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Title: Methods of forming boron nitride

Abstract

A method of forming a boron nitride. The method comprises contacting a metal article with a monomeric boron-nitrogen compound and converting the monomeric boron-nitrogen compound to a boron nitride. The boron nitride is formed on the same or a different metal article. The monomeric boron-nitrogen compound is borazine, cycloborazane, trimethylcycloborazane, polyborazylene, B-vinylborazine, poly(B-vinylborazine), or combinations thereof. The monomeric boron-nitrogen compound is polymerized to form the boron nitride by exposure to a temperature greater than approximately 100.degree. C. The boron nitride is amorphous boron nitride, hexagonal boron nitride, rhombohedral boron nitride, turbostratic boron nitride, wurzite boron nitride, combinations thereof, or boron nitride and carbon. A method of conditioning a ballistic weapon and a metal article coated with the monomeric boron-nitrogen compound are also disclosed.

Inventors:
; ; ;
Issue Date:
Research Org.:
Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1171698
Patent Number(s):
8,968,827
Application Number:
12/060,711
Assignee:
U.S. Department of Energy (Washington, DC)
DOE Contract Number:  
AC07-05ID14517
Resource Type:
Patent
Resource Relation:
Patent File Date: 2008 Apr 01
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Trowbridge, Tammy L, Wertsching, Alan K, Pinhero, Patrick J, and Crandall, David L. Methods of forming boron nitride. United States: N. p., 2015. Web.
Trowbridge, Tammy L, Wertsching, Alan K, Pinhero, Patrick J, & Crandall, David L. Methods of forming boron nitride. United States.
Trowbridge, Tammy L, Wertsching, Alan K, Pinhero, Patrick J, and Crandall, David L. Tue . "Methods of forming boron nitride". United States. https://www.osti.gov/servlets/purl/1171698.
@article{osti_1171698,
title = {Methods of forming boron nitride},
author = {Trowbridge, Tammy L and Wertsching, Alan K and Pinhero, Patrick J and Crandall, David L},
abstractNote = {A method of forming a boron nitride. The method comprises contacting a metal article with a monomeric boron-nitrogen compound and converting the monomeric boron-nitrogen compound to a boron nitride. The boron nitride is formed on the same or a different metal article. The monomeric boron-nitrogen compound is borazine, cycloborazane, trimethylcycloborazane, polyborazylene, B-vinylborazine, poly(B-vinylborazine), or combinations thereof. The monomeric boron-nitrogen compound is polymerized to form the boron nitride by exposure to a temperature greater than approximately 100.degree. C. The boron nitride is amorphous boron nitride, hexagonal boron nitride, rhombohedral boron nitride, turbostratic boron nitride, wurzite boron nitride, combinations thereof, or boron nitride and carbon. A method of conditioning a ballistic weapon and a metal article coated with the monomeric boron-nitrogen compound are also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {3}
}

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Works referenced in this record:

Experience with boron-carbide coated target tiles in JET
journal, May 1993


Studies of Boron-Nitrogen Compounds. III. Preparation and Properties of Hexahydroborazole, B3N3H12
journal, July 1961

  • Dahl, Gerd H.; Schaeffer, Riley
  • Journal of the American Chemical Society, Vol. 83, Issue 14, p. 3032-3034
  • DOI: 10.1021/ja01475a014

Studies of Boron-Nitrogen Compounds. V. Two Isomers of 1,3,5-Trimethylcycloborazane
journal, February 1963

  • Gaines, Donald F.; Schaeffer, Riley.
  • Journal of the American Chemical Society, Vol. 85, Issue 4, p. 395-397
  • DOI: 10.1021/ja00887a006

Ab Initio Study of the Isoelectronic Molecules BCN, BNC, and C3 Including Anharmonicity
journal, June 1994

  • Martin, Jan M. L.; Taylor, Peter R.
  • The Journal of Physical Chemistry, Vol. 98, Issue 24, p. 6105-6109
  • DOI: 10.1021/j100075a010

Contribution to the Chemistry of Boron, 241. Improved Synthesis of 2,4,6-Trichloroborazine
journal, November 1997

  • Nöth, Heinrich; Sachdev, Hermann
  • Zeitschrift für Naturforschung B, Vol. 52, Issue 11
  • DOI: 10.1515/znb-1997-1112

Convenient Procedures for the Laboratory Preparation of Borazine
journal, February 1995

  • Wideman, Thomas; Sneddon, Larry G.
  • Inorganic Chemistry, Vol. 34, Issue 4
  • DOI: 10.1021/ic00108a039