Polymers incorporating covalently attached organoimido polyoxometalates
Abstract
New polyoxometalate compounds and polymers comprising recurring monomers of those compounds are provided. The compounds are formed by replacing at least one oxide of the starting polyoxometalate with an organoimido (NR) group bonded to the polyoxometalate via a triple bond to the nitrogen atom. The R of the (NR) group comprises a reactive functional group which renders the compound readily polymerizable, alone or with other monomers (e.g., divinylbenzene), to form the inventive polymers. Additionally, a countercation (e.g., bis(tetra-n-butylammonium)) can be mixed with the polyoxometalate compounds in order to neutralize the negative charge thereof as well as to make those compounds more soluble in organic solvents.
- Inventors:
- Issue Date:
- Research Org.:
- Kansas State University Research Foundation, Manhattan, KS (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1174770
- Patent Number(s):
- 6706833
- Application Number:
- 09/609,863
- Assignee:
- Kansas State University Research Foundation (Manhattan, KS)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- DOE Contract Number:
- FG02-92ER14246
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Maatta, Eric A., and Moore, Aaron R. Polymers incorporating covalently attached organoimido polyoxometalates. United States: N. p., 2004.
Web.
Maatta, Eric A., & Moore, Aaron R. Polymers incorporating covalently attached organoimido polyoxometalates. United States.
Maatta, Eric A., and Moore, Aaron R. Tue .
"Polymers incorporating covalently attached organoimido polyoxometalates". United States. https://www.osti.gov/servlets/purl/1174770.
@article{osti_1174770,
title = {Polymers incorporating covalently attached organoimido polyoxometalates},
author = {Maatta, Eric A. and Moore, Aaron R.},
abstractNote = {New polyoxometalate compounds and polymers comprising recurring monomers of those compounds are provided. The compounds are formed by replacing at least one oxide of the starting polyoxometalate with an organoimido (NR) group bonded to the polyoxometalate via a triple bond to the nitrogen atom. The R of the (NR) group comprises a reactive functional group which renders the compound readily polymerizable, alone or with other monomers (e.g., divinylbenzene), to form the inventive polymers. Additionally, a countercation (e.g., bis(tetra-n-butylammonium)) can be mixed with the polyoxometalate compounds in order to neutralize the negative charge thereof as well as to make those compounds more soluble in organic solvents.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2004},
month = {3}
}
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