Multifunctional thin film surface
Abstract
A thin film with multiple binding functionality can be prepared on an electrode surface via consecutive electroreduction of two or more aryl-onium salts with different functional groups. This versatile and simple method for forming multifunctional surfaces provides an effective means for immobilization of diverse molecules at close proximities. The multifunctional thin film has applications in bioelectronics, molecular electronics, clinical diagnostics, and chemical and biological sensing.
- Inventors:
- Issue Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1223108
- Patent Number(s):
- 9157161
- Application Number:
- 13/183,099
- Assignee:
- Sandia Corporation (Albuquerque, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25D - PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS
- DOE Contract Number:
- AC04-94AL85000
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2011 Jul 14
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION
Citation Formats
Brozik, Susan M., Harper, Jason C., Polsky, Ronen, Wheeler, David R., Arango, Dulce C., and Dirk, Shawn M. Multifunctional thin film surface. United States: N. p., 2015.
Web.
Brozik, Susan M., Harper, Jason C., Polsky, Ronen, Wheeler, David R., Arango, Dulce C., & Dirk, Shawn M. Multifunctional thin film surface. United States.
Brozik, Susan M., Harper, Jason C., Polsky, Ronen, Wheeler, David R., Arango, Dulce C., and Dirk, Shawn M. Tue .
"Multifunctional thin film surface". United States. https://www.osti.gov/servlets/purl/1223108.
@article{osti_1223108,
title = {Multifunctional thin film surface},
author = {Brozik, Susan M. and Harper, Jason C. and Polsky, Ronen and Wheeler, David R. and Arango, Dulce C. and Dirk, Shawn M.},
abstractNote = {A thin film with multiple binding functionality can be prepared on an electrode surface via consecutive electroreduction of two or more aryl-onium salts with different functional groups. This versatile and simple method for forming multifunctional surfaces provides an effective means for immobilization of diverse molecules at close proximities. The multifunctional thin film has applications in bioelectronics, molecular electronics, clinical diagnostics, and chemical and biological sensing.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {10}
}
Works referenced in this record:
Methods and devices for carrying out chemical reactions
patent, June 2001
- Gordon, Gary B.; Dellinger, Douglas J.
- US Patent Document 6,251,595
Analytical instruments, biosensors and methods thereof
patent, November 2003
- Mansouri, Sohrab; Cosofret, Vasile; Xu, Clarke
- US Patent Document 6,652,720
Electrochemical assembly of organic molecules by the reduction of iodonium salts
patent, June 2009
- Dirk, Shawn M.; Howell, Stephen W.; Wheeler, David R.
- US Patent Document 7,550,071
Method for grafting and growing a conductive organic film on a surface
patent-application, December 2004
- Bureau, Christophe; Levy, Edouard; Viel, Pascal
- US Patent Application 10/487731; 20040248428
Diazonium−Protein Adducts for Graphite Electrode Microarrays Modification: Direct and Addressed Electrochemical Immobilization
journal, December 2005
- Corgier, Benjamin P.; Marquette, Christophe A.; Blum, Loïc J.
- Journal of the American Chemical Society, Vol. 127, Issue 51
Diazonium salts: Stable monolayers on gold electrodes for sensing applications
journal, February 2007
- Liu, Guozhen; Böcking, Till; Gooding, J. Justin
- Journal of Electroanalytical Chemistry, Vol. 600, Issue 2, p. 335-344
Covalent modification of carbon surfaces by grafting of functionalized aryl radicals produced from electrochemical reduction of diazonium salts
journal, July 1992
- Delamar, Michel; Hitmi, Rachid; Pinson, Jean
- Journal of the American Chemical Society, Vol. 114, Issue 14, p. 5883-5884
Formation of Multilayers on Glassy Carbon Electrodes via the Reduction of Diazonium Salts
journal, September 2001
- Kariuki, James K.; McDermott, Mark T.
- Langmuir, Vol. 17, Issue 19
Immobilization of Glycosylated Enzymes on Carbon Electrodes, and its Application in Biosensors
journal, April 2005
- Ma, Ying; Gao, Qiang; Yang, Xiurong
- Microchimica Acta, Vol. 150, Issue 1
Immobilization of Aryl and Alkynyl Groups onto Glassy Carbon Surfaces by Electrochemical Reduction of Iodonium Salts
journal, August 2005
- Vase, Karina Højrup; Holm, Allan Hjarbæk; Pedersen, Steen Uttrup
- Langmuir, Vol. 21, Issue 18
Covalent Grafting of Glassy Carbon Electrodes with Diaryliodonium Salts: New Aspects
journal, March 2007
- Vase, Karina Højrup; Holm, Allan Hjarbæk; Norrman, Kion
- Langmuir, Vol. 23, Issue 7
Anti-Sticking Effect of Organic Dielectric Formed by Electrodeposition in Microelectromechanical-System Structures
journal, July 2005
- Sakata, Tomomi; Ishii, Hiromu; Okabe, Yuichi
- Japanese Journal of Applied Physics, Vol. 44, Issue 7B
Electrochemical Surface Derivatization of Glassy Carbon by the Reduction of Triaryl- and Alkyldiphenylsulfonium Salts
journal, January 2008
- Vase, Karina Højrup; Holm, Allan Hjarbæk; Norrman, Kion
- Langmuir, Vol. 24, Issue 1
Direct electrochemistry of horseradish peroxidase bonded on a conducting polymer modified glassy carbon electrode
journal, November 2003
- Kong, Young-Tae; Boopathi, Mannan; Shim, Yoon-Bo
- Biosensors and Bioelectronics, Vol. 19, Issue 3, p. 227-232
Immobilization of glucose oxidase on a carbon surface derivatized by electrochemical reduction of diazonium salts
journal, September 1992
- Bourdillon, Christian; Delamar, Michel; Demaille, Christophe
- Journal of Electroanalytical Chemistry, Vol. 336, Issue 1-2, p. 113-123
Biotinylation of Screen-Printed Carbon Electrodes through the Electrochemical Reduction of the Diazonium Salt of p -Aminobenzoyl Biocytin
journal, July 1999
- Dequaire, Murielle; Degrand, Chantal; Limoges, Benoît
- Journal of the American Chemical Society, Vol. 121, Issue 29
Electroaddressable Selective Functionalization of Electrode Arrays: Catalytic NADH Detection Using Aryl Diazonium Modified Gold Electrodes
journal, June 2007
- Harper, Jason C.; Polsky, Ronen; Dirk, Shawn M.
- Electroanalysis, Vol. 19, Issue 12
Protein Pattern Assembly by Active Control of a Triblock Copolymer Monolayer
journal, December 2006
- Fan, Chao Yung; Kurabayashi, Katsuo; Meyhöfer, Edgar
- Nano Letters, Vol. 6, Issue 12
Diazonium salts: Stable monolayers on gold electrodes for sensing applications
journal, February 2007
- Liu, Guozhen; Böcking, Till; Gooding, J. Justin
- Journal of Electroanalytical Chemistry, Vol. 600, Issue 2, p. 335-344
DNA immobilization onto electrochemically functionalized Si(100) surfaces
journal, October 2006
- Shabani, A.; Mak, A. W. H.; Gerges, I.
- Talanta, Vol. 70, Issue 3, p. 615-623
Multifunctional Electrode Arrays: Towards a Universal Detection Platform
journal, March 2008
- Polsky, Ronen; Harper, Jason C.; Wheeler, David R.
- Electroanalysis, Vol. 20, Issue 6, p. 671-679
Enzyme Based Amperometric Biosensors for Food Analysis
journal, February 2002
- Prodromidis, Mamas I.; Karayannis, Miltiades I.
- Electroanalysis, Vol. 14, Issue 4
Diazonium−Protein Adducts for Graphite Electrode Microarrays Modification: Direct and Addressed Electrochemical Immobilization
journal, December 2005
- Corgier, Benjamin P.; Marquette, Christophe A.; Blum, Loïc J.
- Journal of the American Chemical Society, Vol. 127, Issue 51
Biomolecule immobilization on electrode surfaces by entrapment or attachment to electrochemically polymerized films. A review
journal, May 1999
- Cosnier, Serge
- Biosensors and Bioelectronics, Vol. 14, Issue 5, p. 443-456
Direct electrical communication between chemically modified enzymes and metal electrodes. 2. Methods for bonding electron-transfer relays to glucose oxidase and D-amino-acid oxidase
journal, April 1988
- Degani, Yinon.; Heller, Adam.
- Journal of the American Chemical Society, Vol. 110, Issue 8, p. 2615-2620
Covalent modification of carbon surfaces by grafting of functionalized aryl radicals produced from electrochemical reduction of diazonium salts
journal, July 1992
- Delamar, Michel; Hitmi, Rachid; Pinson, Jean
- Journal of the American Chemical Society, Vol. 114, Issue 14, p. 5883-5884
Characterization of the Deposition of Organic Molecules at the Surface of Gold by the Electrochemical Reduction of Aryldiazonium Cations
journal, July 2005
- Laforgue, Alexis; Addou, Tania; Bélanger, Daniel
- Langmuir, Vol. 21, Issue 15
Electrically Addressable Biomolecular Functionalization of Carbon Nanotube and Carbon Nanofiber Electrodes
journal, September 2004
- Lee, Chang-Soo; Baker, Sarah E.; Marcus, Matthew S.
- Nano Letters, Vol. 4, Issue 9
An Interface Comprising Molecular Wires and Poly(ethylene glycol) Spacer Units Self-Assembled on Carbon Electrodes for Studies of Protein Electrochemistry
journal, August 2006
- Liu, ; Gooding, J. Justin
- Langmuir, Vol. 22, Issue 17
Universal tools for biomolecular attachment to surfaces
journal, November 2006
- Medintz, Igor
- Nature Materials, Vol. 5, Issue 11
Diazonium-Functionalized Horseradish Peroxidase Immobilized via Addressable Electrodeposition: Direct Electron Transfer and Electrochemical Detection
journal, January 2007
- Polsky, Ronen; Harper, Jason C.; Dirk, Shawn M.
- Langmuir, Vol. 23, Issue 2, p. 364-366
Direct Covalent Grafting of Conjugated Molecules onto Si, GaAs, and Pd Surfaces from Aryldiazonium Salts
journal, January 2004
- Stewart, Michael P.; Maya, Francisco; Kosynkin, Dmitry V.
- Journal of the American Chemical Society, Vol. 126, Issue 1, p. 370-378
Formation of Polyphenylene Films on Metal Electrodes by Electrochemical Reduction of Benzenediazonium Salts
journal, April 2006
- Adenier, Alain; Combellas, Catherine; Kanoufi, Frédéric
- Chemistry of Materials, Vol. 18, Issue 8
Covalent Modification of Carbon Surfaces by Aryl Radicals Generated from the Electrochemical Reduction of Diazonium Salts
journal, January 1997
- Allongue, Philippe; Delamar, Michel; Desbat, Bernard
- Journal of the American Chemical Society, Vol. 119, Issue 1
Mono- and Multilayer Formation by Diazonium Reduction on Carbon Surfaces Monitored with Atomic Force Microscopy “Scratching”
journal, August 2003
- Anariba, Franklin; DuVall, Stacy H.; McCreery, Richard L.
- Analytical Chemistry, Vol. 75, Issue 15
Organic Layers Bonded to Industrial, Coinage, and Noble Metals through Electrochemical Reduction of Aryldiazonium Salts
journal, September 2003
- Bernard, Marie-Claude; Chaussé, Annie; Cabet-Deliry, Eva
- Chemistry of Materials, Vol. 15, Issue 18
Multilayer Nitroazobenzene Films Covalently Attached to Carbon. An AFM and Electrochemical Study
journal, May 2005
- Brooksby, Paula A.; Downard, Alison J.
- The Journal of Physical Chemistry B, Vol. 109, Issue 18
Nanoscale Patterning of Flat Carbon Surfaces by Scanning Probe Lithography and Electrochemistry
journal, March 2005
- Brooksby, Paula A.; Downard, Alison J.
- Langmuir, Vol. 21, Issue 5
Covalent modification of carbon surfaces by grafting of functionalized aryl radicals produced from electrochemical reduction of diazonium salts
journal, July 1992
- Delamar, Michel; Hitmi, Rachid; Pinson, Jean
- Journal of the American Chemical Society, Vol. 114, Issue 14, p. 5883-5884
Microscale Patterning of Organic Films on Carbon Surfaces Using Electrochemistry and Soft Lithography †
journal, December 2006
- Downard, Alison J.; Garrett, David J.; Tan, Emelyn S. Q.
- Langmuir, Vol. 22, Issue 25
A Multifunctional Thin Film Au Electrode Surface Formed by Consecutive Electrochemical Reduction of Aryl Diazonium Salts
journal, March 2009
- Harper, Jason C.; Polsky, Ronen; Wheeler, David R.
- Langmuir, Vol. 25, Issue 5, p. 3282-3288
The modification of glassy carbon and gold electrodes with aryl diazonium salt: The impact of the electrode materials on the rate of heterogeneous electron transfer
journal, December 2005
- Liu, Guozhen; Liu, Jingquan; Böcking, Till
- Chemical Physics, Vol. 319, Issue 1-3, p. 136-146
An Interface Comprising Molecular Wires and Poly(ethylene glycol) Spacer Units Self-Assembled on Carbon Electrodes for Studies of Protein Electrochemistry
journal, August 2006
- Liu, ; Gooding, J. Justin
- Langmuir, Vol. 22, Issue 17
The Electrochemical Grafting of a Mixture of Substituted Phenyl Groups at a Glassy Carbon Electrode Surface
journal, June 2008
- Louault, Cyril; D'Amours, Mathieu; Bélanger, Daniel
- ChemPhysChem, Vol. 9, Issue 8
Modified Carbon Surfaces as “Organic Electrodes” That Exhibit Conductance Switching
journal, January 2003
- Solak, Ali Osman; Eichorst, Laura R.; Clark, William J.
- Analytical Chemistry, Vol. 75, Issue 2
Direct Covalent Grafting of Conjugated Molecules onto Si, GaAs, and Pd Surfaces from Aryldiazonium Salts
journal, January 2004
- Stewart, Michael P.; Maya, Francisco; Kosynkin, Dmitry V.
- Journal of the American Chemical Society, Vol. 126, Issue 1, p. 370-378