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Title: Polymers incorporating covalently attached organoimido polyoxometalates

Abstract

New polyoxometalate compounds and polymers comprising recurring monomers of those compounds are provided. The compounds are formed by replacing at least one oxide of the starting polyoxometalate with an organoimido (NR) group bonded to the polyoxometalate via a triple bond to the nitrogen atom. The R of the (NR) group comprises a reactive functional group which renders the compound readily polymerizable, alone or with other monomers (e.g., divinylbenzene), to form the inventive polymers. Additionally, a countercation (e.g., bis(tetra-n-butylammonium)) can be mixed with the polyoxometalate compounds in order to neutralize the negative charge thereof as well as to make those compounds more soluble in organic solvents.

Inventors:
;
Issue Date:
Research Org.:
Kansas State University Research Foundation, Manhattan, KS (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1174770
Patent Number(s):
6706833
Application Number:
09/609,863
Assignee:
Kansas State University Research Foundation (Manhattan, KS)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
DOE Contract Number:  
FG02-92ER14246
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Maatta, Eric A., and Moore, Aaron R. Polymers incorporating covalently attached organoimido polyoxometalates. United States: N. p., 2004. Web.
Maatta, Eric A., & Moore, Aaron R. Polymers incorporating covalently attached organoimido polyoxometalates. United States.
Maatta, Eric A., and Moore, Aaron R. Tue . "Polymers incorporating covalently attached organoimido polyoxometalates". United States. https://www.osti.gov/servlets/purl/1174770.
@article{osti_1174770,
title = {Polymers incorporating covalently attached organoimido polyoxometalates},
author = {Maatta, Eric A. and Moore, Aaron R.},
abstractNote = {New polyoxometalate compounds and polymers comprising recurring monomers of those compounds are provided. The compounds are formed by replacing at least one oxide of the starting polyoxometalate with an organoimido (NR) group bonded to the polyoxometalate via a triple bond to the nitrogen atom. The R of the (NR) group comprises a reactive functional group which renders the compound readily polymerizable, alone or with other monomers (e.g., divinylbenzene), to form the inventive polymers. Additionally, a countercation (e.g., bis(tetra-n-butylammonium)) can be mixed with the polyoxometalate compounds in order to neutralize the negative charge thereof as well as to make those compounds more soluble in organic solvents.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2004},
month = {3}
}

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Works referenced in this record:

Derivatives of heteropolyanions. 2. Metal-metal-bonded derivatives
journal, April 1979


Synthesis and properties of polyoxometalates based inorganic-organic polymers
journal, January 1992


Silicone-Polyoxometalate (SiPOM) Hybrid Compounds
journal, January 1996


A Survey of Applications of Polyoxometalates
journal, February 1998