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Title: Nanomaterials for sodium-ion batteries

Abstract

A crystalline nanowire and method of making a crystalline nanowire are disclosed. The method includes dissolving a first nitrate salt and a second nitrate salt in an acrylic acid aqueous solution. An initiator is added to the solution, which is then heated to form polyacrylatyes. The polyacrylates are dried and calcined. The nanowires show high reversible capacity, enhanced cycleability, and promising rate capability for a battery or capacitor.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1179028
Patent Number(s):
9,023,529
Application Number:
13/474,963
Assignee:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 May 18
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Liu, Jun, Cao, Yuliang, Xiao, Lifen, Yang, Zhenguo, Wang, Wei, Choi, Daiwon, and Nie, Zimin. Nanomaterials for sodium-ion batteries. United States: N. p., 2015. Web.
Liu, Jun, Cao, Yuliang, Xiao, Lifen, Yang, Zhenguo, Wang, Wei, Choi, Daiwon, & Nie, Zimin. Nanomaterials for sodium-ion batteries. United States.
Liu, Jun, Cao, Yuliang, Xiao, Lifen, Yang, Zhenguo, Wang, Wei, Choi, Daiwon, and Nie, Zimin. Tue . "Nanomaterials for sodium-ion batteries". United States. https://www.osti.gov/servlets/purl/1179028.
@article{osti_1179028,
title = {Nanomaterials for sodium-ion batteries},
author = {Liu, Jun and Cao, Yuliang and Xiao, Lifen and Yang, Zhenguo and Wang, Wei and Choi, Daiwon and Nie, Zimin},
abstractNote = {A crystalline nanowire and method of making a crystalline nanowire are disclosed. The method includes dissolving a first nitrate salt and a second nitrate salt in an acrylic acid aqueous solution. An initiator is added to the solution, which is then heated to form polyacrylatyes. The polyacrylates are dried and calcined. The nanowires show high reversible capacity, enhanced cycleability, and promising rate capability for a battery or capacitor.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {5}
}

Patent:

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Works referenced in this record:

Formation of Na0.44MnO2 nanowires via stress-induced splitting of birnessite nanosheets
journal, January 2009


Na4Mn9O18 as a positive electrode material for an aqueous electrolyte sodium-ion energy storage device
journal, March 2010


Structural and Electrochemical Characterization of Nanocrystalline Li[Li 0.12 Ni 0.32 Mn 0.56 ]O 2 Synthesized by a Polymer-Pyrolysis Route
journal, January 2005

  • Yu, Lihong; Yang, Hanxi; Ai, Xinping
  • The Journal of Physical Chemistry B, Vol. 109, Issue 3
  • DOI: 10.1021/jp0464369

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
journal, September 2007

  • Ellis, B. L.; Makahnouk, W. R. M.; Makimura, Y.
  • Nature Materials, Vol. 6, Issue 10
  • DOI: 10.1038/nmat2007

Synthesis and characterization of high-temperature hexagonal P2-Na0.6 MnO2 and its electrochemical behaviour as cathode in sodium cells
journal, February 2002

  • Caballero, A.; Hernán, L.; Morales, J.
  • Journal of Materials Chemistry, Vol. 12, Issue 4
  • DOI: 10.1039/b108830k

Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011

  • Kim, Donghan; Kang, Sun-Ho; Slater, Michael
  • Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336
  • DOI: 10.1002/aenm.201000061

High Capacity Anode Materials for Rechargeable Sodium-Ion Batteries
journal, January 2000

  • Stevens, D. A.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 147, Issue 4
  • DOI: 10.1149/1.1393348

Study of the Insertion/Deinsertion Mechanism of Sodium into Na 0.44 MnO 2
journal, April 2007

  • Sauvage, F.; Laffont, L.; Tarascon, J. -M.
  • Inorganic Chemistry, Vol. 46, Issue 8
  • DOI: 10.1021/ic0700250

Ionothermal Synthesis of Sodium-Based Fluorophosphate Cathode Materials
journal, January 2009

  • Recham, N.; Chotard, J-N.; Dupont, L.
  • Journal of The Electrochemical Society, Vol. 156, Issue 12
  • DOI: 10.1149/1.3236480

Synthesis and Electrochemical Insertion Properties of the Layered Li[sub x]MoO[sub 2] Phases (x = 0.74, 0.85, and 1.00)
journal, January 2003

  • Barker, J.; Saidi, M. Y.; Swoyer, J. L.
  • Electrochemical and Solid-State Letters, Vol. 6, Issue 12
  • DOI: 10.1149/1.1621288

A High-Rate Manganese Oxide for Rechargeable Lithium Battery Applications
journal, January 2001

  • Doeff, Marca M.; Anapolsky, Abraham; Edman, Ludvig
  • Journal of The Electrochemical Society, Vol. 148, Issue 3
  • DOI: 10.1149/1.1349883

Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
journal, June 1996

  • Armstrong, A. Robert; Bruce, Peter G.
  • Nature, Vol. 381, Issue 6582
  • DOI: 10.1038/381499a0

Lithium Insertion Processes of Orthorhombic Na[sub x]MnO[sub 2]-Based Electrode Materials
journal, January 1996

  • Doeff, Marca M.
  • Journal of The Electrochemical Society, Vol. 143, Issue 8
  • DOI: 10.1149/1.1837039

Orthorhombic Na[sub x]MnO[sub 2] as a Cathode Material for Secondary Sodium and Lithium Polymer Batteries
journal, January 1994

  • Doeff, Marca M.
  • Journal of The Electrochemical Society, Vol. 141, Issue 11
  • DOI: 10.1149/1.2059323

Electrochemical and structural characterization of titanium-substituted manganese oxides based on Na0.44MnO2
journal, September 2004

  • Doeff, Marca M.; Richardson, Thomas J.; Hwang, Kwang-Taek
  • Journal of Power Sources, Vol. 135, Issue 1-2, p. 240-248
  • DOI: 10.1016/j.jpowsour.2004.03.073

Synthesis of single crystalline electro-conductive Na0.44MnO2 nanowires with high aspect ratio for the fast charge–discharge Li ion battery
journal, July 2008


EIS and GITT studies on oxide cathodes, O2-Li(2/3)+x(Co0.15Mn0.85)O2 (x=0 and 1/3)
journal, August 2003


Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn 2 O 4
journal, December 2009

  • Yang, Yuan; Xie, Chong; Ruffo, Riccardo
  • Nano Letters, Vol. 9, Issue 12
  • DOI: 10.1021/nl902315u

Hybrid Tin Oxide Nanowires as Stable and High Capacity Anodes for Li-Ion Batteries
journal, February 2009

  • Meduri, Praveen; Pendyala, Chandrashekhar; Kumar, Vivekanand
  • Nano Letters, Vol. 9, Issue 2
  • DOI: 10.1021/nl802864a

Structural and Electrochemical Characterization of Nanocrystalline Li[Li 0.12 Ni 0.32 Mn 0.56 ]O 2 Synthesized by a Polymer-Pyrolysis Route
journal, January 2005

  • Yu, Lihong; Yang, Hanxi; Ai, Xinping
  • The Journal of Physical Chemistry B, Vol. 109, Issue 3
  • DOI: 10.1021/jp0464369

Preparation and electrochemical performance of Sn–Co–C composite as anode material for Li-ion batteries
journal, April 2009


The structure of Na4Mn4Ti5O18
journal, August 1968

  • Mumme, W. G.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 24, Issue 8, p. 1114-1120
  • DOI: 10.1107/S0567740868003778

Charge/discharge cycling and impedance response of LiMn2O4 electrode in organic electrolyte solutions with different compositions
journal, March 2000


Influence of Li-Ion Kinetics in the Cathodic Performance of Layered Li(Ni[sub 1/3]Co[sub 1/3]Mn[sub 1/3])O[sub 2]
journal, January 2004

  • Shaju, K. M.; Subba Rao, G. V.; Chowdari, B. V. R.
  • Journal of The Electrochemical Society, Vol. 151, Issue 9
  • DOI: 10.1149/1.1775218

Structure, porosity, and redox in porous manganese oxide octahedral layer and molecular sieve materials
journal, January 2008

  • Suib, Steven L.
  • Journal of Materials Chemistry, Vol. 18, Issue 14
  • DOI: 10.1039/B714966M

Hydrothermal Synthesis of Structure- and Shape-Controlled Manganese Oxide Octahedral Molecular Sieve Nanomaterials
journal, June 2006

  • Li, W. -N.; Yuan, J.; Shen, X. -F.
  • Advanced Functional Materials, Vol. 16, Issue 9
  • DOI: 10.1002/adfm.200500504

Determination of the chemical diffusion coefficient of lithium in LiFePO4
journal, May 2002


Electronically conductive phospho-olivines as lithium storage electrodes
journal, September 2002

  • Chung, Sung-Yoon; Bloking, Jason T.; Chiang, Yet-Ming
  • Nature Materials, Vol. 1, Issue 2, p. 123-128
  • DOI: 10.1038/nmat732

The Design of a LiFePO4/Carbon Nanocomposite With a Core-Shell Structure and Its Synthesis by an In Situ Polymerization Restriction Method
journal, September 2008

  • Wang, Yonggang; Wang, Yarong; Hosono, Eiji
  • Angewandte Chemie International Edition, Vol. 47, Issue 39, p. 7461-7465
  • DOI: 10.1002/anie.200802539

Template-Free Hydrothermal Synthesis of Nanoembossed Mesoporous LiFePO 4 Microspheres for High-Performance Lithium-Ion Batteries
journal, February 2010

  • Qian, Jiangfeng; Zhou, Min; Cao, Yuliang
  • The Journal of Physical Chemistry C, Vol. 114, Issue 8
  • DOI: 10.1021/jp912102k

Projector augmented-wave method
journal, December 1994


Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Ab initiomolecular dynamics for liquid metals
journal, January 1993


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998

  • Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
  • Physical Review B, Vol. 57, Issue 3, p. 1505-1509
  • DOI: 10.1103/PhysRevB.57.1505

Relating Synthesis Conditions and Electrochemical Performance for the Sodium Intercalation Compound Na[sub 4]Mn[sub 9]O[sub 18] in Aqueous Electrolyte
journal, January 2010

  • Tevar, A. D.; Whitacre, J. F.
  • Journal of The Electrochemical Society, Vol. 157, Issue 7
  • DOI: 10.1149/1.3428667