Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid

Dumesic, James A; Wettstein, Stephanie G; Alonso, David Martin; Gurbuz, Elif Ispir

Advanced Search OptionsAdvanced Search queries use a traditional Term Search. For more info, see our FAQ.

All Fields:

Patent Title:

Abstract:

Assignee:

Inventor(s):

Patent Number:

Patent Classification (CPC):

All Classifications
A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
E03 - water supply
E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
E21 - earth drilling
E99 - subject matter not otherwise provided for in this section
F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
G10 - musical instruments
G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
G99 - subject matter not otherwise provided for in this section
H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
H99 - subject matter not otherwise provided for in this section
Y - new / cross sectional technologies
Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

More Options ...

Title: Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid

Abstract

A method to produce levulinic acid (LA) and gamma-valerolactone (GVL) from biomass-derived cellulose or lignocellulose by selective extraction of LA using GVL and optionally converting the LA so isolated into GVL, with no purifications steps required to yield the GVL.

Inventors:: Dumesic, James A; Wettstein, Stephanie G; Alonso, David Martin; Gurbuz, Elif Ispir

Issue Date:: Tue Feb 24 00:00:00 EST 2015

Research Org.:: Wisconsin Alumni Research Foundation, Madison, WI (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1170743

Patent Number(s):: 8962867

Application Number:: 13/327,468

Assignee:: Wisconsin Alumni Research Foundation (Madison, WI)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

Show more

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C51/00 - Preparation of carboxylic acids or their salts, halides or anhydrides
C07C51/48 - by liquid-liquid treatment
C07C59/185 - Saturated compounds having only one carboxyl group and containing keto groups
C07C67/04 - by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
C07C67/08 - by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
C07C69/716 - Esters of keto-carboxylic acids {or aldehydo-carboxylic acids}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D307/33 - in position 2, the oxygen atom being in its keto or unsubstituted enol form

Show less

DOE Contract Number:: FC02-07ER64494

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Dec 15

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Dumesic, James A, Wettstein, Stephanie G, Alonso, David Martin, and Gurbuz, Elif Ispir. Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid.  United States: N. p., 2015. 
        Web.

Copy to clipboard


                    Dumesic, James A, Wettstein, Stephanie G, Alonso, David Martin, & Gurbuz, Elif Ispir. Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid.  United States.

Copy to clipboard


                    Dumesic, James A, Wettstein, Stephanie G, Alonso, David Martin, and Gurbuz, Elif Ispir. Tue .  
        "Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid".  United States.  https://www.osti.gov/servlets/purl/1170743.

Copy to clipboard


                    
@article{osti_1170743,

  title        = {Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid},

  author       = {Dumesic, James A and Wettstein, Stephanie G and Alonso, David Martin and Gurbuz, Elif Ispir},

  abstractNote = {A method to produce levulinic acid (LA) and gamma-valerolactone (GVL) from biomass-derived cellulose or lignocellulose by selective extraction of LA using GVL and optionally converting the LA so isolated into GVL, with no purifications steps required to yield the GVL.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Feb 24 00:00:00 EST 2015},

  month        = {Tue Feb 24 00:00:00 EST 2015}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Production of levulinic acid from carbohydrate-containing materials
patent, March 1997

Fitzpatrick, Stephen W.
US Patent Document 5,608,105
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5608105

Production of levulinic acid, furfural, and gamma valerolactone from C5 and C6 carbohydrates in mono- and biphasic systems using gamma-valerolactone as a solvent
patent, March 2013

Dumesic, James A.; Alonso, David Martin; Gurbuz, Elif Ispir
US Patent Document 8,399,688
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8399688

Production of Levulinic Acid and Levulinate Esters from Biomass
patent-application, December 2010

Lake, Michael A.; Burton, Steven W.; Fuller, William Craing
US Patent Application 12/793806; 20100312006
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100312006

Determination of Chlorophenols in Potable Water: Preconcentration by Solvent Extraction, Derivatization of the Extract, and Chromatographic Analysis of the Derivatives
journal, July 2003

Korenman, Ya. I.; Gruzdev, I. V.; Kondratenok, B. M.
Journal of Analytical Chemistry, Vol. 58, Issue 7, p. 635-635
https://doi.org/10.1023/A:1024773618060

Green Chemicals
journal, May 2006

Girisuta, B.; Janssen, L. P. B. M.; Heeres, H. J.
Chemical Engineering Research and Design, Vol. 84, Issue 5
https://doi.org/10.1205/cherd05038

Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels
journal, February 2010

Bond, J. Q.; Alonso, D. M.; Wang, D.
Science, Vol. 327, Issue 5969, p. 1110-1114
https://doi.org/10.1126/science.1184362

Production of levulinic acid and use as a platform chemical for derived products
journal, February 2000

Bozell, Joseph J.; Moens, L.; Elliott, D. C.
Resources, Conservation and Recycling, Vol. 28, Issue 3-4, p. 227-239
https://doi.org/10.1016/S0921-3449(99)00047-6

Connecting Biomass and Petroleum Processing with a Chemical Bridge
journal, July 2010

Bozell, Joseph J.
Science, Vol. 329, Issue 5991, p. 522-523
https://doi.org/10.1126/science.1191662

Catalytic Conversion of Biomass-Derived Carbohydrates into γ-Valerolactone without Using an External H₂ Supply
journal, August 2009

Deng, Li; Li, Jiang; Lai, Da-Ming
Angewandte Chemie International Edition, Vol. 48, Issue 35, p. 6529-6532
https://doi.org/10.1002/anie.200902281

Gamma-valerolactone-based solvents
journal, January 2010

Fegyverneki, Dániel; Orha, László; Láng, Győző
Tetrahedron, Vol. 66, Issue 5, p. 1078-1081
https://doi.org/10.1016/j.tet.2009.11.013

A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst
journal, May 2008

Fellay, Céline; Dyson, Paul J.; Laurenczy, Gábor
Angewandte Chemie International Edition, Vol. 47, Issue 21, p. 3966-3968
https://doi.org/10.1002/anie.200800320

Selective and Flexible Transformation of Biomass-Derived Platform Chemicals by a Multifunctional Catalytic System
journal, June 2010

Geilen, Frank M. A.; Engendahl, Barthel; Harwardt, Andreas
Angewandte Chemie International Edition, Vol. 49, Issue 32, p. 5510-5514
https://doi.org/10.1002/anie.201002060

Mechanism of levulinic acid formation
journal, January 1985

Horvat, Jaroslav; Klaić, Branimir; Metelko, Biserka
Tetrahedron Letters, Vol. 26, Issue 17, p. 2111-2114
https://doi.org/10.1016/S0040-4039(00)94793-2

γ-Valerolactone—a sustainable liquid for energy and carbon-based chemicals
journal, January 2008

Horváth, István T.; Mehdi, Hasan; Fábos, Viktória
Green Chem., Vol. 10, Issue 2
https://doi.org/10.1039/B712863K

Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons
journal, June 2003

Huber, G. W.
Science, Vol. 300, Issue 5628
https://doi.org/10.1126/science.1085597

Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes
journal, October 2008

Kunkes, E. L.; Simonetti, D. A.; West, R. M.
Science, Vol. 322, Issue 5900
https://doi.org/10.1126/science.1159210

Valeric Biofuels: A Platform of Cellulosic Transportation Fuels
journal, June 2010

Lange, Jean-Paul; Price, Richard; Ayoub, Paul M.
Angewandte Chemie International Edition, Vol. 49, Issue 26, p. 4479-4483
https://doi.org/10.1002/anie.201000655

The Effect of Flow Rate of Compressed Hot Water on Xylan, Lignin, and Total Mass Removal from Corn Stover
journal, September 2003

Liu, Chaogang; Wyman, Charles E.
Industrial & Engineering Chemistry Research, Vol. 42, Issue 21, p. 5409-5416
https://doi.org/10.1021/ie030458k

Integration of Homogeneous and Heterogeneous Catalytic Processes for a Multi-step Conversion of Biomass: From Sucrose to Levulinic Acid, γ-Valerolactone, 1,4-Pentanediol, 2-Methyl-tetrahydrofuran, and Alkanes
journal, April 2008

Mehdi, Hasan; Fábos, Viktória; Tuba, Róbert
Topics in Catalysis, Vol. 48, Issue 1-4
https://doi.org/10.1007/s11244-008-9047-6

A fourier transform infrared spectroscopic study of C02 methanation on supported ruthenium
journal, May 1991

Prairie, M.
Journal of Catalysis, Vol. 129, Issue 1
https://doi.org/10.1016/0021-9517(91)90017-X

Ru-Sn catalysts for selective hydrogenation of crotonaldehyde: Effect of the Sn/(Ru+Sn) ratio
journal, February 2007

Riguetto, B. A.; Rodrigues, C. E. C.; Morales, M. A.
Applied Catalysis A: General, Vol. 318, p. 70-78
https://doi.org/10.1016/j.apcata.2006.10.045

Conversion of cellulose to hydrocarbon fuels by progressive removal of oxygen
journal, October 2010

Serrano-Ruiz, Juan Carlos; Braden, Drew J.; West, Ryan M.
Applied Catalysis B: Environmental, Vol. 100, Issue 1-2, p. 184-189
https://doi.org/10.1016/j.apcatb.2010.07.029

Selective hydrogenation of α,β-unsaturated carbonyl compounds on supported Ru-Sn catalysts
journal, November 2005

Špringerová, Jana; Kačer, Petr; Červený, Libor
Research on Chemical Intermediates, Vol. 31, Issue 9
https://doi.org/10.1163/156856705774576236

Synthesis of γ-Valerolactone by Hydrogenation of Biomass-derived Levulinic Acid over Ru/C Catalyst
journal, August 2009

Yan, Zhi-pei; Lin, Lu; Liu, Shijie
Energy & Fuels, Vol. 23, Issue 8
https://doi.org/10.1021/ef900259h

Production of Biofuels from Cellulose and Corn Stover Using Alkylphenol Solvents
journal, June 2011

Alonso, David Martin; Wettstein, Stephanie G.; Bond, Jesse Q.
ChemSusChem, Vol. 4, Issue 8
https://doi.org/10.1002/cssc.201100256

Conversion of Hemicellulose to Furfural and Levulinic Acid using Biphasic Reactors with Alkylphenol Solvents
journal, January 2012

Gürbüz, Elif I.; Wettstein, Stephanie G.; Dumesic, James A.
ChemSusChem, Vol. 5, Issue 2, p. 383-387
https://doi.org/10.1002/cssc.201100608

Works referencing / citing this record: