Non-aqueous electrolytes for lithium ion batteries

Chen, Zonghai; Amine, Khalil

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Title: Non-aqueous electrolytes for lithium ion batteries

Abstract

The present invention is generally related to electrolytes containing anion receptor additives to enhance the power capability of lithium-ion batteries. The anion receptor of the present invention is a Lewis acid that can help to dissolve LiF in the passivation films of lithium-ion batteries. Accordingly, one aspect the invention provides electrolytes comprising a lithium salt; a polar aprotic solvent; and an anion receptor additive; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.

Inventors:: Chen, Zonghai; Amine, Khalil

Issue Date:: Thu Nov 12 00:00:00 EST 2015

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1225698

Patent Number(s):: 9184428

Application Number:: 11/373,054

Assignee:: UCHICAGO ARGONNE LLC

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/0566 - Liquid materials
H01M10/0567 - characterised by the additives
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M10/4235 - {Safety or regulating additives or arrangements in electrodes, separators or electrolyte
H01M2300/0025 - Organic electrolyte
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/1315 - containing halogen atoms, e.g. LiCoOxFy
H01M4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: W31-109-ENG-38

Resource Type:: Patent

Resource Relation:: Patent File Date: 2006 Mar 10

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

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                    Chen, Zonghai, and Amine, Khalil. Non-aqueous electrolytes for lithium ion batteries.  United States: N. p., 2015. 
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                    Chen, Zonghai, & Amine, Khalil. Non-aqueous electrolytes for lithium ion batteries.  United States.

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                    Chen, Zonghai, and Amine, Khalil. Thu .  
        "Non-aqueous electrolytes for lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1225698.

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@article{osti_1225698,

  title        = {Non-aqueous electrolytes for lithium ion batteries},

  author       = {Chen, Zonghai and Amine, Khalil},

  abstractNote = {The present invention is generally related to electrolytes containing anion receptor additives to enhance the power capability of lithium-ion batteries. The anion receptor of the present invention is a Lewis acid that can help to dissolve LiF in the passivation films of lithium-ion batteries. Accordingly, one aspect the invention provides electrolytes comprising a lithium salt; a polar aprotic solvent; and an anion receptor additive; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Nov 12 00:00:00 EST 2015},

  month        = {Thu Nov 12 00:00:00 EST 2015}

}

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journal, January 2002

Sun, X.; Lee, H. S.; Yang, X. -Q.
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https://doi.org/10.1149/1.1510321

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A lithium-air cell includes a negative electrode; an air positive electrode; and a non-aqueous electrolyte which includes an anion receptor that may be represented by one or more of the formulas. ##STR00001##
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Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Patent Chen, Zonghai; Amine, Khalil

Lithium-air cells employing poly(ethyleneoxide) phosphate-based electrolytes may be prepared and exhibit improved charge carrying capacity. Such PEO phosphates generally have the formulas IIa, IIb, IIc, where: ##STR00001##
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Title: Non-aqueous electrolytes for lithium ion batteries

Abstract

Citation Formats

Preparation of ketene acetals patent, April 1985

Method for making duplex metal alloy/polymer composites patent, September 1986

Overcharge protection of secondary, non-aqueous batteries patent, August 1989

Method of making an electrolyte activatable lithium-ion rechargeable battery cell patent, October 1995

Layer for stabilization of lithium anode patent, January 1996

Gel electrolyte bonded rechargeable electrochemical cell and method of making same patent, October 1997

Method of making a gel electrolyte bonded rechargeable electrochemical cell patent, November 1997

Non-aqueous electrolyte secondary battery patent, January 1998

Multilayered gel electrolyte bonded rechargeable electrochemical cell and method of making same patent, February 1998

Electrolytic solution for lithium secondary battery and lithium secondary battery using the same patent, March 1998

Non-aqueous electrolyte secondary cell having shuttle agent patent, June 1998

Easy open end of a metal-plastic construction patent, June 1998

Method of making a multilayered gel electrolyte bonded rechargeable electrochemical cell patent, November 1998

Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents patent, December 1998

Chemical overcharge protection of lithium and lithium-ion secondary batteries patent, January 1999

Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection patent, December 1999

Boron compounds as anion binding agents for nonaqueous battery electrolytes patent, February 2000

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes patent, April 2000

Additives for overcharge protection in non-aqueous rechargeable lithium batteries patent, June 2000

Nonaqueous secondary battery patent, May 2001

Non-aqueous electrolyte battery patent, September 2001

Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes patent, March 2002

Electrolyte for a rechargeable cell patent, May 2002

Nonaqueous electrolyte battery patent, November 2002

Lithium bisoxalatoborate, the production thereof and its use as a conducting salt patent, January 2003

Process for producing electrode of nonaqueous electrolyte battery patent, January 2004

Method for manufacturing galvanic elements having a liquid organic electrolyte patent, August 2004

Lithium-based active materials and preparation thereof patent-application, April 2002

Rechargeable lithium electrochemical cell patent-application, February 2004

Mesoporous network electrode for electrochemical cell patent-application, July 2004

Positive electrode material for lithium ion batteries patent-application, August 2004

Electrodes for lithium batteries patent-application, September 2004

Long life lithium batteries with stabilized electrodes patent-application, January 2005

Overcharge protection for electrochemical cells patent-application, October 2005

Using a Boron-Based Anion Receptor Additive to Improve the Thermal Stability of LiPF[sub 6]-Based Electrolyte for Lithium Batteries journal, January 2002

Storage and cycling performance of Cr-modified spinel at elevated temperatures journal, October 2001

Electroactivity of natural and synthetic triphylite journal, July 2001

Rechargeable cathodes based on Li2CrxMn2−xO4 journal, April 1995

Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mössbauer spectroscopy study journal, May 2000

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate journal, September 2002

Optimized LiFePO[sub 4] for Lithium Battery Cathodes journal, January 2001

Optimized Lithium Iron Phosphate for High-Rate Electrochemical Applications journal, January 2004

Electronically conductive phospho-olivines as lithium storage electrodes journal, September 2002

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal, April 1997

Failure Mechanism and Improvement of the Elevated Temperature Cycling of LiMn[sub 2]O[sub 4] Compounds Through the Use of the LiAl[sub x]Mn[sub 2−x]O[sub 4−z]F[sub z] Solid Solution journal, January 2001

Influence of the Cr Content on the Electrochemical Behavior of the LiCr[sub y]Mn[sub 2−y]O[sub 4] (0≤y≤1) Compounds: III. Galvanostatic Study of Bulk and Superficial Processes journal, January 2001

Processing and properties of two different poly (ortho esters) journal, January 2000

Synthesis of a Series of Fluorinated Boronate Compounds and Their Use as Additives in Lithium Battery Electrolytes journal, January 2004

Synthesis of Anion Receptor Grafted Siloxane Polymers and the Ionic Conductivity Studies of Polymer-Salt Complexes journal, January 1999

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries journal, January 2005

2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn 2 O 4 Rechargable Battery journal, December 2002

Anion receptor for enhanced thermal stability of the graphite anode interface in a Li-ion battery journal, June 2003

Artificial Organic Host Molecules for Anions journal, August 1997

Comparative Studies of the Electrochemical and Thermal Stability of Two Types of Composite Lithium Battery Electrolytes Using Boron-Based Anion Receptors journal, January 1999

Improved Elevated Temperature Cycling of LiMn[sub 2]O[sub 4] Spinel Through the Use of a Composite LiF-Based Electrolyte journal, January 2001

The Compatibility of a Boron-Based Anion Receptor with the Carbon Anode in Lithium-Ion Batteries journal, January 2003

A Novel Lithium Battery Electrolyte Based on Lithium Fluoride and a Tris(pentafluorophenyl) Borane Anion Receptor in DME journal, January 1999

Using a Boron-Based Anion Receptor Additive to Improve the Thermal Stability of LiPF[sub 6]-Based Electrolyte for Lithium Batteries journal, January 2002

Preparation of ketene acetals
patent, April 1985

Method for making duplex metal alloy/polymer composites
patent, September 1986

Overcharge protection of secondary, non-aqueous batteries
patent, August 1989

Method of making an electrolyte activatable lithium-ion rechargeable battery cell
patent, October 1995

Layer for stabilization of lithium anode
patent, January 1996

Gel electrolyte bonded rechargeable electrochemical cell and method of making same
patent, October 1997

Method of making a gel electrolyte bonded rechargeable electrochemical cell
patent, November 1997

Non-aqueous electrolyte secondary battery
patent, January 1998

Multilayered gel electrolyte bonded rechargeable electrochemical cell and method of making same
patent, February 1998

Electrolytic solution for lithium secondary battery and lithium secondary battery using the same
patent, March 1998

Non-aqueous electrolyte secondary cell having shuttle agent
patent, June 1998

Easy open end of a metal-plastic construction
patent, June 1998

Method of making a multilayered gel electrolyte bonded rechargeable electrochemical cell
patent, November 1998

Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents
patent, December 1998

Chemical overcharge protection of lithium and lithium-ion secondary batteries
patent, January 1999

Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection
patent, December 1999

Boron compounds as anion binding agents for nonaqueous battery electrolytes
patent, February 2000

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes
patent, April 2000

Additives for overcharge protection in non-aqueous rechargeable lithium batteries
patent, June 2000

Nonaqueous secondary battery
patent, May 2001

Non-aqueous electrolyte battery
patent, September 2001

Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes
patent, March 2002

Electrolyte for a rechargeable cell
patent, May 2002

Nonaqueous electrolyte battery
patent, November 2002

Lithium bisoxalatoborate, the production thereof and its use as a conducting salt
patent, January 2003

Process for producing electrode of nonaqueous electrolyte battery
patent, January 2004

Method for manufacturing galvanic elements having a liquid organic electrolyte
patent, August 2004

Lithium-based active materials and preparation thereof
patent-application, April 2002

Rechargeable lithium electrochemical cell
patent-application, February 2004

Mesoporous network electrode for electrochemical cell
patent-application, July 2004

Positive electrode material for lithium ion batteries
patent-application, August 2004

Electrodes for lithium batteries
patent-application, September 2004

Long life lithium batteries with stabilized electrodes
patent-application, January 2005

Overcharge protection for electrochemical cells
patent-application, October 2005

Using a Boron-Based Anion Receptor Additive to Improve the Thermal Stability of LiPF[sub 6]-Based Electrolyte for Lithium Batteries
journal, January 2002

Storage and cycling performance of Cr-modified spinel at elevated temperatures
journal, October 2001

Electroactivity of natural and synthetic triphylite
journal, July 2001

Rechargeable cathodes based on Li₂Cr_xMn_2−xO₄
journal, April 1995

Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mössbauer spectroscopy study
journal, May 2000

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate
journal, September 2002

Optimized LiFePO[sub 4] for Lithium Battery Cathodes
journal, January 2001

Optimized Lithium Iron Phosphate for High-Rate Electrochemical Applications
journal, January 2004

Electronically conductive phospho-olivines as lithium storage electrodes
journal, September 2002

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

Failure Mechanism and Improvement of the Elevated Temperature Cycling of LiMn[sub 2]O[sub 4] Compounds Through the Use of the LiAl[sub x]Mn[sub 2−x]O[sub 4−z]F[sub z] Solid Solution
journal, January 2001

Influence of the Cr Content on the Electrochemical Behavior of the LiCr[sub y]Mn[sub 2−y]O[sub 4] (0≤y≤1) Compounds: III. Galvanostatic Study of Bulk and Superficial Processes
journal, January 2001

Processing and properties of two different poly (ortho esters)
journal, January 2000

Synthesis of a Series of Fluorinated Boronate Compounds and Their Use as Additives in Lithium Battery Electrolytes
journal, January 2004

Synthesis of Anion Receptor Grafted Siloxane Polymers and the Ionic Conductivity Studies of Polymer-Salt Complexes
journal, January 1999

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries
journal, January 2005

2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn ₂ O ₄ Rechargable Battery
journal, December 2002

Anion receptor for enhanced thermal stability of the graphite anode interface in a Li-ion battery
journal, June 2003

Artificial Organic Host Molecules for Anions
journal, August 1997

Comparative Studies of the Electrochemical and Thermal Stability of Two Types of Composite Lithium Battery Electrolytes Using Boron-Based Anion Receptors
journal, January 1999

Improved Elevated Temperature Cycling of LiMn[sub 2]O[sub 4] Spinel Through the Use of a Composite LiF-Based Electrolyte
journal, January 2001

The Compatibility of a Boron-Based Anion Receptor with the Carbon Anode in Lithium-Ion Batteries
journal, January 2003

A Novel Lithium Battery Electrolyte Based on Lithium Fluoride and a Tris(pentafluorophenyl) Borane Anion Receptor in DME
journal, January 1999

Using a Boron-Based Anion Receptor Additive to Improve the Thermal Stability of LiPF[sub 6]-Based Electrolyte for Lithium Batteries
journal, January 2002