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Title: Method for conducting nonlinear electrochemical impedance spectroscopy

Abstract

A method for conducting nonlinear electrochemical impedance spectroscopy. The method includes quantifying the nonlinear response of an electrochemical system by measuring higher-order current or voltage harmonics generated by moderate-amplitude sinusoidal current or voltage perturbations. The method involves acquisition of the response signal followed by time apodization and fast Fourier transformation of the data into the frequency domain, where the magnitude and phase of each harmonic signal can be readily quantified. The method can be implemented on a computer as a software program.

Inventors:
; ; ;
Issue Date:
Research Org.:
Univ. of Washington, Seattle, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1183352
Patent Number(s):
9,046,463
Application Number:
11/408,594
Assignee:
University of Washington (Seattle, WA)
DOE Contract Number:  
FC26-02NT41566
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 97 MATHEMATICS AND COMPUTING

Citation Formats

Adler, Stuart B., Wilson, Jamie R., Huff, Shawn L., and Schwartz, Daniel T. Method for conducting nonlinear electrochemical impedance spectroscopy. United States: N. p., 2015. Web.
Adler, Stuart B., Wilson, Jamie R., Huff, Shawn L., & Schwartz, Daniel T. Method for conducting nonlinear electrochemical impedance spectroscopy. United States.
Adler, Stuart B., Wilson, Jamie R., Huff, Shawn L., and Schwartz, Daniel T. Tue . "Method for conducting nonlinear electrochemical impedance spectroscopy". United States. https://www.osti.gov/servlets/purl/1183352.
@article{osti_1183352,
title = {Method for conducting nonlinear electrochemical impedance spectroscopy},
author = {Adler, Stuart B. and Wilson, Jamie R. and Huff, Shawn L. and Schwartz, Daniel T.},
abstractNote = {A method for conducting nonlinear electrochemical impedance spectroscopy. The method includes quantifying the nonlinear response of an electrochemical system by measuring higher-order current or voltage harmonics generated by moderate-amplitude sinusoidal current or voltage perturbations. The method involves acquisition of the response signal followed by time apodization and fast Fourier transformation of the data into the frequency domain, where the magnitude and phase of each harmonic signal can be readily quantified. The method can be implemented on a computer as a software program.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {6}
}

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Works referenced in this record:

Corrosion rate measurements by non-linear electrochemical impedance spectroscopy
journal, June 1995


Nonlinear Dynamics of Limiting Current in the Flow-Modulated Uniform-Injection Cell
journal, January 1997

  • Medina, J. Antonio
  • Journal of The Electrochemical Society, Vol. 144, Issue 1
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Full-spectrum nonlinear response of a sinusoidally modulated rotating disk electrode
journal, June 2005

  • Wilson, Jamie R.; Adler, Stuart B.; Schwartz, Daniel T.
  • Physics of Fluids, Vol. 17, Issue 6
  • DOI: 10.1063/1.1920547

Nonlinear electrochemical impedance spectroscopy for solid oxide fuel cell cathode materials
journal, January 2006