skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ether and ester derivatives of the perborate icosahedron

Abstract

New boron icosahedral ethers and esters formed from Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ],; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by reacting the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with an acid anhdride or acid chloride to form the ester or an alkylating agent to form the ether.

Inventors:
; ;
Issue Date:
Research Org.:
The Regents of the University of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1174629
Patent Number(s):
6,664,426
Application Number:
09/592,214
Assignee:
The Regents of the University of California (Oakland, CA) OSTI
DOE Contract Number:  
FG03-95ERG1975
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hawthorne, M. Frederick, Peymann, Toralf, and Maderna, Andreas. Ether and ester derivatives of the perborate icosahedron. United States: N. p., 2003. Web.
Hawthorne, M. Frederick, Peymann, Toralf, & Maderna, Andreas. Ether and ester derivatives of the perborate icosahedron. United States.
Hawthorne, M. Frederick, Peymann, Toralf, and Maderna, Andreas. Tue . "Ether and ester derivatives of the perborate icosahedron". United States. https://www.osti.gov/servlets/purl/1174629.
@article{osti_1174629,
title = {Ether and ester derivatives of the perborate icosahedron},
author = {Hawthorne, M. Frederick and Peymann, Toralf and Maderna, Andreas},
abstractNote = {New boron icosahedral ethers and esters formed from Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ],; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by reacting the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with an acid anhdride or acid chloride to form the ester or an alkylating agent to form the ether.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2003},
month = {12}
}

Patent:

Save / Share: