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Title: Convergent synthesis of multiporphyrin light-harvesting rods

Abstract

The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A.sup.1 (A.sup.b+1).sub.b, wherein b is at least 1, A.sup.1 through A.sup.b+1 are covalently coupled rod segments, and each rod segment A.sup.1 through A.sup.1+b comprises a compound of the formula X.sup.1 (X.sup.m+1).sub.m wherein m is at least 1 and X.sup.1 through X.sup.m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.

Inventors:
;
Issue Date:
Research Org.:
North Carolina State Univ., Raleigh, NC (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1174435
Patent Number(s):
6,603,070
Application Number:
09/939,010
Assignee:
North Carolina State University (Raleigh, NC) OSTI
DOE Contract Number:  
FG02-96ER14632
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Lindsey, Jonathan S., and Loewe, Robert S. Convergent synthesis of multiporphyrin light-harvesting rods. United States: N. p., 2003. Web.
Lindsey, Jonathan S., & Loewe, Robert S. Convergent synthesis of multiporphyrin light-harvesting rods. United States.
Lindsey, Jonathan S., and Loewe, Robert S. Tue . "Convergent synthesis of multiporphyrin light-harvesting rods". United States. https://www.osti.gov/servlets/purl/1174435.
@article{osti_1174435,
title = {Convergent synthesis of multiporphyrin light-harvesting rods},
author = {Lindsey, Jonathan S. and Loewe, Robert S.},
abstractNote = {The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A.sup.1 (A.sup.b+1).sub.b, wherein b is at least 1, A.sup.1 through A.sup.b+1 are covalently coupled rod segments, and each rod segment A.sup.1 through A.sup.1+b comprises a compound of the formula X.sup.1 (X.sup.m+1).sub.m wherein m is at least 1 and X.sup.1 through X.sup.m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2003},
month = {8}
}

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