Method for halogenating or radiohalogenating a chemical compound

Kabalka, George W.

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Title: Method for halogenating or radiohalogenating a chemical compound

Abstract

A method for obtaining a halogenated organic compound, whereby an organotrifluoroborate compound is reacted with a halide ion in the presence of an oxidizing agent to produce the corresponding halogenated organic compound. The method may be used for producing radiohalogenated organic compounds.

Inventors:: Kabalka, George W.

Issue Date:: 2006-05-09

Research Org.:: University Of Tennessee Research Foundation, Knoxville, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1175735

Patent Number(s):: 7041859

Application Number:: 11/174,797

Assignee:: University Of Tennessee Research Foundation

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
C07B39/00 - Halogenation
C07B59/00 - Introduction of isotopes of elements into organic compounds {

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/093 - by replacement by halogens
C07C19/16 - and iodine
C07C201/12 - by reactions not involving the formation of nitro groups
C07C205/12 - the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
C07C21/17 - containing iodine
C07C21/22 - containing carbon-to-carbon triple bonds
C07C22/00 - Cyclic compounds containing halogen atoms bound to an acyclic carbon atom
C07C25/02 - Monocyclic aromatic halogenated hydrocarbons
C07C25/22 - with condensed rings
C07C25/24 - Halogenated aromatic hydrocarbons with unsaturated side chains
C07C253/30 - by reactions not involving the formation of cyano groups
C07C255/50 - to carbon atoms of non-condensed six-membered aromatic rings
C07C45/63 - by introduction of halogen
C07C49/807 - all halogen atoms bound to the ring

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Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Kabalka, George W. Method for halogenating or radiohalogenating a chemical compound.  United States: N. p., 2006. 
        Web.

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                    Kabalka, George W. Method for halogenating or radiohalogenating a chemical compound.  United States.

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                    Kabalka, George W. Tue .  
        "Method for halogenating or radiohalogenating a chemical compound".  United States.  https://www.osti.gov/servlets/purl/1175735.

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@article{osti_1175735,

  title        = {Method for halogenating or radiohalogenating a chemical compound},

  author       = {Kabalka, George W.},

  abstractNote = {A method for obtaining a halogenated organic compound, whereby an organotrifluoroborate compound is reacted with a halide ion in the presence of an oxidizing agent to produce the corresponding halogenated organic compound. The method may be used for producing radiohalogenated organic compounds.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2006},

  month        = {5}

}

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Works referenced in this record:

Cross-coupling reactions of arenediazonium tetrafluoroborates with potassium aryl- or alkenyltrifluoroborates catalyzed by palladium
journal, June 1997

Darses, Sylvain; Genêt, Jean-Pierre; Brayer, Jean-Louis
Tetrahedron Letters, Vol. 38, Issue 25
https://doi.org/10.1016/S0040-4039(97)00939-8

Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides
journal, February 2004

Kabalka, George W.; Reddy Mereddy, Arjun
Tetrahedron Letters, Vol. 45, Issue 7
https://doi.org/10.1016/j.tetlet.2003.12.050

Potassium Organotrifluoroborates: New Partners in Palladium-Catalysed Cross-Coupling Reactions
journal, August 1999

Darses, Sylvain; Michaud, Guillaume; Genêt, Jean-Pierre
European Journal of Organic Chemistry, Vol. 1999, Issue 8, p. 1875-1883
URL: 10.1002/(SICI)1099-0690(199908)1999:8<1875::AID-EJOC1875>3.0.CO;2-W

A facile synthesis of aryl iodides via potassium aryltrifluoroborates
journal, January 2004

Kabalka, George W.; Mereddy, Arjun R.
Tetrahedron Letters, Vol. 45, Issue 2
https://doi.org/10.1016/j.tetlet.2003.10.149

Conversion of Arylboronic Acids into Potassium Aryltrifluoroborates: Convenient Precursors of Arylboron Difluoride Lewis Acids
journal, May 1995

Vedejs, E.; Chapman, R. W.; Fields, S. C.
The Journal of Organic Chemistry, Vol. 60, Issue 10
https://doi.org/10.1021/jo00115a016

Synthesis of Organic Bromides via Organotrifluoroborates
journal, September 2004

Kabalka, George W.; Mereddy, Arjun Reddy
Organometallics, Vol. 23, Issue 19
https://doi.org/10.1021/om049685s

Palladium-Catalyzed Cross-Coupling of Acetates of Baylis−Hillman Adducts and Potassium Organotrifluoroborates
journal, October 2003

Kabalka, George W.; Venkataiah, Bollu; Dong, Gang
Organic Letters, Vol. 5, Issue 21
https://doi.org/10.1021/ol0351798

Development of the Suzuki−Miyaura Cross-Coupling Reaction: Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations
journal, November 2002

Molander, Gary A.; Katona, Bryson W.; Machrouhi, Fouzia
The Journal of Organic Chemistry, Vol. 67, Issue 24
https://doi.org/10.1021/jo0262356

Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates ^†
journal, January 2002

Molander, Gary A.; Rivero, Marta Rodríguez
Organic Letters, Vol. 4, Issue 1
https://doi.org/10.1021/ol0169729

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Similar Records

Title: Method for halogenating or radiohalogenating a chemical compound

Abstract

Citation Formats

Cross-coupling reactions of arenediazonium tetrafluoroborates with potassium aryl- or alkenyltrifluoroborates catalyzed by palladium journal, June 1997

Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides journal, February 2004

Potassium Organotrifluoroborates: New Partners in Palladium-Catalysed Cross-Coupling Reactions journal, August 1999

A facile synthesis of aryl iodides via potassium aryltrifluoroborates journal, January 2004

Conversion of Arylboronic Acids into Potassium Aryltrifluoroborates: Convenient Precursors of Arylboron Difluoride Lewis Acids journal, May 1995

Synthesis of Organic Bromides via Organotrifluoroborates journal, September 2004

Palladium-Catalyzed Cross-Coupling of Acetates of Baylis−Hillman Adducts and Potassium Organotrifluoroborates journal, October 2003

Development of the Suzuki−Miyaura Cross-Coupling Reaction: Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations journal, November 2002

Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates † journal, January 2002

Cross-coupling reactions of arenediazonium tetrafluoroborates with potassium aryl- or alkenyltrifluoroborates catalyzed by palladium
journal, June 1997

Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides
journal, February 2004

Potassium Organotrifluoroborates: New Partners in Palladium-Catalysed Cross-Coupling Reactions
journal, August 1999

A facile synthesis of aryl iodides via potassium aryltrifluoroborates
journal, January 2004

Conversion of Arylboronic Acids into Potassium Aryltrifluoroborates: Convenient Precursors of Arylboron Difluoride Lewis Acids
journal, May 1995

Synthesis of Organic Bromides via Organotrifluoroborates
journal, September 2004

Palladium-Catalyzed Cross-Coupling of Acetates of Baylis−Hillman Adducts and Potassium Organotrifluoroborates
journal, October 2003

Development of the Suzuki−Miyaura Cross-Coupling Reaction: Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations
journal, November 2002

Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates ^†
journal, January 2002