Porous silicon based anode material formed using metal reduction

Anguchamy, Yogesh Kumar; Masarapu, Charan; Deng, Haixia; Han, Yongbong; Venkatachalam, Subramanian; Kumar, Sujeet; Lopez, Herman A.

Title: Porous silicon based anode material formed using metal reduction

Abstract

A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m.sup.2/g to about 200 m.sup.2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm.sup.2 to about 3.5 mg/cm.sup.2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.

Inventors:: Anguchamy, Yogesh Kumar; Masarapu, Charan; Deng, Haixia; Han, Yongbong; Venkatachalam, Subramanian; Kumar, Sujeet; Lopez, Herman A.

Issue Date:: 2015-09-22

Research Org.:: Envia Systems, Inc., Newark, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1221392

Patent Number(s):: 9139441

Application Number:: 13/354,096

Assignee:: Envia Systems, Inc. (Newark, CA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
B82Y30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B33/023 - by reduction of silica or {free} silica-containing material

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M2004/021 - {Physical characteristics, e.g. porosity, surface area}
H01M2010/4292 - {Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode}
H01M4/134 - Electrodes based on metals, Si or alloys
H01M4/362 - {Composites}
H01M4/366 - {as layered products}
H01M4/386 - {Silicon or alloys based on silicon}
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M4/622 - {being polymers}
H01M4/625 - {Carbon or graphite}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T10/70 - Energy storage for electromobility

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DOE Contract Number:: AR0000034

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Jan 19

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Anguchamy, Yogesh Kumar, Masarapu, Charan, Deng, Haixia, Han, Yongbong, Venkatachalam, Subramanian, Kumar, Sujeet, and Lopez, Herman A. Porous silicon based anode material formed using metal reduction.  United States: N. p., 2015. 
        Web.

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                    Anguchamy, Yogesh Kumar, Masarapu, Charan, Deng, Haixia, Han, Yongbong, Venkatachalam, Subramanian, Kumar, Sujeet, & Lopez, Herman A. Porous silicon based anode material formed using metal reduction.  United States.

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                    Anguchamy, Yogesh Kumar, Masarapu, Charan, Deng, Haixia, Han, Yongbong, Venkatachalam, Subramanian, Kumar, Sujeet, and Lopez, Herman A. Tue .  
        "Porous silicon based anode material formed using metal reduction".  United States.  https://www.osti.gov/servlets/purl/1221392.

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@article{osti_1221392,

  title        = {Porous silicon based anode material formed using metal reduction},

  author       = {Anguchamy, Yogesh Kumar and Masarapu, Charan and Deng, Haixia and Han, Yongbong and Venkatachalam, Subramanian and Kumar, Sujeet and Lopez, Herman A.},

  abstractNote = {A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m.sup.2/g to about 200 m.sup.2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm.sup.2 to about 3.5 mg/cm.sup.2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2015},

  month        = {9}

}

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Composite Anode Active Material, Anode Including the Same and Lithium Battery Using the Anode
patent-application, January 2009

Hwang, Seung-sik; Kim, Han-su
US Patent Application 12/120262; 20090023065
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SI/C Composite, Anode Active Materials, and Lithium Battery Including the Same
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Mah, Sang-kook; Kim, Han-su
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Anode active material hybridizing carbon nanofiber for lithium secondary battery
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Choi, Im Goo; Jang, Seung Yeon; Choi, Namsun
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Nano-Sized Silicon
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Treger, Jack
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Hybrid anode compositions for lithium ion batteries
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Zhamu, Aruna; Jang, Bor Z.
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Carbon-Coated Silicon Particle Powder as the Anode Material for Lithium Ion Batteries and Method of Making the Same
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Mao, Zhenhua; Chahar, Bharat
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Composite for Anode Material, Anode Materials and Lithium Battery Using the Same
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Mah, Sang-kook; Kim, Han-su
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Porous Silicon Particulates for Lithium Batteries
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Tiegs, Terry N.
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Anode and Secondary Battery
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Wakita, Shinya; Okae, Izaya
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Non-Aqueous Electrolyte Secondary Battery, Negative Electrode Material, and Making Method
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Nakanishi, Tetsuo; Watanabe, Koichiro; Fukuoka, Hirofumi
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High Energy Lithium Ion Secondary Batteries
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Buckley, James P.; Kumar, Sujeet
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High Energy Lithium Ion Batteries With Particular Negative Electrode Compositions
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Kumar, Sujeet; Buckley, James P.
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Non-Aqueous Electrolyte Secondary Battery
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Shirane, Takayuki; Inoue, Kaoru; Ugaji, Masaya
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Secondary Battery
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Lim, Wan Mook
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Negative Electrode Material, Making Method, Lithium Ion Secondary Battery, and Electrochemical Capacitor
patent-application, January 2010

Watanabe, Koichiro
US Patent Application 12/501759; 20100009261
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High Energy Density Redox Flow Device
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Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan H.
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Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials
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Venkatachalam, Subramanian; Lopez, Herman; Kumar, Sujeet
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Fluorine Doped Lithium Rich Metal Oxide Positive Electrode Battery Materials With High Specific Capacity and Corresponding Batteries
patent-application, April 2010

Kumar, Sujeet; Lopez, Herman; Venkatachalam, Subramanian
US Patent Application 12/569606; 20100086854
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Negative Electrode Base Member
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Misumi, Koichi; Saito, Koji; Mitsuhiro, Mitsuhiro
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Composite Compositions, Negative Electrodes with Composite Compositions and Corresponding Batteries
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Kumar, Sujeet
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Method of producing prelithiated anodes for secondary lithium ion batteries
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Zhamu, Aruna; Jang, Bor Z.
US Patent Application 12/291689; 20100120179
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Positive Electrode Materials for High Discharge Capacity Lithium Ion Batteries
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Lopez, Herman; Venkatachalam, Subramanian; Kumar, Sujeet
US Patent Application 12/332735; 20100151332
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Layer-By-Layer Assemblies of Carbon-Based Nanostructures and Their Applications in Energy Storage and Generation Devices
patent-application, June 2010

Shao-Horn, Yang; Lee, Seung Woo; Yabuuchi, Naoaki
US Patent Application 12/541305; 20100159366
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Secondary lithium ion battery containing a prelithiated anode
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Zhamu, Aruna; Jang, Bor Z.
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Method of Producing Silicon Oxide, Negative Electrode Active Material for lithium Ion Secondary Battery and Lithium Ion Secondary Battery Using the Same
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Kogetsu, Yasutaka; Ishida, Sumihito
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Negative Electrode Material for Nonaqueous Electrolyte Secondary Battery, Making Method and Lithium Ion Secondary Battery
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Watanabe, Kohichiro; Kashida, Meguru; Fukuoka, Hirofumi
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Negative Electrode Material for Nonaqueous Electrolyte Secondary Battery, Making Method and Lithium Ion Secondary Battery
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Watanabe, Koichiro; Kashida, Meguru; Fukuoka, Hirofumi
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Lithium Secondary Battery with High Energy Density
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Chung, Geun-Chang; Shin, Dong Seok; Kim, Sun Kyu
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Lithium Ion Batteries With Long Cycling Performance
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Kumar, Sujeet; Buckley, James P.; Shi, Hang
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Layer-Layer Lithium Rich Complex Metal Oxides with High Specific Capacity and Excellent Cycling
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Lopez, Herman A.; Venkatachalam, Subramanian; Karthikeyan, Deepak Kumaar Kandasamy
US Patent Application 12/869976; 20110052981
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Lithium Doped Cathode Material
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Venkatachalam, Subramanian; Karthikeyan, Deepak Kumaar Kandasamy; Amiruddin, Shabab
US Patent Application 12/870295; 20110052989
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Metal Oxide Coated Positive Electrode Materials For Lithium-Based Batteries
patent-application, March 2011

Karthikeyan, Deepak; Venkatachalam, Subramanian; Lopez, Herman
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Method of manufacturing high-surface-area silicon
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Mukasyan, Alexander; Mukasyan, Vasiliy; Nersesyan, Mikael
US Patent Application 12/587738; 20110085960
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High Capacity Anode Materials for Lithium Ion Batteries
patent-application, May 2011

Lopez, Heman; Anguchamy, Yogesh; Deng, Haixia
US Patent Application 12/938951; 20110111294
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Coated Positive Electrode Materials For Lithium Ion Batteries
patent-application, May 2011

Lopez, Herman; Venkatachalam, Subramanian; Kandasamy Karthikeyan, Deepak
US Patent Application 12/616226; 20110111298
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Preloading Lithium Ion Cell Components With Lithium
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Cui, Yi; Han, Song; Platshon, Mark
US Patent Application 12/944593; 20110111304
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Lithium Ion Battery With High Voltage Electrolytes And Additives
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Amiruddin, Shabab; Lopez, Herman
US Patent Application 12/630992; 20110136019
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Doped Positive Electrode Active Materials And Lithium Ion Secondary Battery Constructed Therefrom
patent-application, October 2011

Karthikeyan, Deepak; Venkatachalam, Subramanian; Amiruddin, Shabab
US Patent Application 12/753312; 20110244331
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Battery Packs for Vehicles and High Capacity Pouch Secondary Batteries for Incorporation into Compact Battery Packs
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Kumar, Sujeet; Buckley, James P.
US Patent Application 13/195672; 20120028105
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Auxiliary Electrodes For Electrochemical Cells Containing High Capacity Active Materials
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Stefan, Constantin; Fasching, Rainer; Roberts, Gregory
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Very Long Cycling of Lithium Ion Batteries with Lithium Rich Cathode Materials
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Amiruddin, Shabab; Li, Bing; Kumar, Sujeet
US Patent Application 13/213756; 20120056590
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Metal Halide Coatings On Lithium Ion Battery Positive Electrode Materials And Corresponding Batteries
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Venkatachalam, Subramanian; Karthikeyan, Deepak; Lopez, Herman
US Patent Application 12/888131; 20120070725
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High Capacity Battery Electrode Structures
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Liu, Zuqin; Han, Song; Loveness, Ghyrn
US Patent Application 13/277821; 20120070741
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Lithium Ion Batteries With Supplemental Lithium
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Amiruddin, Shabab; Venkatachalam, Subramanian; Li, Bing
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Lithium Ion Batteries with Supplemental Lithium
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Amiruddin, Shabab; Venkatachalam, Subramanian; Li, Bing
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Electrode Active Material, Electrode, And Electricity Storage Device
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Harimoto, Yukinari; Fukui, Hiroshi; Hino, Takakazu
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Silicon Oxide Based High Capacity Anode Materials For Lithium Ion Batteries
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Deng, Haixia; Han, Yongbong; Masarapu, Charan
US Patent Application 13/108708; 20120295155
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Lithium Ion Batteries Based On Nanoporous Silicon
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Tolbert, Sarah; Nemanick, Eric; Kang, Chris Byung-Hwa
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High-performance lithium battery anodes using silicon nanowires
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Chan, Candace K.; Peng, Hailin; Liu, Gao
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High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries
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Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young‐Il
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Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni_0.17Li_0.2Co_0.07Mn_0.56]O₂
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Ito, Atsushi; Li, Decheng; Sato, Yuichi
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A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment
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Kang, Sun-Ho; Thackeray, Michael M.
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Kang, S.-H.; Amine, K.
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Synthesis of spherical Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ as positive electrode material for lithium-ion battery
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Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries
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High capacity Li[Li_0.2Ni_0.2Mn_0.6]O₂ cathode materials via a carbonate co-precipitation method
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Title: Porous silicon based anode material formed using metal reduction

Abstract

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