High capacity carbon dioxide sorbent
Abstract
The present invention provides a sorbent for the removal of carbon dioxide from gas streams, comprising: a CO.sub.2 capacity of at least 9 weight percent when measured at 22.degree. C. and 1 atmosphere; an H.sub.2O capacity of at most 15 weight percent when measured at 25.degree. C. and 1 atmosphere; and an isosteric heat of adsorption of from 5 to 8.5 kilocalories per mole of CO.sub.2. The invention also provides a carbon sorbent in a powder, a granular or a pellet form for the removal of carbon dioxide from gas streams, comprising: a carbon content of at least 90 weight percent; a nitrogen content of at least 1 weight percent; an oxygen content of at most 3 weight percent; a BET surface area from 50 to 2600 m.sup.2/g; and a DFT micropore volume from 0.04 to 0.8 cc/g.
- Inventors:
- Issue Date:
- Research Org.:
- TDA Research, Inc., Wheat Ridge, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1213459
- Patent Number(s):
- 9120079
- Application Number:
- 14/217,218
- Assignee:
- TDA Research, Inc. (Wheat Ridge, CO)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- SC0006239
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Mar 17
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES
Citation Formats
Dietz, Steven Dean, Alptekin, Gokhan, and Jayaraman, Ambalavanan. High capacity carbon dioxide sorbent. United States: N. p., 2015.
Web.
Dietz, Steven Dean, Alptekin, Gokhan, & Jayaraman, Ambalavanan. High capacity carbon dioxide sorbent. United States.
Dietz, Steven Dean, Alptekin, Gokhan, and Jayaraman, Ambalavanan. Tue .
"High capacity carbon dioxide sorbent". United States. https://www.osti.gov/servlets/purl/1213459.
@article{osti_1213459,
title = {High capacity carbon dioxide sorbent},
author = {Dietz, Steven Dean and Alptekin, Gokhan and Jayaraman, Ambalavanan},
abstractNote = {The present invention provides a sorbent for the removal of carbon dioxide from gas streams, comprising: a CO.sub.2 capacity of at least 9 weight percent when measured at 22.degree. C. and 1 atmosphere; an H.sub.2O capacity of at most 15 weight percent when measured at 25.degree. C. and 1 atmosphere; and an isosteric heat of adsorption of from 5 to 8.5 kilocalories per mole of CO.sub.2. The invention also provides a carbon sorbent in a powder, a granular or a pellet form for the removal of carbon dioxide from gas streams, comprising: a carbon content of at least 90 weight percent; a nitrogen content of at least 1 weight percent; an oxygen content of at most 3 weight percent; a BET surface area from 50 to 2600 m.sup.2/g; and a DFT micropore volume from 0.04 to 0.8 cc/g.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {9}
}
Works referenced in this record:
Reactivation of Monoethanolamine Impregnated Activate Carbon
patent, June 1970
- Stoneburner, George R.
- US Patent Document 3491031
Carbon dioxide removal using aminated carbon molecular sieves
patent, March 1989
- Zinnen, Hermann A.; Oroskar, Anil R.; Chang, Chin-Hsiung
- US Patent Document 4,810,266
Regenerable supported amine-polyol sorbent
patent, December 1994
- Birbara, Philip J.; Nalette, Timothy A.
- US Patent Document 5,376,614
Regenerable supported amine-polyol sorbent
patent, February 1996
- Birbara, Philip J.; Nalette, Timothy A.
- US Patent Document 5,492,683
Process for forming a regenerable supported amine-polyol sorbent
patent, April 1997
- Birbara, Philip J.; Nalette, Timothy A.
- US Patent Document 5,620,940
Regenerable solid amine sorbent
patent, March 1999
- Birbara, Philip J.; Filburn, Thomas P.; Nalette, Timothy A.
- US Patent Document 5,876,488
Sorbent system and method for absorbing carbon dioxide (CO2) from the atmosphere of a closed habitable environment
patent, April 2002
- Birbara, Philip J.; Filburn, Thomas P.; Michels, H. Harvey
- US Patent Document 6,364,938
Amine enriched solid sorbents for carbon dioxide capture
patent, April 2003
- Gray, McMahan L.; Soong, Yee; Champagne, Kenneth J.
- US Patent Document 6,547,854
High capacity immobilized amine sorbents
patent, October 2007
- Gray, McMahan L.; Champagne, Kenneth J.; Soong, Yee
- US Patent Document 7,288,136
Porous carbons from carbohydrates
patent, June 2009
- Dietz, Steven; Recla, Dean
- US Patent Document 7,541,312
Mesoporous Carbon Materials Comprising Bifunctional Catalysts
patent-application, September 2011
- Feaver, Aaron M.; Costantino, Henry R.; Varjian, Richard D.
- US Patent Document 13/046572; 20110223494
Characterization and application of activated carbon produced by H3PO4 and water vapor activation
journal, October 2006
- Budinova, T.; Ekinci, E.; Yardim, F.
- Fuel Processing Technology, Vol. 87, Issue 10, p. 899-905
Effects of activated carbon surface chemistry and pore structure on the adsorption of organic contaminants from aqueous solution
journal, January 2002
- Li, Lei; Quinlivan, Patricia A.; Knappe, Detlef R. U.
- Carbon, Vol. 40, Issue 12, p. 2085-2100
Adsorption of CO 2 on Activated Carbon: Simultaneous Determination of Integral Heat and Isotherm of Adsorption
journal, January 1996
- Berlier, Karl; Frère, Marc
- Journal of Chemical & Engineering Data, Vol. 41, Issue 5
A new model for calculating the adsorption equilibrium constant of water vapor in micropores of activated carbon
journal, June 2014
- Yao, Xiaolong; Li, Liqing; Li, Hailong
- Computational Materials Science, Vol. 89, p. 137-141