DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Liquid precursor for deposition of copper selenide and method of preparing the same

Abstract

Liquid precursors containing copper and selenium suitable for deposition on a substrate to form thin films suitable for semiconductor applications are disclosed. Methods of preparing such liquid precursors and methods of depositing a precursor on a substrate are also disclosed.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1214119
Patent Number(s):
9130084
Application Number:
14/026,516
Assignee:
Alliance for Substainable Energy, LLC (Golden, CO)
Patent Classifications (CPCs):
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Sep 13
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Curtis, Calvin J., Miedaner, Alexander, Franciscus Antonius Maria Van Hest, Marinus, Ginley, David S., Hersh, Peter A., Eldada, Louay, and Stanbery, Billy J. Liquid precursor for deposition of copper selenide and method of preparing the same. United States: N. p., 2015. Web.
Curtis, Calvin J., Miedaner, Alexander, Franciscus Antonius Maria Van Hest, Marinus, Ginley, David S., Hersh, Peter A., Eldada, Louay, & Stanbery, Billy J. Liquid precursor for deposition of copper selenide and method of preparing the same. United States.
Curtis, Calvin J., Miedaner, Alexander, Franciscus Antonius Maria Van Hest, Marinus, Ginley, David S., Hersh, Peter A., Eldada, Louay, and Stanbery, Billy J. Tue . "Liquid precursor for deposition of copper selenide and method of preparing the same". United States. https://www.osti.gov/servlets/purl/1214119.
@article{osti_1214119,
title = {Liquid precursor for deposition of copper selenide and method of preparing the same},
author = {Curtis, Calvin J. and Miedaner, Alexander and Franciscus Antonius Maria Van Hest, Marinus and Ginley, David S. and Hersh, Peter A. and Eldada, Louay and Stanbery, Billy J.},
abstractNote = {Liquid precursors containing copper and selenium suitable for deposition on a substrate to form thin films suitable for semiconductor applications are disclosed. Methods of preparing such liquid precursors and methods of depositing a precursor on a substrate are also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 08 00:00:00 EDT 2015},
month = {Tue Sep 08 00:00:00 EDT 2015}
}

Works referenced in this record:

Thin film photovoltaic cells
patent, May 1981


Back contacted MIS photovoltaic cell
patent, February 1982


Equilibrium crystal growth from substrate confined liquid
patent, October 1984


Thin films of mixed metal compounds
patent, June 1985


Optical shield for image sensing device
patent, September 1986


CuInSe.sub.2 thin film solar cell with thin CdS and transparent window layer
patent, September 1986


Apparatus for forming deposited film
patent, June 1987


Deposition of thin films using supercritical fluids
patent, April 1988


Registration of a new cordless telephone to an existing system
patent, September 1989


Computer program for vacuum coating systems
patent, February 1990


Monosubstituted dithiooxamide compounds and their use
patent, June 1992


Heat transfer sheet
patent, June 1992


Direct write with microelectronic circuit fabrication
patent, July 1992


Bilayer oxide film and process for producing same
patent, January 1993


Process of fabricating a semiconductor substrate
patent, April 1995


Multi-phase back contacts for CIS solar cells
patent, December 1995


Camera having trimming function
patent, December 1995


Process for producing chalcopyrite type compound thin film
patent, October 1996


Solar cell with chalcopyrite absorber layer
patent, May 1997


Method for leaching nickel-copper matte employing substantially neutral leaching solutions
patent, May 1997


Process for preparing group Ib-IIIa-VIa semiconducting films
patent, October 1997


Cordless telephone
patent, November 1997


Method of making composite with discontinuous adhesive structure
patent, January 1998


Production of films and powders for semiconductor device applications
patent, March 1998


Method of making color filter arrays by transferring colorant material
patent, May 1998


Transfer member and thermal transfer printing method
patent, June 1998


Headset for hands-free wireless telephone
patent, August 1998


Composite optical and electro-optical devices
patent, December 1998


Thin film solar cell and method for manufacturing the same
patent, January 1999


Black thermal transfer sheet
patent, January 1999


Cadmium-free junction fabrication process for CuInSe.sub.2 thin film solar cells
patent, September 1999


Method of making compound semiconductor films and making related electronic devices
patent, November 1999


Wireless open ear canal earpiece
patent, February 2000


Solar cell and method for manufacturing the same
patent, February 2000


Wireless communication system
patent, February 2000


Semiconductor light emission device
patent, June 2000


Method of manufacturing semiconductor article
patent, August 2000


Solution synthesis of mixed-metal chalcogenide nanoparticles and spray deposition of precursor films
patent, October 2000


Adaptive digital radio communication system
patent, February 2001


Method for attractive bonding of two crystalline substrates
patent, February 2001


Growth of epitaxial semiconductor material with improved crystallographic properties
patent, February 2001


Semiconductor device having triple-well
patent, May 2001


Semiconductor substrate manufacturing method
patent, June 2001


Self-organized formation of quantum dots of a material on a substrate
patent, November 2001


Method of making I-III-VI semiconductor materials for use in photovoltaic cells
patent, November 2001


Cordless phone data transfer
patent, January 2002


Fabrication of thin-film, flexible photovoltaic module
patent, April 2002


Preparation of sulphides and selenides
patent, April 2002


Method of improved copper gap fill
patent, June 2002


Silicon on III-V semiconductor bonding for monolithic optoelectronic integration
patent, September 2002


Preparation of nanocrystallites
patent, June 2003


Copper-based alloy, method for production of the alloy, and products using the alloy
patent, July 2003


Preparation of nanocrystallites
patent, November 2004


Direct printing of thin-film conductors using metal-chelate inks
patent, December 2004


Nano-architected/assembled solar electricity cell
patent, February 2005


Shaped nanocrystal particles and methods for making the same
patent, February 2005


Thin-film solar cells
patent, December 2005


Solvent vapor infiltration of organic materials into nanostructures
patent, January 2006


Hydrazine-free solution deposition of chalcogenide films
patent, August 2006


Self assembled organic nanocrystal superlattices
patent, August 2006


Coated nanoparticles and quantum dots for solution-based fabrication of photovoltaic cells
patent, December 2007


Multicomponent nanorods
patent, September 2008


Solution-based fabrication of photovoltaic cell
patent, February 2010


Conductive inks and manufacturing method thereof
patent, April 2010


Ink for ink jet printing and method for preparing metal nanoparticles used therein
patent, January 2011


Chalcogenide solar cells
patent, November 2011


Method for Forming Particulate Materials
patent-application, January 2002


Solar cell
patent-application, December 2004


Method and apparatus for applying conductive ink onto semiconductor substrates
patent-application, January 2005


Hydrazine-free solution deposition of chalcogenide films
patent-application, January 2005


Light absorbing layer producing method
patent-application, February 2005


Photovoltaic devices fabricated from nanostructured template
patent-application, May 2005


Photovoltaic devices fabricated from insulating nanostructured template
patent-application, May 2005


Photovoltaic Devices Fabricated by Growth from Porous Template
patent-application, June 2005


Solution deposition of chalcogenide films containing transition metals
patent-application, July 2005


Solution-based fabrication of photovoltaic cell
patent-application, August 2005


Formation of CIGS absorber layer materials using atomic layer deposition and high throughput surface treatment
patent-application, August 2005


Coated Nanoparticles and Quantum Dots for Solution-Based Fabrication of Photovoltaic Cells
patent-application, March 2006


Multicomponent nanorods
patent-application, April 2007


Assembly of quasicrystalline photonic heterostructures
patent-application, May 2007


Photovoltaic devices printed from nanostructured particles
patent-application, July 2007


High-throughput printing of semiconductor precursor layer from inter-metallic microflake articles
patent-application, July 2007


High-throughput printing of semiconductor precursor layer by use of chalcogen-containing vapor and inter-metallic material
patent-application, July 2007


High-throughput printing of semiconductor precursor layer from microflake particles
patent-application, July 2007


Bandgap grading in thin-film devices via solid group IIIA particles
patent-application, March 2008


High-Throughput Printing of Semiconductor Precursor Layer from Chalcogenide Microflake Particles
patent-application, May 2008


High-Throughput Printing of Semiconductor Precursor Layer from Chalcogenide Particles
patent-application, May 2008


Solution-Based Fabrication of Photovoltaic Cell
patent-application, June 2008


Thin-film devices formed from solid group IIIA alloy particles
patent-application, July 2008


Precursors for Formation of Copper Selenide, Indium Selenide, Copper Indium Diselenide, and/or Copper Indium Gallium Diselenide Films
patent-application, November 2009


Synthesis of Metal Chalcogenide Nanocrystals Using Organodichalcogenide Reagents
patent-application, January 2011


Methods of making copper selenium precursor compositions with a targeted copper selenide content and precursor compositions and thin films resulting therefrom
patent-application, August 2011


Thin film photovoltaics
journal, February 1996


Toward Sustainable Nanoproducts
journal, June 2008


Role of sodium in the control of defect structures in CIS [solar cells]
conference, January 2000

  • Stanbery, B. J.; Kincal, S.; Kim, S.
  • 28th IEEE Photovoltaic Specialists Conference, Conference Record of the Twenty-Eighth IEEE Photovoltaic Specialists Conference - 2000 (Cat. No.00CH37036)
  • https://doi.org/10.1109/PVSC.2000.915864

Copper Indium Selenides and Related Materials for Photovoltaic Devices
journal, April 2002


The intra-absorber junction (IAJ) model for the device physics of copper indium selenide-based photovoltaics
conference, January 2005


XPS studies of sodium compound formation and surface segregation in CIGS thin films [solar cells]
conference, January 1997


A 15.2% AMO/1433 W/kg thin-film Cu(In,Ga)Se/sub 2/ solar cell for space applications
conference, January 2000

  • Tuttle, J. R.; Szalaj, A.; Keane, J.
  • 28th IEEE Photovoltaic Specialists Conference, Conference Record of the Twenty-Eighth IEEE Photovoltaic Specialists Conference - 2000 (Cat. No.00CH37036)
  • https://doi.org/10.1109/PVSC.2000.916065

Sonochemical synthesis of copper selenides nanocrystals with different phases
journal, January 2002


Chemical fluctuation-induced nanodomains in Cu(In,Ga)Se2 films
journal, September 2005


The Spectroscopy of InSe Nanoparticles
journal, July 2005


Colloidal nanocrystal synthesis and the organic–inorganic interface
journal, September 2005


Influence of sodium on the growth of polycrystalline Cu(In,Ga)Se2 thin films
journal, February 2000


Chemistry and Properties of Nanocrystals of Different Shapes
journal, April 2005


Room Temperature Tailoring of Electrical Properties of Ternary and Multinary Chalcogenide Semiconductors
journal, January 1993


Five-fold symmetry in crystalline quasicrystal lattices
journal, December 1996


Novel Multilayer Process for CuInSe 2 Thin Film Formation by Rapid Thermal Processing
journal, January 1997


Synthesis of CuInGaSe2 nanoparticles by solvothermal route
journal, June 2005


Progress toward 20% efficiency in Cu(In,Ga)Se2 polycrystalline thin-film solar cells
journal, July 1999


Substructure formation during pattern transposition from substrate into polymer blend film
journal, June 2003


Nonvacuum techniques for fabricating thin-film CIGS
conference, January 2000

  • Eberspacher, C.; Pauls, K.; Serra, J.
  • 28th IEEE Photovoltaic Specialists Conference, Conference Record of the Twenty-Eighth IEEE Photovoltaic Specialists Conference - 2000 (Cat. No.00CH37036)
  • https://doi.org/10.1109/PVSC.2000.915885

Microwave-Assisted Polyol Synthesis of CuInTe 2 and CuInSe 2 Nanoparticles
journal, November 2003


Reaction Pathways to CuInSe[sub 2] Formation from Electrodeposited Precursors
journal, January 1995


Evaluation and characterization of polycrystalline CuInSe 2 thin films prepared by the sandwich structure technique
journal, June 1994


Formation of Decagonal Quasicrystal in the Al-Pd-Mn System and Its Structure
journal, September 1991


Catalyzed Growth of a Metastable InS Crystal Structure as Colloidal Crystals
journal, April 2000

  • Hollingsworth, Jennifer A.; Poojary, Damadora M.; Clearfield, Abraham
  • Journal of the American Chemical Society, Vol. 122, Issue 14, p. 3562-3563
  • https://doi.org/10.1021/ja000106u

Electroluminescent properties of device based on ZnS:Tb/CdS core-shell nanocrystals
journal, February 2006


Elemental Solvothermal Reaction To Produce Ternary Semiconductor CuInE 2 (E = S, Se) Nanorods
journal, July 2000


Thin‐film CuInSe 2 /CdS heterojunction solar cells
journal, August 1976


Influence of Na on the electro-optical properties of Cu(In,Ga)Se/sub 2/
conference, January 1997


Shape Control of II–VI Semiconductor Nanomaterials
journal, March 2006


Characteristics of indium phosphide solar cells bonded on silicon
conference, January 1993


Field‐assisted bonding below 200 °C using metal and glass thin‐film interlayers
journal, March 1987


Effects of buffer layer processing on CIGS excess carrier lifetime: application of dual-beam optical modulation to process analysis [of solar cells]
conference, January 1996


Sonochemical process for the preparation of α-CuSe nanocrystals and flakes
journal, January 2002


Atmospheric pressure synthesis of In 2 Se 3 , Cu 2 Se, and CuInSe 2 without external selenization from solution precursors
journal, April 2009


Hydrazine-based deposition route for device-quality CIGS films
journal, February 2009


Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
journal, August 2000


Direct cover glass bonding to GaAs and GaAs/Ge solar cells
conference, January 1991


Phase-Controlled One-Dimensional Shape Evolution of InSe Nanocrystals
journal, November 2006


Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility
journal, July 1997

  • Peng, Xiaogang; Schlamp, Michael C.; Kadavanich, Andreas V.
  • Journal of the American Chemical Society, Vol. 119, Issue 30, p. 7019-7029
  • https://doi.org/10.1021/ja970754m

Triangular CdS Nanocrystals: Structural and Optical Studies
journal, February 2001


Advanced Stacked Elemental Layer Process for Cu(InGa)Se 2 Thin Film Photovoltaic Devices
journal, January 1996


Rapid CIS-process for high efficiency PV-modules: development towards large area processing
journal, May 2001


The impact of controlled sodium incorporation on rapid thermal processed Cu(InGa)Se/sub 2/-thin films and devices
conference, January 1994

  • Probst, V.; Rimmasch, J.; Riedl, W.
  • Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)
  • https://doi.org/10.1109/WCPEC.1994.519828

The Effect of Organic Ligand Binding on the Growth of CdSe Nanoparticles Probed by Ab Initio Calculations
journal, December 2004


Rapid thermal processing of CIS precursors
conference, January 2002

  • Kerr, L. L.; Kim, S.; Kincal, S.
  • Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference 2002, Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference, 2002.
  • https://doi.org/10.1109/PVSC.2002.1190655

CIGS films via nanoparticle spray deposition: attempts at densifying a porous precursor
conference, January 1997


Reaction engineering and precursor film deposition for CIS synthesis
conference, January 1997

  • Stanbery, B. J.; Davydov, A.; Chang, C. H.
  • National renewable energy laboratory and sandia national laboratories photovoltaics program review meeting, AIP Conference Proceedings
  • https://doi.org/10.1063/1.52863

Assembly of conducting polymer/ metal oxide multilayer in one step
journal, June 1999