Silicon nanocrystal inks, films, and methods
Abstract
Silicon nanocrystal inks and films, and methods of making and using silicon nanocrystal inks and films, are disclosed herein. In certain embodiments the nanocrystal inks and films include halide-terminated (e.g., chloride-terminated) and/or halide and hydrogen-terminated nanocrystals of silicon or alloys thereof. Silicon nanocrystal inks and films can be used, for example, to prepare semiconductor devices.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1213437
- Patent Number(s):
- 9123538
- Application Number:
- 13/870,554
- Assignee:
- Regents of the University of Minnesota (Minneapolis, MN)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Apr 25
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Wheeler, Lance Michael, and Kortshagen, Uwe Richard. Silicon nanocrystal inks, films, and methods. United States: N. p., 2015.
Web.
Wheeler, Lance Michael, & Kortshagen, Uwe Richard. Silicon nanocrystal inks, films, and methods. United States.
Wheeler, Lance Michael, and Kortshagen, Uwe Richard. Tue .
"Silicon nanocrystal inks, films, and methods". United States. https://www.osti.gov/servlets/purl/1213437.
@article{osti_1213437,
title = {Silicon nanocrystal inks, films, and methods},
author = {Wheeler, Lance Michael and Kortshagen, Uwe Richard},
abstractNote = {Silicon nanocrystal inks and films, and methods of making and using silicon nanocrystal inks and films, are disclosed herein. In certain embodiments the nanocrystal inks and films include halide-terminated (e.g., chloride-terminated) and/or halide and hydrogen-terminated nanocrystals of silicon or alloys thereof. Silicon nanocrystal inks and films can be used, for example, to prepare semiconductor devices.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {9}
}
Works referenced in this record:
Low temperature thin films formed from nanocrystal precursors
patent, November 1993
- Alivisatos, A. Paul; Goldstein, Avery N.
- US Patent Document 5,262,357
Group IV semiconductor thin films formed at low temperature using nanocrystal precursors
patent, November 1996
- Goldstein, Avery N.
- US Patent Document 5,576,248
Process and apparatus for forming nanoparticles using radiofrequency plasmas
patent, November 2008
- Kortshagen, Uwe; Thimsen, Elijah J.; Mangolini, Lorenzo
- US Patent Document 7,446,335
Process and apparatus for forming nanoparticles using radiofrequency plasmas
patent, September 2011
- Kortshagen, Uwe; Thimsen, Elijah J.; Mangolini, Lorenzo
- US Patent Document 8,016,944
Nanostructured material comprising semiconductor nanocrystal complexes for use in solar cell and method of making a solar cell comprising nanostructured material
patent-application, January 2007
-
LoCascio,
- US Patent Application 11/484778; 20070012355
Nanocrystal Solar Cells Processed From Solution
patent-application, September 2009
- Alivisatos, Paul A.; Gur, Ilan; Milliron, Delia
- US Patent Application 12/083723; 20090217973
Routes to Achieving High Quantum Yield Luminescence from Gas-Phase-Produced Silicon Nanocrystals
journal, August 2011
- Anthony, Rebecca J.; Rowe, David J.; Stein, Matthias
- Advanced Functional Materials, Vol. 21, Issue 21
Assembly of Organic Molecules on Silicon Surfaces via the Si−N Linkage
journal, January 1999
- Bergerson, W. F.; Mulder, J. A.; Hsung, R. P.
- Journal of the American Chemical Society, Vol. 121, Issue 2
Carrier transport in thin films of silicon nanoparticles
journal, August 1997
- Burr, T. A.; Seraphin, A. A.; Werwa, E.
- Physical Review B, Vol. 56, Issue 8
Wet chemical routes to the assembly of organic monolayers on silicon surfaces via the formation of Si–C bonds: surface preparation, passivation and functionalization
journal, January 2010
- Ciampi, Simone; Harper, Jason B.; Gooding, J. Justin
- Chemical Society Reviews, Vol. 39, Issue 6
Raman spectral studies of ion association and solvation in solutions of LiAsF 6 –acetone
journal, January 1992
- Deng, Zhongyi; Irish, Donald E.
- J. Chem. Soc., Faraday Trans., Vol. 88, Issue 19
Creating Ligand-Free Silicon Germanium Alloy Nanocrystal Inks
journal, September 2011
- Erogbogbo, Folarin; Liu, Tianhang; Ramadurai, Nithin
- ACS Nano, Vol. 5, Issue 10
Solvent-induced frequency shifts in the infrared spectrum of acetonitrile in organic solvents
journal, September 1993
- Fawcett, W. Ronald; Liu, Guojun; Kessler, Tori E.
- The Journal of Physical Chemistry, Vol. 97, Issue 37, p. 9293-9298
The Origins of Hydration Forces: Monte Carlo Simulations and Density Functional Theory
journal, October 1997
- Forsman, Jan; Woodward, Clifford E.; Jönsson, Bo
- Langmuir, Vol. 13, Issue 20
A Nanostructured Porous Silicon Near Insulator Becomes Either a p- or an n-Type Semiconductor upon Gas Adsorption
journal, March 2005
- Garrone, E.; Geobaldo, F.; Rivolo, P.
- Advanced Materials, Vol. 17, Issue 5, p. 528-531
Nonthermal plasma synthesis of size-controlled, monodisperse, freestanding germanium nanocrystals
journal, August 2007
- Gresback, Ryan; Holman, Zachary; Kortshagen, Uwe
- Applied Physics Letters, Vol. 91, Issue 9
Nanocrystalline silicon as intrinsic layer in thin film solar cells
journal, December 1998
- Hazra, Sukti; Ray, Swati
- Solid State Communications, Vol. 109, Issue 2, p. 125-128
Nanocrystal Inks without Ligands: Stable Colloids of Bare Germanium Nanocrystals
journal, May 2011
- Holman, Zachary C.; Kortshagen, Uwe R.
- Nano Letters, Vol. 11, Issue 5
Germanium and Silicon Nanocrystal Thin-Film Field-Effect Transistors from Solution
journal, July 2010
- Holman, Zachary C.; Liu, Chin-Yi; Kortshagen, Uwe R.
- Nano Letters, Vol. 10, Issue 7
A flexible method for depositing dense nanocrystal thin films: impaction of germanium nanocrystals
journal, July 2010
- Holman, Z. C.; Kortshagen, U. R.
- Nanotechnology, Vol. 21, Issue 33
Solution-Processed Germanium Nanocrystal Thin Films as Materials for Low-Cost Optical and Electronic Devices
journal, October 2009
- Holman, Zachary C.; Kortshagen, Uwe R.
- Langmuir, Vol. 25, Issue 19
Infrared matrix isolation studies of molecular interactions: complexes of trichlorosilane, HSiCl3, with selected bases
journal, February 1990
- Jeng, Mei Lee H.; Ault, Bruce S.
- Inorganic Chemistry, Vol. 29, Issue 4
Silicon nanocrystals with ensemble quantum yields exceeding 60%
journal, June 2006
- Jurbergs, David; Rogojina, Elena; Mangolini, Lorenzo
- Applied Physics Letters, Vol. 88, Issue 23
Nonthermal plasma synthesis of semiconductor nanocrystals
journal, May 2009
- Kortshagen, Uwe
- Journal of Physics D: Applied Physics, Vol. 42, Issue 11
Colloidal Nanocrystals with Molecular Metal Chalcogenide Surface Ligands
journal, June 2009
- Kovalenko, M. V.; Scheele, M.; Talapin, D. V.
- Science, Vol. 324, Issue 5933
Structural, Optical, and Electrical Properties of PbSe Nanocrystal Solids Treated Thermally or with Simple Amines
journal, May 2008
- Law, Matt; Luther, Joseph M.; Song, Qing
- Journal of the American Chemical Society, Vol. 130, Issue 18
Interaction forces between colloidal particles in liquid: Theory and experiment
journal, October 2007
- Liang, Yuncheng; Hilal, Nidal; Langston, Paul
- Advances in Colloid and Interface Science, Vol. 134-135, p. 151-166
Surface chemistry dependence of native oxidation formation on silicon nanocrystals
journal, September 2009
- Liptak, R. W.; Kortshagen, U.; Campbell, S. A.
- Journal of Applied Physics, Vol. 106, Issue 6
Robust, Functional Nanocrystal Solids by Infilling with Atomic Layer Deposition
journal, December 2011
- Liu, Yao; Gibbs, Markelle; Perkins, Craig L.
- Nano Letters, Vol. 11, Issue 12, p. 5349-5355
Hybrid Solar Cells from P3HT and Silicon Nanocrystals
journal, January 2009
- Liu, Chin-Yi; Holman, Zachary C.; Kortshagen, Uwe R.
- Nano Letters, Vol. 9, Issue 1
Plasma-Assisted Synthesis of Silicon Nanocrystal Inks
journal, September 2007
- Mangolini, L.; Kortshagen, U.
- Advanced Materials, Vol. 19, Issue 18, p. 2513-2519
High-Yield Plasma Synthesis of Luminescent Silicon Nanocrystals
journal, April 2005
- Mangolini, L.; Thimsen, E.; Kortshagen, U.
- Nano Letters, Vol. 5, Issue 4
Electronic Structure of Silicon Nanocrystals Passivated with Nitrogen and Chlorine
journal, June 2010
- Martínez, Ana; Alonso, Juan C.; Sansores, Luis. E.
- The Journal of Physical Chemistry C, Vol. 114, Issue 29
13C NMR estimation of preferential solvation of lithium ions in non-aqueous mixed solvents
journal, January 1998
- Matsubara, Koshi; Kaneuchi, Rie; Maekita, Noriko
- Journal of the Chemical Society, Faraday Transactions, Vol. 94, Issue 24
Self-Organization of CdSe Nanocrystallites into Three-Dimensional Quantum Dot Superlattices
journal, November 1995
- Murray, C. B.; Kagan, C. R.; Bawendi, M. G.
- Science, Vol. 270, Issue 5240
Metal-free Inorganic Ligands for Colloidal Nanocrystals: S2–, HS–, Se2–, HSe–, Te2–, HTe–, TeS32–, OH–, and NH2– as Surface Ligands
journal, July 2011
- Nag, Angshuman; Kovalenko, Maksym V.; Lee, Jong-Soo
- Journal of the American Chemical Society, Vol. 133, Issue 27, p. 10612-10620
Infrared Studies of Ketones: Parameters Affecting the Induced Carbonyl Stretching Vibration by Solute/Solvent Interaction
journal, March 1990
- Nyquist, Richard A.
- Applied Spectroscopy, Vol. 44, Issue 3
Reaction Chemistry and Ligand Exchange at Cadmium−Selenide Nanocrystal Surfaces
journal, September 2008
- Owen, Jonathan S.; Park, Jungwon; Trudeau, Paul-Emile
- Journal of the American Chemical Society, Vol. 130, Issue 37
Hydrodynamic Dimensions, Electrophoretic Mobility, and Stability of Hydrophilic Quantum Dots
journal, October 2006
- Pons, Thomas; Uyeda, H. Tetsuo; Medintz, Igor L.
- The Journal of Physical Chemistry B, Vol. 110, Issue 41
Gas phase chlorination of hydrogen-passivated silicon surfaces
journal, September 2004
- Rivillon, Sandrine; Amy, Fabrice; Chabal, Yves J.
- Applied Physics Letters, Vol. 85, Issue 13
Chemistry of Silicon Nanocrystal Surfaces Exposed to Ammonia
journal, March 2010
- Salivati, Navneethakrishnan; Shuall, Nimrod; McCrate, Joseph M.
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
Effect of Surface Chemistry on Quantum Confinement and Photoluminescence of Ammonia-Passivated Silicon Nanocrystals
journal, June 2010
- Salivati, Navneethakrishnan; Shuall, Nimrod; McCrate, Joseph M.
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 13
Understanding the Stabilization of Liquid-Phase-Exfoliated Graphene in Polar Solvents: Molecular Dynamics Simulations and Kinetic Theory of Colloid Aggregation
journal, October 2010
- Shih, Chih-Jen; Lin, Shangchao; Strano, Michael S.
- Journal of the American Chemical Society, Vol. 132, Issue 41
Free charge carriers in mesoporous silicon
journal, August 2001
- Timoshenko, V. Yu.; Dittrich, Th.; Lysenko, V.
- Physical Review B, Vol. 64, Issue 8
Surface nitridation of silicon nano-particles using double multi-hollow discharge plasma CVD
journal, July 2011
- Uchida, Giichiro; Yamamoto, Kosuke; Kawashima, Yuki
- physica status solidi (c), Vol. 8, Issue 10
Intrinsic microcrystalline silicon: A new material for photovoltaics
journal, April 2000
- Vetterl, O.; Finger, F.; Carius, R.
- Solar Energy Materials and Solar Cells, Vol. 62, Issue 1-2, p. 97-108
Hypervalent surface interactions for colloidal stability and doping of silicon nanocrystals
journal, July 2013
- Wheeler, Lance M.; Neale, Nathan R.; Chen, Ting
- Nature Communications, Vol. 4, Article No. 2197
The electronic conduction mechanism of hydrogenated nanocrystalline silicon films
conference, January 1995
- Mingbin Yu,
- Proceedings of 4th International Conference on Solid-State and IC Technology
Effect of Nitrogen on the Stability of Silicon Nanocrystals Produced by Decomposition of Alkyl Silanes
journal, March 2008
- Zaitseva, Natalia; Hamel, Sebastien; Dai, Zu Rong
- The Journal of Physical Chemistry C, Vol. 112, Issue 10