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Title: Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids

Abstract

A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

Inventors:
;
Issue Date:
Research Org.:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1175719
Patent Number(s):
7033551
Application Number:
10/057,543
Assignee:
Battelle Energy Alliance, LLC (Idaho Falls, ID)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
AC07-05ID14517
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
47 OTHER INSTRUMENTATION

Citation Formats

Kong, Peter C., and Lessing, Paul A. Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids. United States: N. p., 2006. Web.
Kong, Peter C., & Lessing, Paul A. Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids. United States.
Kong, Peter C., and Lessing, Paul A. Tue . "Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids". United States. https://www.osti.gov/servlets/purl/1175719.
@article{osti_1175719,
title = {Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids},
author = {Kong, Peter C. and Lessing, Paul A.},
abstractNote = {A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2006},
month = {4}
}

Works referenced in this record:

Generation of atmospheric pressure plasma with a dual-chamber discharge
journal, October 2000


The effect of gravity direction on the EHD surface waves of dielectric oil thin films generated by wire-plate barrier discharges
conference, January 1998


EHD surface waves of diesel oil thin films generated by wire-plate barrier discharges
conference, August 2002