Rapid synthesis of beta zeolites

Fan, Wei; Chang, Chun -Chih; Dornath, Paul; Wang, Zhuopeng

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Title: Rapid synthesis of beta zeolites

Abstract

The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.

Inventors:: Fan, Wei; Chang, Chun -Chih; Dornath, Paul; Wang, Zhuopeng

Issue Date:: 2015-08-18

Research Org.:: University of Massachusetts, Boston, MA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1210887

Patent Number(s):: 9108190

Application Number:: 14/025,557

Assignee:: University of Massachusetts (Boston, MA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2229/16 - to increase the Si/Al ratio
B01J2229/183 - in framework positions
B01J29/035 - {Microporous crystalline materials not having base exchange properties, such as} silica polymorphs, e.g. silicalites
B01J29/7007 - {Zeolite Beta}
B01J29/7057 - {Zeolite Beta}
B01J29/7615 - {Zeolite Beta}
B01J29/88 - Ferrosilicates
B01J29/89 - Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium {

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B37/005 - {Silicates, i.e. so-called metallosilicalites or metallozeosilites}
C01B39/06 - Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements {, i.e. by direct or secondary synthesis}
C01B39/065 - {Galloaluminosilicates
C01B39/085 - {Group IVB- metallosilicates}
C01B39/087 - {Ferrosilicates}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D307/50 - Preparation from natural products

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07H - SUGARS
C07H1/00 - Processes for the preparation of sugar derivatives

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DOE Contract Number:: SC0001004

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Sep 12

Country of Publication:: United States

Language:: English

Subject:: 09 BIOMASS FUELS; 10 SYNTHETIC FUELS

Citation Formats


                    Fan, Wei, Chang, Chun -Chih, Dornath, Paul, and Wang, Zhuopeng. Rapid synthesis of beta zeolites.  United States: N. p., 2015. 
        Web.

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                    Fan, Wei, Chang, Chun -Chih, Dornath, Paul, & Wang, Zhuopeng. Rapid synthesis of beta zeolites.  United States.

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                    Fan, Wei, Chang, Chun -Chih, Dornath, Paul, and Wang, Zhuopeng. Tue .  
        "Rapid synthesis of beta zeolites".  United States.  https://www.osti.gov/servlets/purl/1210887.

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@article{osti_1210887,

  title        = {Rapid synthesis of beta zeolites},

  author       = {Fan, Wei and Chang, Chun -Chih and Dornath, Paul and Wang, Zhuopeng},

  abstractNote = {The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2015},

  month        = {8}

}

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Works referenced in this record:

High silica faujasite aluminosilicate, ECR-4, and a process for making it
patent, October 1990

Vaughan, David E. W.
US Patent Document 4,965,059
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Substituted aluminosilicate compositions and process for preparing
patent, December 1993

Skeels, Gary W.; Ramos, Richard
US Patent Document 5,271,761
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Stannosilicate molecular sieves
patent, October 1999

Valencia, Susana; Canos, Avelino Corma
US Patent Document 5,968,473
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5968473

Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta
patent, February 2001

Nemeth, Laszlo T.; Canos, Avelino Corma; Valencia, Susana
US Patent Document 6,191,323
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6191323

Zeolite compositions and preparation and use thereof
patent, April 2011

Vermeiren, Walter; Dath, Jean-Pierre; Buono, Valérie
US Patent Document 7,922,995
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7922995

Method for synthesizing all-silica zeolite beta with small crystal size
patent, June 2012

Wang, Yu; Tsai, Chien-Hsun; Tsai, Chi-Hsing
US Patent Document 8,206,683
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8206683

Isomerization of Sugars
patent-application, August 2011

Moliner-Marin, Manuel; Roman-Leshkov, Yuriy; Davis, Mark E.
US Patent Application 13/007389; 20110207923
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110207923

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

Corma, Avelino; Nemeth, Laszlo T.; Renz, Michael
Nature, Vol. 412, Issue 6845
https://doi.org/10.1038/35086546

Water-resistant solid Lewis acid catalysts: Meerwein–Ponndorf–Verley and Oppenauer reactions catalyzed by tin-beta zeolite
journal, April 2003

Corma, A.
Journal of Catalysis, Vol. 215, Issue 2
https://doi.org/10.1016/S0021-9517(03)00014-9

Tin-containing zeolite for the isomerization of cellulosic sugars
journal, May 2012

Lew, Christopher M.; Rajabbeigi, Nafiseh; Tsapatsis, Michael
Microporous and Mesoporous Materials, Vol. 153, p. 55-58
https://doi.org/10.1016/j.micromeso.2011.12.020

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
https://doi.org/10.1073/pnas.1002358107

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Similar Records

Title: Rapid synthesis of beta zeolites

Abstract

Citation Formats

High silica faujasite aluminosilicate, ECR-4, and a process for making it patent, October 1990

Substituted aluminosilicate compositions and process for preparing patent, December 1993

Stannosilicate molecular sieves patent, October 1999

Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta patent, February 2001

Zeolite compositions and preparation and use thereof patent, April 2011

Method for synthesizing all-silica zeolite beta with small crystal size patent, June 2012

Isomerization of Sugars patent-application, August 2011

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations journal, July 2001

Water-resistant solid Lewis acid catalysts: Meerwein–Ponndorf–Verley and Oppenauer reactions catalyzed by tin-beta zeolite journal, April 2003

Tin-containing zeolite for the isomerization of cellulosic sugars journal, May 2012

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water journal, March 2010

High silica faujasite aluminosilicate, ECR-4, and a process for making it
patent, October 1990

Substituted aluminosilicate compositions and process for preparing
patent, December 1993

Stannosilicate molecular sieves
patent, October 1999

Process for the reduction of ketones and aldehydes to alcohols using a tin substituted zeolite beta
patent, February 2001

Zeolite compositions and preparation and use thereof
patent, April 2011

Method for synthesizing all-silica zeolite beta with small crystal size
patent, June 2012

Isomerization of Sugars
patent-application, August 2011

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

Water-resistant solid Lewis acid catalysts: Meerwein–Ponndorf–Verley and Oppenauer reactions catalyzed by tin-beta zeolite
journal, April 2003

Tin-containing zeolite for the isomerization of cellulosic sugars
journal, May 2012

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010