and Lithium Battery Containing the Material
patent-application, August 2008

Mah, Sang-kook; Kim, Han-su
US Patent Application 11/861200; 20080193831
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080193831

Auxiliary Electrodes For Electrochemical Cells Containing High Capacity Active Materials
patent-application, February 2012

Stefan, Constantin; Fasching, Rainer; Roberts, Gregory
US Patent Application 13/245530; 20120045670
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120045670

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent, October 2008

Jeong, Goo-Jin; Lee, Sang-Min; Kim, Sung-Soo
US Patent Document 7,432,015
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7432015

Lithium Ion Batteries Based On Nanoporous Silicon
patent-application, March 2013

Tolbert, Sarah; Nemanick, Eric; Kang, Chris Byung-Hwa
US Patent Application 13/702990; 20130078508
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130078508

Electrode including porous particles with embedded active material for use in a secondary electrochemical cell
patent, April 1978

Vissers, Donald R.; Nelson, Paul A.; Kaun, Thomas D.
US Patent Document 4,086,404
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4086404

Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004

Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
US Patent Document 6,680,143
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6680143

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Chan, Candace K.; Peng, Hailin; Liu, Gao
Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
https://doi.org/10.1038/nnano.2007.411

Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating
journal, April 2009

Liu, Y.; Wen, Z. Y.; Wang, X. Y.
Journal of Power Sources, Vol. 189, Issue 1, p. 480-484
https://doi.org/10.1016/j.jpowsour.2008.12.045

Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same
patent-application, December 2004

Nakamoto, Takayuki; Bito, Yasuhiko
US Patent Application 10/816221; 20040241548
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040241548

Comments on the structural complexity of lithium-rich Li_1+xM_1−xO₂ electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006

Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538
https://doi.org/10.1016/j.elecom.2006.06.030

Non-aqueous electrolyte secondary battery
patent, July 2000

Watanabe, Shunji; Takasugi, Shinichi; Sakai, Tsugio
US Patent Document 6,083,644
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6083644

Significant Improvement of Electrochemical Performance of AlF₃-Coated Li[Ni_0.8Co_0.1Mn_0.1]O₂ Cathode Materials
journal, January 2007

Woo, S.-U.; Yoon, C. S.; Amine, K.
Journal of The Electrochemical Society, Vol. 154, Issue 11, p. A1005-A1009
https://doi.org/10.1149/1.2776160

Negative Electrode Material For Lithium Secondary Battery, Negative Electrode Using The Material, Lithium Secondary Battery Using The Negative Electrode, And Manufacturing Method Of Negative Electrode Material
patent-application, May 2008

Yamamoto, Teruaki; Sato, Toshitada; Bito, Yasuhiko
US Patent Application 10/584776; 20080113269
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080113269

Method of producing porous silicon particles by stain-etching and silicon nanoparticles from stain-etched silicon powder
patent, April 2009

Li, Yunjun; Pavlovsky, Igor
US Patent Document 7,514,369
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7514369

Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery comprising same
patent, November 2008

Lee, Sang-Min; Kim, Sung-Soo; Sheem, Kyou-Yoon
US Patent Document 7,452,632
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7452632

Amorphous electrode compositions
patent, March 2004

Turner, Robert L.; Fredericksen, Brian D.; Krause, Larry J.
US Patent Document 6,699,336
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6699336

Lithium ion electrochemical cell
patent, September 1999

Moses, Peter R.; Zeng, Shuming; Wang, Enoch I.
US Patent Document 5,948,569
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5948569

Secondary battery
patent, April 2005

Fujita, Shigeru; Akashi, Hiroyuki; Adachi, Momoe
US Patent Document 6,884,546
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6884546

Negative active material for lithium secondary battery and method for preparating same
patent-application, August 2007

Lee, Sung-Man; Lee, Heon Young; Hong, Moon Ki
US Patent Application 10/566344; 20070190413
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070190413

Alloy compositions for lithium ion batteries
patent, December 2010

Obrovac, Mark N.; Christensen, Leif
US Patent Document 7,851,085
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7851085

Lithium Secondary Battery with High Energy Density
patent-application, December 2010

Chung, Geun-Chang; Shin, Dong Seok; Kim, Sun Kyu
US Patent Application 12/829116; 20100330430
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100330430

Secondary battery
patent, July 1990

Miyabayashi, Mitsutaka; Nishii, Toshifumi; Yui, Hiroshi
US Patent Document 4,945,014
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4945014

Positive Electrode Materials for High Discharge Capacity Lithium Ion Batteries
patent-application, June 2010

Lopez, Herman; Venkatachalam, Subramanian; Kumar, Sujeet
US Patent Application 12/332735; 20100151332
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100151332

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries
journal, January 1999

Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young‐Il
Electrochemical and Solid-State Letters, Vol. 2, Issue 3, p. 107-110
https://doi.org/10.1149/1.1390750

Double current collector negative electrode design for alkali metal ion electrochemical cells
patent, May 2004

Gan, Hong; Rubino, Robert S.; Takeuchi, Esther S.
US Patent Document 6,737,191
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6737191

Negative-electrode active material for nonaqueous electrolyte secondary battery, and negative electrode and nonaqueous electrolyte secondary battery using the same
patent-application, September 2007

Ohtsuka, Takashi; Ishida, Sumihito; Matsuda, Hiroaki
US Patent Application 11/703210; 20070207381
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070207381

Fluorine Doped Lithium Rich Metal Oxide Positive Electrode Battery Materials With High Specific Capacity and Corresponding Batteries
patent-application, April 2010

Kumar, Sujeet; Lopez, Herman; Venkatachalam, Subramanian
US Patent Application 12/569606; 20100086854
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100086854

Hybrid anode compositions for lithium ion batteries
patent-application, May 2009

Zhamu, Aruna; Jang, Bor Z.
US Patent Application 11/982662; 20090117466
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090117466

Nonaqueous electrolyte secondary battery
patent, August 2007

Takeuchi, Masanobu; Yoshimura, Seiji
US Patent Document 7,252,907
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7252907

Electrode for use in lithium battery and rechargeable lithium battery
patent, March 2007

Fujimoto, Masahisa; Fujitani, Shin; Shima, Masaki
US Patent Document 7,195,842
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7195842

Electrochemical secondary element
patent, November 1992

Herr, Rudolf; Hoge, Detlev; Bittihn, Rainer
US Patent Document 5,162,176
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5162176

Electrochemical cell electrodes comprising coal-based carbon foam
patent, May 2005

Rogers, Darren Kenneth; Plucinski, Janusz Wladyslaw
US Patent Document 6,899,970
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6899970

Nonaqueous electrolyte secondary battery
patent-application, September 2008

Minami, Hiroshi; Imachi, Naoki
US Patent Application 12/073882; 20080226988
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080226988

Lithium Ion Batteries With Supplemental Lithium
patent-application, May 2012

Amiruddin, Shabab; Venkatachalam, Subramanian; Li, Bing
US Patent Application 13/305981; 20120105007
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120105007

Lithium Ion Batteries With Long Cycling Performance
patent-application, January 2011

Kumar, Sujeet; Buckley, James P.; Shi, Hang
US Patent Application 12/509131; 20110017528
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110017528

High Energy Density Redox Flow Device
patent-application, February 2010

Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan H.
US Patent Document 12/484113; 20100047671
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100047671

Layer-By-Layer Assemblies of Carbon-Based Nanostructures and Their Applications in Energy Storage and Generation Devices
patent-application, June 2010

Shao-Horn, Yang; Lee, Seung Woo; Yabuuchi, Naoaki
US Patent Application 12/541305; 20100159366
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100159366

Method of manufacturing high-surface-area silicon
patent-application, April 2011

Mukasyan, Alexander; Mukasyan, Vasiliy; Nersesyan, Mikael
US Patent Application 12/587738; 20110085960
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110085960

Non-aqueous electrolyte secondary battery
patent, April 2011

Yamamoto, Teruaki; Ueda, Tomohiro; Waki, Shinichi
US Patent Document 7,923,150
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7923150

Lithium ion battery and methods of manufacture
patent-application, April 2006

Munshi, M. Zafar A.
US Patent Application 11/285046; 20060078797
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060078797

Negative Electrode Material for Nonaqueous Electrolyte Secondary Battery, Making Method and Lithium Ion Secondary Battery
patent-application, September 2010

Watanabe, Kohichiro; Kashida, Meguru; Fukuoka, Hirofumi
US Patent Application 12/731044; 20100243951
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100243951

Nano-Sized Silicon
patent-application, April 2009

Treger, Jack
US Patent Application 12/207821; 20090092899
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090092899

AlF₃-Coating to Improve High Voltage Cycling Performance of Li[Ni_1∕3]Co_1∕3]Mn_1∕3]O₂ Cathode Materials for Lithium Secondary Batteries
journal, January 2007

Sun, Y.-K.; Cho, S.-W.; Lee, S.-W.
Journal of The Electrochemical Society, Vol. 154, Issue 3, p. A168-A172
https://doi.org/10.1149/1.2422890

Lithium secondary battery
patent-application, September 2004

Kawamura, Naoya; Kawakami, Soichiro
US Patent Application 10/808481; 20040191630
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040191630

Composite Compositions, Negative Electrodes with Composite Compositions and Corresponding Batteries
patent-application, May 2010

Kumar, Sujeet
US Patent Application 12/502609; 20100119942
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100119942

Secondary lithium ion battery containing a prelithiated anode
patent-application, July 2010

Zhamu, Aruna; Jang, Bor Z.
US Patent Application 12/319114; 20100173198
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100173198

Non-aqueous electrolyte secondary battery and its production method
patent, March 1995

Tahara, Kensuke; Ishikawa, Hideki; Iwasaki, Fumiharu
US Patent Document 5,395,711
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5395711

Conductive silicon composite, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent, May 2006

Aramata, Mikio; Miyawaki, Satoru; Ueno, Susumu
US Patent Document 7,037,581
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7037581

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent, April 2009

Jeong, Goo-Jin; Lee, Sang-Min; Kim, Sung-Soo
US Patent Document 7,517,614
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7517614

Lithium-ion battery
patent, September 2009

Howard, William G.; Schmidt, Craig L.; Scott, Erik R.
US Patent Document 7,582,387
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7582387

Negative electrode material for use in lithium-ion secondary battery and process for producing the same
patent, August 1998

Ejiri, Hiroshi; Yamazaki, Yoshinori; Nakajima, Hideyuki
US Patent Document 5,792,577
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5792577

Nonaqueous electrolyte battery
patent-application, February 2004

Imachi, Naoki; Yoshimura, Seiji; Fujitani, Shin
US Patent Application 10/627677; 20040023117
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040023117

Non-Aqueous Electrolyte Secondary Battery, Negative Electrode Material, and Making Method
patent-application, September 2009

Nakanishi, Tetsuo; Watanabe, Koichiro; Fukuoka, Hirofumi
US Patent Application 12/404710; 20090239151
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090239151

Method of Producing Silicon Oxide, Negative Electrode Active Material for lithium Ion Secondary Battery and Lithium Ion Secondary Battery Using the Same
patent-application, July 2010

Kogetsu, Yasutaka; Ishida, Sumihito
US Patent Application 12/729994; 20100178566
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100178566

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent-application, October 2005

Lee, Sang-Min; Jeong, Goo-Jin; Kim, Sung-Soo
US Patent Application 11/077377; 20050233213
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050233213

Metal Oxide Coated Positive Electrode Materials For Lithium-Based Batteries
patent-application, March 2011

Karthikeyan, Deepak; Venkatachalam, Subramanian; Lopez, Herman
US Patent Application 12/870096; 20110076556
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110076556

Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes
journal, June 2009

Ruffo, Riccardo; Hong, Seung Sae; Chan, Candace K.
The Journal of Physical Chemistry C, Vol. 113, Issue 26, p. 11390-11398
https://doi.org/10.1021/jp901594g

Process for prelithiation of carbon based anodes for lithium ion electrochemical cells
patent, May 1998

Koksbang, Rene; Olsen, Ib I.; Barker, Jeremy
US Patent Document 5,753,388
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5753388

Lithium Doped Cathode Material
patent-application, March 2011

Venkatachalam, Subramanian; Karthikeyan, Deepak Kumaar Kandasamy; Amiruddin, Shabab
US Patent Application 12/870295; 20110052989
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110052989

Silicon Oxide Based High Capacity Anode Materials For Lithium Ion Batteries
patent-application, November 2012

Deng, Haixia; Han, Yongbong; Masarapu, Charan
US Patent Application 13/108708; 20120295155
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120295155

Electrode Active Material, Electrode, And Electricity Storage Device
patent-application, May 2012

Harimoto, Yukinari; Fukui, Hiroshi; Hino, Takakazu
US Patent Application 13/387242; 20120121982
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120121982

Lithium metal dispersion in electrodes
patent-application, June 2005

Gao, Yuan; Yakovleva, Marina; Engel, John
US Patent Application 10/900715; 20050130043
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050130043

Method of producing prelithiated anodes for secondary lithium ion batteries
patent-application, May 2010

Zhamu, Aruna; Jang, Bor Z.
US Patent Application 12/291689; 20100120179
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100120179

Alloy composition for lithium ion batteries
patent, January 2011

Obrovac, Mark N.; Christensen, Leif
US Patent Document 7,871,727
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7871727

High energy electrochemical cell having composite solid-state anode
patent, September 1992

Beard, Kirby W.
US Patent Document 5,147,739
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5147739

Electrodes for alkali metal batteries
patent-application, July 2003

Huggins, Robert A.; Netz, Andreas
US Patent Application 10/053050; 20030135989
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030135989

Nanosized silicon-based composite derived by in situ mechanochemical reduction for lithium ion batteries
journal, February 2007

Yang, Xuelin; Wen, Zhaoyin; Xu, Xiaoxiong
Journal of Power Sources, Vol. 164, Issue 2, p. 880-884
https://doi.org/10.1016/j.jpowsour.2006.11.010

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode
patent, November 2003

Tsutsumi, Masami; Horiuchi, Hiroshi; Yamamoto, Tamotsu
US Patent Document 6,645,671
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6645671

Layer-Layer Lithium Rich Complex Metal Oxides with High Specific Capacity and Excellent Cycling
patent-application, March 2011

Lopez, Herman A.; Venkatachalam, Subramanian; Karthikeyan, Deepak Kumaar Kandasamy
US Patent Application 12/869976; 20110052981
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110052981

Lithium ion cell
patent, February 2000

Herr, Rudolf
US Patent Document 6,025,093
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6025093

Enhancing the rate capability of high capacity xLi₂MnO₃ · (1−x)LiMO₂ (M=Mn, Ni, Co) electrodes by Li–Ni–PO₄ treatment
journal, April 2009

Kang, Sun-Ho; Thackeray, Michael M.
Electrochemistry Communications, Vol. 11, Issue 4, p. 748-751
https://doi.org/10.1016/j.elecom.2009.01.025

Negative Electrode Material, Making Method, Lithium Ion Secondary Battery, and Electrochemical Capacitor
patent-application, January 2010

Watanabe, Koichiro
US Patent Application 12/501759; 20100009261
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100009261

Lithium metal oxide electrodes for lithium batteries
patent-application, February 2005

Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S.
US Patent Application 10/825931; 20050026040
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050026040

Preloading Lithium Ion Cell Components With Lithium
patent-application, May 2011

Cui, Yi; Han, Song; Platshon, Mark
US Patent Application 12/944593; 20110111304
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110111304

Silicon/germanium particle inks, doped particles, printing and processes for semiconductor applications
patent-application, July 2008

Hieslmair, Henry; Dioumaev, Vladimir; Chiruvolu, Shivkumar
US Patent Application 12/006453; 20080160265
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080160265

Doped Positive Electrode Active Materials And Lithium Ion Secondary Battery Constructed Therefrom
patent-application, October 2011

Karthikeyan, Deepak; Venkatachalam, Subramanian; Amiruddin, Shabab
US Patent Application 12/753312; 20110244331
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110244331

Rechargeable lithium battery having improved reversible capacity
patent, February 1998

Jacobs, James K.; Dasgupta, Sankar
US Patent Document 5,721,067
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5721067

Silicon-Silicon Oxide-Lithium Composite, Making Method, And Non-Aqueous Electrolyte Secondary Cell Negative Electrode Material
patent-application, September 2007

Aramata, Mikio; Watanabe, Koichiro; Miyawaki, Satoru
US Patent Application 11/689649; 20070224508
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070224508

Negative Electrode Base Member
patent-application, May 2010

Misumi, Koichi; Saito, Koji; Mitsuhiro, Mitsuhiro
US Patent Application 12/518834; 20100119939
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100119939

Silicon-Containing Alloys Useful as Electrodes for Lithium-Ion Batteries
patent-application, June 2007

Le, Dinh Ba
US Patent Application 11/469561; 20070148544
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070148544

Battery Packs for Vehicles and High Capacity Pouch Secondary Batteries for Incorporation into Compact Battery Packs
patent-application, February 2012

Kumar, Sujeet; Buckley, James P.
US Patent Application 13/195672; 20120028105
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120028105

Method of making a cell using a lithium-deactivated carbon anode
patent, April 1998

Nazri, Gholam-Abbas; Howie, Blake J.
US Patent Document 5,743,921
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5743921

Alloy for negative electrode of lithium secondary battery
patent-application, March 2007

Nakajima, Kenichiro; Takeuchi, Masataka
US Patent Application 11/497275; 20070048612
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070048612

Composite Anode Active Material, Anode Including the Same and Lithium Battery Using the Anode
patent-application, January 2009

Hwang, Seung-sik; Kim, Han-su
US Patent Application 12/120262; 20090023065
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090023065

Electrode structure for lithium secondary battery and secondary battery having such electrode structure
patent, November 2009

Kawakami, Soichiro; Morita, Akira; Ogura, Takao
US Patent Document 7,615,314
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7615314

Electrode for use in lithium battery and rechargeable lithium battery
patent, June 2007

Fujimoto, Masahisa; Fujitani, Shin; Shima, Masaki
US Patent Document 7,235,330
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7235330

Negative Electrode Material for Nonaqueous Electrolyte Secondary Battery, Making Method and Lithium Ion Secondary Battery
patent-application, November 2010

Watanabe, Koichiro; Kashida, Meguru; Fukuoka, Hirofumi
US Patent Application 12/781579; 20100288970
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100288970

Significant improvement of high voltage cycling behavior AlF₃-coated LiCoO₂ cathode
journal, May 2006

Sun, Y.; Han, J.; Myung, S.
Electrochemistry Communications, Vol. 8, Issue 5, p. 821-826
https://doi.org/10.1016/j.elecom.2006.03.040

Multiphase nanocomposite material and method for its manufacture
patent-application, July 2004

Miller, John; Wang, Liya
US Patent Application 10/759348; 20040146734
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040146734

Process for prelithiation of carbon based anodes for lithium batteries
patent, January 1997

Olsen, Ib I.; Koksbang, Rene
US Patent Document 5,595,837
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5595837

Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling
journal, January 1998

Wang, C. S.; Wu, G. T.; Zhang, X. B.
Journal of The Electrochemical Society, Vol. 145, Issue 8, p. 2751-2758
https://doi.org/10.1149/1.1838709

Lithium ion secondary battery
patent, July 2013

Honda, Kazuyoshi; Sato, Toshitada; Suetsugu, Daisuke
US Patent Document 8,486,549
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8486549

Electrolytes, Electrolyte Additives And Cells
patent-application, June 2008

Jambunathan, Krishnakumar; Dantsin, Gennady; Casteel, William
US Patent Application 12/031256; 20080131772
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080131772

Lithium metal dispersion in secondary battery anodes
patent, October 2007

Gao, Yuan; Burba, III, John L.
US Patent Document 7,276,314
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7276314

Stabilized lithium metal powder for li-ion application, composition and process
patent, September 2009

Dover, B. Troy; Woltermann, Christopher Jay; Yakovleva, Marina
US Patent Document 7,588,623
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7588623

Lithium Ion Battery With High Voltage Electrolytes And Additives
patent-application, June 2011

Amiruddin, Shabab; Lopez, Herman
US Patent Application 12/630992; 20110136019
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110136019

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Title: High capacity anode materials for lithium ion batteries

Abstract

Citation Formats

Anodes for rechargeable lithium batteries patent, March 2003

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell patent, July 1995

Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent, February 2010

Non-Aqueous Electrolyte Secondary Battery patent-application, December 2009

Composite anode for nonaqueous secondary battery and method for producing the same patent, July 1996

A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment journal, August 2008

Nonaqueous secondary battery containing silicic material patent, May 2001

Metal Halide Coatings On Lithium Ion Battery Positive Electrode Materials And Corresponding Batteries patent-application, March 2012

Lithium-ion battery patent, July 2009

Anode and Secondary Battery patent-application, August 2009

Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials patent-application, April 2010

Nanowire battery methods and arrangements patent, October 2010

Carbon-Coated Silicon Particle Powder as the Anode Material for Lithium Ion Batteries and Method of Making the Same patent-application, May 2009

Electrode material for lithium secondary battery and electrode structure having the electrode material patent-application, February 2006

Porous Silicon Particulates for Lithium Batteries patent-application, July 2009

Layered Li(Li0.2Ni0.15+0.5zCo0.10Mn0.55−0.5z)O2−zFz cathode materials for Li-ion secondary batteries journal, August 2005

Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 journal, January 2010

Active Material for Non-Aqueous Electrolyte Secondary Battery and Manufacturing Method Therefore patent-application, October 2008

Lithium Ion Batteries with Supplemental Lithium patent-application, May 2012

Electrochemical behaviors of silicon based anode material journal, August 2005

Negative electrode for nonaqueous secondary battery patent-application, March 2006

Battery including an electrolyte solution comprising a halogenated carbonate derivative patent, July 2010

Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent, August 2010

Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries journal, July 2005

High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions patent-application, December 2009

SI/C Composite, Anode Active Materials, and Lithium Battery Including the Same patent-application, January 2009

Composite for Anode Material, Anode Materials and Lithium Battery Using the Same patent-application, July 2009

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent, September 2010

Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries journal, September 2009

Anode for Lithium Ion Cell patent-application, November 2008

Coated Positive Electrode Materials For Lithium Ion Batteries patent-application, May 2011

Method of making activated carbon derived from pitches patent, June 2001

Negative electrode for rechargeable lithium battery and method for fabrication thereof patent, November 2007

Electric separator, method for producing the same and the use thereof patent-application, February 2005

High capacity Li[Li0.2Ni0.2Mn0.6]O2 cathode materials via a carbonate co-precipitation method journal, November 2006

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode patent-application, October 2001

High Energy Lithium Ion Secondary Batteries patent-application, October 2009

Synthesis of spherical Li[Ni(1/3−z)Co(1/3−z)Mn(1/3−z)Mgz]O2 as positive electrode material for lithium-ion battery journal, February 2006

Non-aqueous electrolyte secondary battery and making method patent-application, March 2008

Negative active material, negative electrode using the same, non-aqueous electrolyte battery using the same, and method for preparing the same patent-application, February 2004

Battery including carbon foam current collectors patent, December 2005

Secondary lithium-ion cell with an auxiliary electrode patent, January 2002

Electrode material, and production method and use thereof patent-application, February 2006

Secondary Battery patent-application, December 2009

Method for intercalating alkali metal ions into carbon electrodes patent, August 1995

Electrochemical characterization of a novel Si–graphite–Li2.6Co0.4N composite as anode material for lithium secondary batteries journal, January 2005

Anode active material hybridizing carbon nanofiber for lithium secondary battery patent-application, February 2009

Lithium metal dispersion in secondary battery anodes patent, March 2004

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent-application, September 2005

Electrical transport in doped multiwalled carbon nanotubes journal, April 2001

Negative Electrode for Lithium Ion Secondary Battery and Lithium Ion Secondary Battery patent-application, September 2008

Very Long Cycling of Lithium Ion Batteries with Lithium Rich Cathode Materials patent-application, March 2012

Anode Active Material, Method of Preparing the Same, Anode and Lithium Battery Containing the Material patent-application, August 2008

Auxiliary Electrodes For Electrochemical Cells Containing High Capacity Active Materials patent-application, February 2012

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same patent, October 2008

Lithium Ion Batteries Based On Nanoporous Silicon patent-application, March 2013

Electrode including porous particles with embedded active material for use in a secondary electrochemical cell patent, April 1978

Lithium metal oxide electrodes for lithium cells and batteries patent, January 2004

High-performance lithium battery anodes using silicon nanowires journal, December 2007

Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating journal, April 2009

Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same patent-application, December 2004

Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries journal, September 2006

Non-aqueous electrolyte secondary battery patent, July 2000

Significant Improvement of Electrochemical Performance of AlF3-Coated Li[Ni0.8Co0.1Mn0.1]O2 Cathode Materials journal, January 2007

Negative Electrode Material For Lithium Secondary Battery, Negative Electrode Using The Material, Lithium Secondary Battery Using The Negative Electrode, And Manufacturing Method Of Negative Electrode Material patent-application, May 2008

Method of producing porous silicon particles by stain-etching and silicon nanoparticles from stain-etched silicon powder patent, April 2009

Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery comprising same patent, November 2008

Amorphous electrode compositions patent, March 2004

Lithium ion electrochemical cell patent, September 1999

Secondary battery patent, April 2005

Negative active material for lithium secondary battery and method for preparating same patent-application, August 2007

Alloy compositions for lithium ion batteries patent, December 2010

Lithium Secondary Battery with High Energy Density patent-application, December 2010

Secondary battery patent, July 1990

Positive Electrode Materials for High Discharge Capacity Lithium Ion Batteries patent-application, June 2010

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries journal, January 1999

Double current collector negative electrode design for alkali metal ion electrochemical cells patent, May 2004

Anodes for rechargeable lithium batteries
patent, March 2003

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell
patent, July 1995

Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, February 2010

Non-Aqueous Electrolyte Secondary Battery
patent-application, December 2009

Composite anode for nonaqueous secondary battery and method for producing the same
patent, July 1996

A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment
journal, August 2008

Nonaqueous secondary battery containing silicic material
patent, May 2001

Metal Halide Coatings On Lithium Ion Battery Positive Electrode Materials And Corresponding Batteries
patent-application, March 2012

Lithium-ion battery
patent, July 2009

Anode and Secondary Battery
patent-application, August 2009

Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials
patent-application, April 2010

Nanowire battery methods and arrangements
patent, October 2010

Carbon-Coated Silicon Particle Powder as the Anode Material for Lithium Ion Batteries and Method of Making the Same
patent-application, May 2009

Electrode material for lithium secondary battery and electrode structure having the electrode material
patent-application, February 2006

Porous Silicon Particulates for Lithium Batteries
patent-application, July 2009

Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries
journal, August 2005

Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni_0.17Li_0.2Co_0.07Mn_0.56]O₂
journal, January 2010

Active Material for Non-Aqueous Electrolyte Secondary Battery and Manufacturing Method Therefore
patent-application, October 2008

Lithium Ion Batteries with Supplemental Lithium
patent-application, May 2012

Electrochemical behaviors of silicon based anode material
journal, August 2005

Negative electrode for nonaqueous secondary battery
patent-application, March 2006

Battery including an electrolyte solution comprising a halogenated carbonate derivative
patent, July 2010

Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, August 2010

Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries
journal, July 2005

High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions
patent-application, December 2009

SI/C Composite, Anode Active Materials, and Lithium Battery Including the Same
patent-application, January 2009

Composite for Anode Material, Anode Materials and Lithium Battery Using the Same
patent-application, July 2009

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent, September 2010

Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries
journal, September 2009

Anode for Lithium Ion Cell
patent-application, November 2008

Coated Positive Electrode Materials For Lithium Ion Batteries
patent-application, May 2011

Method of making activated carbon derived from pitches
patent, June 2001

Negative electrode for rechargeable lithium battery and method for fabrication thereof
patent, November 2007

Electric separator, method for producing the same and the use thereof
patent-application, February 2005

High capacity Li[Li_0.2Ni_0.2Mn_0.6]O₂ cathode materials via a carbonate co-precipitation method
journal, November 2006

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode
patent-application, October 2001

High Energy Lithium Ion Secondary Batteries
patent-application, October 2009

Synthesis of spherical Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ as positive electrode material for lithium-ion battery
journal, February 2006

Non-aqueous electrolyte secondary battery and making method
patent-application, March 2008

Negative active material, negative electrode using the same, non-aqueous electrolyte battery using the same, and method for preparing the same
patent-application, February 2004

Battery including carbon foam current collectors
patent, December 2005

Secondary lithium-ion cell with an auxiliary electrode
patent, January 2002

Electrode material, and production method and use thereof
patent-application, February 2006

Secondary Battery
patent-application, December 2009

Method for intercalating alkali metal ions into carbon electrodes
patent, August 1995

Electrochemical characterization of a novel Si–graphite–Li_2.6Co_0.4N composite as anode material for lithium secondary batteries
journal, January 2005

Anode active material hybridizing carbon nanofiber for lithium secondary battery
patent-application, February 2009

Lithium metal dispersion in secondary battery anodes
patent, March 2004

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent-application, September 2005

Electrical transport in doped multiwalled carbon nanotubes
journal, April 2001

Negative Electrode for Lithium Ion Secondary Battery and Lithium Ion Secondary Battery
patent-application, September 2008

Very Long Cycling of Lithium Ion Batteries with Lithium Rich Cathode Materials
patent-application, March 2012

Anode Active Material, Method of Preparing the Same, Anode and Lithium Battery Containing the Material
patent-application, August 2008

Auxiliary Electrodes For Electrochemical Cells Containing High Capacity Active Materials
patent-application, February 2012

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent, October 2008

Lithium Ion Batteries Based On Nanoporous Silicon
patent-application, March 2013

Electrode including porous particles with embedded active material for use in a secondary electrochemical cell
patent, April 1978

Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating
journal, April 2009

Negative electrode active material and non-aqueous electrolyte rechargeable battery using the same
patent-application, December 2004

Comments on the structural complexity of lithium-rich Li_1+xM_1−xO₂ electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006

Non-aqueous electrolyte secondary battery
patent, July 2000

Significant Improvement of Electrochemical Performance of AlF₃-Coated Li[Ni_0.8Co_0.1Mn_0.1]O₂ Cathode Materials
journal, January 2007

Negative Electrode Material For Lithium Secondary Battery, Negative Electrode Using The Material, Lithium Secondary Battery Using The Negative Electrode, And Manufacturing Method Of Negative Electrode Material
patent-application, May 2008

Method of producing porous silicon particles by stain-etching and silicon nanoparticles from stain-etched silicon powder
patent, April 2009

Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery comprising same
patent, November 2008

Amorphous electrode compositions
patent, March 2004

Lithium ion electrochemical cell
patent, September 1999

Secondary battery
patent, April 2005

Negative active material for lithium secondary battery and method for preparating same
patent-application, August 2007

Alloy compositions for lithium ion batteries
patent, December 2010

Lithium Secondary Battery with High Energy Density
patent-application, December 2010

Secondary battery
patent, July 1990

Positive Electrode Materials for High Discharge Capacity Lithium Ion Batteries
patent-application, June 2010

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries
journal, January 1999

Double current collector negative electrode design for alkali metal ion electrochemical cells
patent, May 2004

Negative-electrode active material for nonaqueous electrolyte secondary battery, and negative electrode and nonaqueous electrolyte secondary battery using the same
patent-application, September 2007

Fluorine Doped Lithium Rich Metal Oxide Positive Electrode Battery Materials With High Specific Capacity and Corresponding Batteries
patent-application, April 2010

Hybrid anode compositions for lithium ion batteries
patent-application, May 2009