DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Nanocrystalline cerium oxide materials for solid fuel cell systems

Abstract

Disclosed are solid fuel cells, including solid oxide fuel cells and PEM fuel cells that include nanocrystalline cerium oxide materials as a component of the fuel cells. A solid oxide fuel cell can include nanocrystalline cerium oxide as a cathode component and microcrystalline cerium oxide as an electrolyte component, which can prevent mechanical failure and interdiffusion common in other fuel cells. A solid oxide fuel cell can also include nanocrystalline cerium oxide in the anode. A PEM fuel cell can include cerium oxide as a catalyst support in the cathode and optionally also in the anode.

Inventors:
Issue Date:
Research Org.:
Savannah River Ecology Laboratory (SREL), Aiken, SC (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1179027
Patent Number(s):
9023550
Application Number:
13/297,826
Assignee:
Savannah River Nuclear Solutions, LLC (Aiken, SC)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
DOE Contract Number:  
AC09-08SR22470
Resource Type:
Patent
Resource Relation:
Patent File Date: 2011 Nov 16
Country of Publication:
United States
Language:
English
Subject:
30 DIRECT ENERGY CONVERSION; 36 MATERIALS SCIENCE

Citation Formats

Brinkman, Kyle S. Nanocrystalline cerium oxide materials for solid fuel cell systems. United States: N. p., 2015. Web.
Brinkman, Kyle S. Nanocrystalline cerium oxide materials for solid fuel cell systems. United States.
Brinkman, Kyle S. Tue . "Nanocrystalline cerium oxide materials for solid fuel cell systems". United States. https://www.osti.gov/servlets/purl/1179027.
@article{osti_1179027,
title = {Nanocrystalline cerium oxide materials for solid fuel cell systems},
author = {Brinkman, Kyle S},
abstractNote = {Disclosed are solid fuel cells, including solid oxide fuel cells and PEM fuel cells that include nanocrystalline cerium oxide materials as a component of the fuel cells. A solid oxide fuel cell can include nanocrystalline cerium oxide as a cathode component and microcrystalline cerium oxide as an electrolyte component, which can prevent mechanical failure and interdiffusion common in other fuel cells. A solid oxide fuel cell can also include nanocrystalline cerium oxide in the anode. A PEM fuel cell can include cerium oxide as a catalyst support in the cathode and optionally also in the anode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 05 00:00:00 EDT 2015},
month = {Tue May 05 00:00:00 EDT 2015}
}

Works referenced in this record:

Formation of carbon-supported PtM alloys for low temperature fuel cells: a review
journal, February 2003


The Oxygen Permeation Properties of Nanocrystalline CeO[sub 2] Thin Films
journal, January 2010


Defect and transport properties of nanocrystalline CeO 2− x
journal, July 1996


Chemical Modification of Proton Exchange Membrane Fuel Cell Catalysts with a Sulfonated Silane
journal, January 2001


Preparing High Loading Pt/C by Modifying the Carbon Support
journal, January 2003


Modification of carbon supported catalysts to improve performance in gas diffusion electrodes
journal, May 2001


Oxygen Permeable Ce[sub 0.8]Gd[sub 0.2]O[sub 1.9]-CoFe[sub 2]O[sub 4] Thin Films Prepared on Porous Ce[sub 0.8]Gd[sub 0.2]O[sub 1.9] Substrates
journal, January 2005


Characterization of Vulcan Electrochemically Oxidized under Simulated PEM Fuel Cell Conditions
journal, January 2004


Determination of carbon surface oxides on platinum-catalyzed carbon
journal, October 1974


Particle size and alloying effects of Pt-based alloy catalysts for fuel cell applications
journal, August 2000


Enhanced electrocatalysis of oxygen reduction on platinum alloys in proton exchange membrane fuel cells
journal, October 1993


Corrosion behaviour of platinum-catalyzed carbon in phosphoric acid solution
journal, January 1994


A Reverse-Current Decay Mechanism for Fuel Cells
journal, January 2005


Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes
journal, January 2004


Metal-support interaction in Pt/C catalysts. Influence of the support surface chemistry and the metal precursor
journal, January 1995


Spectroelectrochemical Study of the Role Played by Carbon Functionality in Fuel Cell Electrodes
journal, January 1997


Imaging of highly oriented pyrolytic graphite corrosion accelerated by Pt particles
journal, November 2005


PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode
journal, August 2006


Grain Size Dependence of Electrical Conductivity in Polycrystalline Cerium Oxide
journal, December 2001


The influence of Pt-activation on the corrosion of carbon in gas diffusion electrodes—A dems study
journal, February 1984


Advanced Fuel Cell Catalysts
journal, January 2003


High performance carbon-supported catalysts for fuel cells via phosphonation
journal, March 2003


Superior Catalysts for Proton Exchange Membrane Fuel Cells
journal, January 2005


Solid electrolyte fuel cell and method for preparing it
patent, August 1987


Procedure for shutting down a fuel cell system having an anode exhaust recycle loop
patent, February 2003


Shut-down procedure for hydrogen-air fuel cell system
patent, October 2003


Reducing fuel cell cathode potential during startup and shutdown
patent, July 2005


Solid oxide fuel cells, electrolyzers, and sensors, and methods of making and using the same
patent, January 2014


Nano-composite electrodes and method of making the same
patent-application, February 2003