DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Architectures and criteria for the design of high efficiency organic photovoltaic cells

Abstract

An organic photovoltaic cell includes an anode and a cathode, and a plurality of organic semiconductor layers between the anode and the cathode. At least one of the anode and the cathode is transparent. Each two adjacent layers of the plurality of organic semiconductor layers are in direct contact. The plurality of organic semiconductor layers includes an intermediate layer consisting essentially of a photoconductive material, and two sets of at least three layers. A first set of at least three layers is between the intermediate layer and the anode. Each layer of the first set consists essentially of a different organic semiconductor material having a higher LUMO and a higher HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the cathode. A second set of at least three layers is between the intermediate layer and the cathode. Each layer of the second set consists essentially of a different organic semiconductor material having a lower LUMO and a lower HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the anode.

Inventors:
; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1174192
Patent Number(s):
8987589
Application Number:
11/486,163
Assignee:
The Regents of the University of Michigan (Ann Arbor, MI); The Trustees of Princeton University (Princeton, NJ)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC36-98-GO10337
Resource Type:
Patent
Resource Relation:
Patent File Date: 2006 Jul 14
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY

Citation Formats

Rand, Barry, Forrest, Stephen R, and Burk, Diana Pendergrast. Architectures and criteria for the design of high efficiency organic photovoltaic cells. United States: N. p., 2015. Web.
Rand, Barry, Forrest, Stephen R, & Burk, Diana Pendergrast. Architectures and criteria for the design of high efficiency organic photovoltaic cells. United States.
Rand, Barry, Forrest, Stephen R, and Burk, Diana Pendergrast. Tue . "Architectures and criteria for the design of high efficiency organic photovoltaic cells". United States. https://www.osti.gov/servlets/purl/1174192.
@article{osti_1174192,
title = {Architectures and criteria for the design of high efficiency organic photovoltaic cells},
author = {Rand, Barry and Forrest, Stephen R and Burk, Diana Pendergrast},
abstractNote = {An organic photovoltaic cell includes an anode and a cathode, and a plurality of organic semiconductor layers between the anode and the cathode. At least one of the anode and the cathode is transparent. Each two adjacent layers of the plurality of organic semiconductor layers are in direct contact. The plurality of organic semiconductor layers includes an intermediate layer consisting essentially of a photoconductive material, and two sets of at least three layers. A first set of at least three layers is between the intermediate layer and the anode. Each layer of the first set consists essentially of a different organic semiconductor material having a higher LUMO and a higher HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the cathode. A second set of at least three layers is between the intermediate layer and the cathode. Each layer of the second set consists essentially of a different organic semiconductor material having a lower LUMO and a lower HOMO, relative to the material of an adjacent layer of the plurality of organic semiconductor layers closer to the anode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {3}
}

Works referenced in this record:

Effects of Postproduction Treatment on Plastic Solar Cells
journal, January 2003


Bulk-heterojunction photovoltaic devices based on donor–acceptor organic small molecule blends
journal, August 2003


Organic photosensitive devices
patent-application, February 2006


Carrier transport in multilayer organic photodetectors: II. Effects of anode preparation
journal, February 2004


Electrical characterisation of phthalocyanine-fullerene photovoltaic devices
journal, March 2001


Method of preparing photoresponsive devices, and devices made thereby
patent, December 2003


Photovoltaic device with optical concentrator and method of making the same
patent, August 2002


High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions
patent-application, October 2005


Monochromatic versus solar efficiencies of organic solar cells
journal, February 2000


Molecular level control of donor/acceptor heterostructuresin organic photovoltaic devices
journal, July 2004


Thin film organic position sensitive detectors
patent, February 2006


Solar cells using fullerenes
patent, June 2003


Efficient photon harvesting at high optical intensities in ultrathin organic double-heterostructure photovoltaic diodes
journal, May 2000


Optical properties of semiconducting and metallic single wall carbon nanotubes: effects of doping and high pressure
journal, January 2001


The effect of fullerene doping on photoelectric conversion using titanyl phthalocyanine and a perylene pigment
journal, February 2000


Photoluminescence quenching at a p o l y t h i o p h e n e / C 60 heterojunction
journal, May 2000


Multilayer organic photodetectors with improved performance
patent, December 2005


Structure for high efficiency electroluminescent device
patent, August 2000


Exciton diffusion and dissociation in a poly(p‐phenylenevinylene)/C60 heterojunction photovoltaic cell
journal, May 1996


Exciton diffusion and optical interference in organic donor–acceptor photovoltaic cells
journal, October 2001


Three‐layered organic solar cell with a photoactive interlayer of codeposited pigments
journal, March 1991


Organic photovoltaic devices
patent, December 2003


Highly efficient multiple reflection photosensitive optoelectronic device with optical concentrator
patent, December 2001


Weak intrinsic charge transfer complexes: A new route for developing wide spectrum organic photovoltaic cells
journal, January 2002


Highly transparent non-metallic cathodes
patent, July 2002


High efficiency organic solar cells based on single or multiple PIN structures
journal, March 2004


Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films
journal, September 2003


Synthesis and aggregation behavior of hosts containing phthalocyanine and crown ether subunits
journal, July 1987


Influence of codeposition on the performance of CuPc–C60 heterojunction photovoltaic devices
journal, February 2004


Two‐layer organic photovoltaic cell
journal, January 1986


Stacked organic photosensitive devices
patent-application, February 2006


Organic p-i-n solar cells
journal, June 2004


Small molecular weight organic thin-film photodetectors and solar cells
journal, April 2003


Organic photosensitive optoelectronic device with an exciton blocking layer
patent, April 2006


Organic photovoltaic devices
patent-application, March 2003


Ultimate efficiency of polymer/fullerene bulk heterojunction solar cells
journal, February 2006


Exciton Migration and Cathode Quenching in Organic Light Emitting Diodes
journal, May 2000


Transparent Electrodes from Single Wall Carbon Nanotubes
patent-application, October 2004


MIP-type organic solar cells incorporating phthalocyanine/fullerene mixed layers and doped wide-gap transport layers
journal, June 2004


Modeling photocurrent action spectra of photovoltaic devices based on organic thin films
journal, July 1999


2.5% efficient organic plastic solar cells
journal, February 2001


Asymmetric tandem organic photovoltaic cells with hybrid planar-mixed molecular heterojunctions
journal, December 2004


Aperiodic dielectric multilayer stack
patent-application, December 2005


Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells
journal, July 2001


Long-Range Singlet Energy Transfer in Perylene Bis(phenethylimide) Films
journal, July 1997


Transparent contacts for organic devices
patent, December 1997


Photovoltaic yield from exciton dissociation in organic dye layers
journal, January 1999


Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions
journal, December 1995


Solid state photosensitive devices which employ isolated photosynthetic complexes
patent-application, May 2005


Multilayer Organic Photodetectors with Improved Performance
patent-application, May 2005


Efficient photodiodes from interpenetrating polymer networks
journal, August 1995


Design Rules for Donors in Bulk-Heterojunction Solar Cells—Towards 10 % Energy-Conversion Efficiency
journal, March 2006


Method of Fabricating an Optoelectronic Device Having a Bulk Heterojunction
patent-application, October 2005


Stacked organic photosensitive devices
patent-application, February 2006


Organic photosensitive optoelectronic device with an exciton blocking layer
patent, September 2002


p‐i‐n like behavior in three‐layered organic solar cells having a co‐deposited interlayer of pigments
journal, October 1992


Transparent, Conductive Carbon Nanotube Films
journal, August 2004


A Hybrid Planar-Mixed Molecular Heterojunction Photovoltaic Cell
journal, January 2005


Relationship between electroluminescence and current transport in organic heterojunction light‐emitting devices
journal, May 1996


Interface modification to optimize charge separation in cyanine heterojunction photovoltaic devices
journal, May 2005


A method of printing carbon nanotube thin films
journal, March 2006


4.2% efficient organic photovoltaic cells with low series resistances
journal, April 2004


Photoluminescence quenching of Alq3 by metal deposition: A surface analytical investigation
journal, May 1998

  • Choong, V.-E.; Park, Y.; Gao, Y.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 16, Issue 3, p. 1838-1841
  • https://doi.org/10.1116/1.581115

Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C60 active layer
journal, May 2004