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Title: Method for halogenating or radiohalogenating a chemical compound

Abstract

A method for obtaining a halogenated organic compound, whereby an organotrifluoroborate compound is reacted with a halide ion in the presence of an oxidizing agent to produce the corresponding halogenated organic compound. The method may be used for producing radiohalogenated organic compounds.

Inventors:
Issue Date:
Research Org.:
University Of Tennessee Research Foundation, Knoxville, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1175735
Patent Number(s):
7041859
Application Number:
11/174,797
Assignee:
University Of Tennessee Research Foundation
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kabalka, George W. Method for halogenating or radiohalogenating a chemical compound. United States: N. p., 2006. Web.
Kabalka, George W. Method for halogenating or radiohalogenating a chemical compound. United States.
Kabalka, George W. Tue . "Method for halogenating or radiohalogenating a chemical compound". United States. https://www.osti.gov/servlets/purl/1175735.
@article{osti_1175735,
title = {Method for halogenating or radiohalogenating a chemical compound},
author = {Kabalka, George W.},
abstractNote = {A method for obtaining a halogenated organic compound, whereby an organotrifluoroborate compound is reacted with a halide ion in the presence of an oxidizing agent to produce the corresponding halogenated organic compound. The method may be used for producing radiohalogenated organic compounds.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2006},
month = {5}
}

Patent:

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Works referenced in this record:

Cross-coupling reactions of arenediazonium tetrafluoroborates with potassium aryl- or alkenyltrifluoroborates catalyzed by palladium
journal, June 1997


Iodination of organotrifluoroborates: synthesis of vinyl and alkynyl iodides
journal, February 2004


A facile synthesis of aryl iodides via potassium aryltrifluoroborates
journal, January 2004


Conversion of Arylboronic Acids into Potassium Aryltrifluoroborates: Convenient Precursors of Arylboron Difluoride Lewis Acids
journal, May 1995


Synthesis of Organic Bromides via Organotrifluoroborates
journal, September 2004


Palladium-Catalyzed Cross-Coupling of Acetates of Baylis−Hillman Adducts and Potassium Organotrifluoroborates
journal, October 2003


Development of the Suzuki−Miyaura Cross-Coupling Reaction:  Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations
journal, November 2002


Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates
journal, January 2002