Method for removing impurities from an impurity-containing fluid stream
Abstract
A method of removing at least one polar component from a fluid stream. The method comprises providing a fluid stream comprising at least one nonpolar component and at least one polar component. The fluid stream is contacted with a supercritical solvent to remove the at least one polar component. The at least one nonpolar component may be a fat or oil and the at least one polar component may be water, dirt, detergents, or mixtures thereof. The supercritical solvent may decrease solubility of the at least one polar component in the fluid stream. The supercritical solvent may function as a solvent or as a gas antisolvent. The supercritical solvent may dissolve the nonpolar components of the fluid stream, such as fats or oils, while the polar components may be substantially insoluble. Alternatively, the supercritical solvent may be used to increase the nonpolarity of the fluid stream.
- Inventors:
- Issue Date:
- Research Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1176209
- Patent Number(s):
- 7691270
- Application Number:
- 11/181,211
- Assignee:
- Battelle Energy Alliance, LLC (Idaho Falls, ID)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
- DOE Contract Number:
- AC07-05ID14517
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS
Citation Formats
Ginosar, Daniel M., and Fox, Robert V. Method for removing impurities from an impurity-containing fluid stream. United States: N. p., 2010.
Web.
Ginosar, Daniel M., & Fox, Robert V. Method for removing impurities from an impurity-containing fluid stream. United States.
Ginosar, Daniel M., and Fox, Robert V. Tue .
"Method for removing impurities from an impurity-containing fluid stream". United States. https://www.osti.gov/servlets/purl/1176209.
@article{osti_1176209,
title = {Method for removing impurities from an impurity-containing fluid stream},
author = {Ginosar, Daniel M. and Fox, Robert V.},
abstractNote = {A method of removing at least one polar component from a fluid stream. The method comprises providing a fluid stream comprising at least one nonpolar component and at least one polar component. The fluid stream is contacted with a supercritical solvent to remove the at least one polar component. The at least one nonpolar component may be a fat or oil and the at least one polar component may be water, dirt, detergents, or mixtures thereof. The supercritical solvent may decrease solubility of the at least one polar component in the fluid stream. The supercritical solvent may function as a solvent or as a gas antisolvent. The supercritical solvent may dissolve the nonpolar components of the fluid stream, such as fats or oils, while the polar components may be substantially insoluble. Alternatively, the supercritical solvent may be used to increase the nonpolarity of the fluid stream.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {4}
}
Works referenced in this record:
Simple quantitative transesterification of lipids 1. introduction
journal, January 1996
- Stránsky, Karel; Jursik, Tomáš
- Lipid/Fett, Vol. 98, Issue 2
Synthesis of Oleic Acid Esters Catalyzed by Immobilized Lipase
journal, January 1996
- Habulin, Maja; Krmelj, Vlasta; Knez, Željko
- Journal of Agricultural and Food Chemistry, Vol. 44, Issue 1
Reactions in supercritical fluids - a review
journal, January 1986
- Subramaniam, Bala; McHugh, Mark A.
- Industrial & Engineering Chemistry Process Design and Development, Vol. 25, Issue 1
Liquid and supercritical carbon dioxide as organic solvents
journal, December 1984
- Hyatt, John A.
- The Journal of Organic Chemistry, Vol. 49, Issue 26
Biodiesel fuel from rapeseed oil as prepared in supercritical methanol
journal, January 2001
- Saka, S.; Kusdiana, D.
- Fuel, Vol. 80, Issue 2
Comparison of lipase-catalysed esterification in supercritical carbon dioxide and in n-hexane
journal, January 1990
- Marty, A.; Chulalaksananukul, W.; Condoret, J. S.
- Biotechnology Letters, Vol. 12, Issue 1
Biodiesel from vegetable oils via transesterification in supercritical methanol
journal, November 2002
- Demirbaş, Ayhan
- Energy Conversion and Management, Vol. 43, Issue 17
Promotion of a lipase-catalyzed esterification in supercritical carbon dioxide in the near-critical region
journal, June 1996
- Ikushima, Y.; Saito, N.; Hatakeda, K.
- Chemical Engineering Science, Vol. 51, Issue 11
Esterification activity of lipase entrapped in reverse micelles formed in liquefied gas.
journal, January 1996
- Murakata, Tadahiro; Yusa, Kazuhisa; Yada, Manabu
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 29, Issue 2
Methanolysis of seed oils in flowing supercritical carbon dioxide
journal, March 1996
- Jackson, Michael A.; King, Jerry W.
- Journal of the American Oil Chemists' Society, Vol. 73, Issue 3
Enzyme catalyzed reactions in dense gases
journal, October 1998
- Knez, Ž.; Habulin, M.; Krmelj, V.
- The Journal of Supercritical Fluids, Vol. 14, Issue 1
Kinetics of transesterification in rapeseed oil to biodiesel fuel as treated in supercritical methanol
journal, April 2001
- Kusdiana, D.; Saka, S.
- Fuel, Vol. 80, Issue 5
Enzymic esterification of fatty acid mixtures from milk fat and anhydrous milk fat with canola oil in supercritical carbon dioxide
journal, November 1992
- Yu, Zer Ran; Rizvi, Syed S. H.; Zollweg, John A.
- Biotechnology Progress, Vol. 8, Issue 6
Biocatalytic Esterification in Supercritical Carbon Dioxide by Using a Lipid-coated Lipase
journal, September 1998
- Mori, Toshiaki; Kobayashi, Atsushi; Okahata, Yoshio
- Chemistry Letters, Vol. 27, Issue 9
Ester synthesis in lipase-catalyzed reactions
journal, November 1998
- Yahya, Ahmad R. M.; Anderson, William A.; Moo-Young, Murray
- Enzyme and Microbial Technology, Vol. 23, Issue 7-8
Process parameters influencing ethanolysis of cod liver oil in supercritical carbon dioxide
journal, March 1998
- Gunnlaugsdottir, Helga; Järemo, Mattias; Sivik, Björn
- The Journal of Supercritical Fluids, Vol. 12, Issue 1
Enantioselective Esterification of 2-Arylpropionic Acids Catalyzed by Immobilized Rhizomucor miehei Lipase
journal, March 1997
- López-Belmonte, M. Trinidad; Alcántara, Andrés R.; Sinisterra, José V.
- The Journal of Organic Chemistry, Vol. 62, Issue 6
Biodiesel production: a review
journal, October 1999
- Ma, Fangrui; Hanna, Milford A.
- Bioresource Technology, Vol. 70, Issue 1, p. 1-15
Reactions at supercritical conditions: Applications and fundamentals
journal, July 1995
- Savage, Phillip E.; Gopalan, Sudhama; Mizan, Thamid I.
- AIChE Journal, Vol. 41, Issue 7
Biodiesel fuel production by transesterification of oils
journal, January 2001
- Fukuda, Hideki; Kondo, Akihiko; Noda, Hideo
- Journal of Bioscience and Bioengineering, Vol. 92, Issue 5
Continuous reaction-separation process for enzymatic esterification in supercritical carbon dioxide
journal, March 1994
- Marty, Alain; Combes, Didier; Condoret, Jean-St�aphane
- Biotechnology and Bioengineering, Vol. 43, Issue 6
Esterification of decanoic acid during supercritical fluid extraction employing either methanol-modified carbon dioxide or a methanol trap
journal, October 1999
- McDaniel, L. H.; Taylor, L. T.
- Journal of Chromatography A, Vol. 858, Issue 2
Enhancement of Enantioselectivity by Altering Alcohol Concentration for Esterification in Supercritical CO2.
journal, January 1999
- Wu, Jau-Yann; Liang, Ming-Tsai
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 32, Issue 3
Enzymatic Reaction in Supercritical Fluid Carbon Dioxide Using Dry-Ice
journal, October 1999
- Yu, Hui-Ming; Lin, Han-Liang; Wu, Chi-Yue
- Journal of the Chinese Chemical Society, Vol. 46, Issue 5
Enzymatic catalysis in supercritical carbon dioxide: Comparison of different lipases and a novel esterase
journal, January 1996
- Michor, H.; Marr, R.; Gamse, T.
- Biotechnology Letters, Vol. 18, Issue 1
The role of the reaction medium in lipase-catalyzed esterifications and transesterifications
journal, June 1998
- Cernia, E.; Palocci, C.; Soro, S.
- Chemistry and Physics of Lipids, Vol. 93, Issue 1-2
Subtilisin-catalyzed transesterification in supercritical carbon dioxide
journal, September 1989
- Pasta, P.; Mazzola, G.; Carrea, G.
- Biotechnology Letters, Vol. 11, Issue 9
Chemical Reactions in Supercritical Fluids. [超臨界流体中における化学反応]
journal, January 1995
- Ikariya, Takao; Jessop, Philip G.; Noyori, Ryoji
- Journal of Synthetic Organic Chemistry, Japan, Vol. 53, Issue 5
Lipase Catalysed Esterification at High Pressure
journal, January 1994
- Knez, Ž.; Habulin, M.
- Biocatalysis, Vol. 9, Issue 1-4
Lipase-catalyzed alcoholysis with supercritical carbon dioxide extraction 2: Phase behavior
journal, November 1997
- Gunnlaugsdottir, Helga; Karlsson, Anders Å.; Sivik, Björn
- Journal of the American Oil Chemists' Society, Vol. 74, Issue 11
Enzymatic synthesis of oleyl oleate in dense fluids
journal, November 1995
- Knez, Ž.; Rižner, V.; Habulin, M.
- Journal of the American Oil Chemists' Society, Vol. 72, Issue 11
Internal Mass Transfer Limitation During Enzymatic Esterification in Supercritical Carbon Dioxide and Hexane
journal, January 1995
- Bernard, P.; Barth, D.
- Biocatalysis and Biotransformation, Vol. 12, Issue 4
Kinetics of lipase-catalyzed esterification in supercritical CO2
journal, February 1992
- Marty, A.; Chulalaksananukul, W.; Willemot, R. M.
- Biotechnology and Bioengineering, Vol. 39, Issue 3
Transesterification between triolein and ethylbehenate by immobilized lipase in supercritical carbon dioxide
journal, January 1996
- Yoon, Seung-Heon; Miyawaki, Osato; Park, Kwan-Hwa
- Journal of Fermentation and Bioengineering, Vol. 82, Issue 4
Lipases in supercritical fluids
book, January 1997
- Cernia, Enrico; Palocc, Cleofe
- Methods in Enzymology
Lipase-catalysed esterification in supercritical carbon dioxide and in hexane
journal, February 1997
- Vija, Heiki; Telling, Artur; Tõugu, Vello
- Bioorganic & Medicinal Chemistry Letters, Vol. 7, Issue 3
Enzymatic interesterification in supercritical carbon dioxide.
journal, January 1988
- Chi, Young Min; Nakamura, Kozo; Yano, Toshimasa
- Agricultural and Biological Chemistry, Vol. 52, Issue 6
Promotion of lipase-catalyzed esterification of N-valeric acid and citronellol in supercritical carbon dioxide in the near-critical region.
journal, January 1996
- Ikushima, Yutaka; Saito, Norio; Arai, Masahiko
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 29, Issue 3
Solubilities of methyl oleate, oleic acid, oleyl glycerols, and oleyl glycerol mixtures in supercritical carbon dioxide
journal, February 1991
- Nilsson, William B.; Gauglitz, Erich J.; Hudson, Joanne K.
- Journal of the American Oil Chemists' Society, Vol. 68, Issue 2
Alcoholysis and Glyceride Synthesis with Immobilized Lipase on Controlled-Pore Glass of Varying Hydrophobicity in Supercritical Carbon Dioxide
journal, April 1998
- Gunnlaugsdottir, Helga; Wannerberger, Kristin; Sivik, Björn
- Enzyme and Microbial Technology, Vol. 22, Issue 5
Esterification of oleic acid by methanol catalyzed by p-toluenesulfonic acid and the cation-exchange resins K2411 and K1481 in supercritical carbon dioxide
journal, September 1993
- Vieville, Corinne; Mouloungui, Zephirin; Gaset, Antoine
- Industrial & Engineering Chemistry Research, Vol. 32, Issue 9
Continuous synthesis of ethyl myristate by enzymatic reaction in supercritical carbon dioxide
journal, June 1993
- Dumont, T.; Barth, D.; Perrut, M.
- The Journal of Supercritical Fluids, Vol. 6, Issue 2
Supercritical Biocatalysis
journal, February 1999
- Mesiano, Anita J.; Beckman, Eric J.; Russell, Alan J.
- Chemical Reviews, Vol. 99, Issue 2
Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey
journal, August 2003
- Demirbaş, Ayhan
- Energy Conversion and Management, Vol. 44, Issue 13