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Title: Hybrid particles and associated methods

Abstract

Hybrid particles that comprise a coating surrounding a chalcopyrite material, the coating comprising a metal, a semiconductive material, or a polymer; a core comprising a chalcopyrite material and a shell comprising a functionalized chalcopyrite material, the shell enveloping the core; or a reaction product of a chalcopyrite material and at least one of a reagent, heat, and radiation. Methods of forming the hybrid particles are also disclosed.

Inventors:
; ; ;
Issue Date:
Research Org.:
Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1169628
Patent Number(s):
8,951,446
Application Number:
13/365,800
Assignee:
Battelle Energy Alliance, LLC (Idaho Falls, ID)
DOE Contract Number:  
AC07-05ID14517
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS

Citation Formats

Fox, Robert V, Rodriguez, Rene, Pak, Joshua J, and Sun, Chivin. Hybrid particles and associated methods. United States: N. p., 2015. Web.
Fox, Robert V, Rodriguez, Rene, Pak, Joshua J, & Sun, Chivin. Hybrid particles and associated methods. United States.
Fox, Robert V, Rodriguez, Rene, Pak, Joshua J, and Sun, Chivin. Tue . "Hybrid particles and associated methods". United States. https://www.osti.gov/servlets/purl/1169628.
@article{osti_1169628,
title = {Hybrid particles and associated methods},
author = {Fox, Robert V and Rodriguez, Rene and Pak, Joshua J and Sun, Chivin},
abstractNote = {Hybrid particles that comprise a coating surrounding a chalcopyrite material, the coating comprising a metal, a semiconductive material, or a polymer; a core comprising a chalcopyrite material and a shell comprising a functionalized chalcopyrite material, the shell enveloping the core; or a reaction product of a chalcopyrite material and at least one of a reagent, heat, and radiation. Methods of forming the hybrid particles are also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {2}
}

Patent:

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Works referenced in this record:

Ultrasmall Metal Oxide Particles: Preparation, Photophysical Characterization, and Photocatalytic Properties
journal, January 1993


Ternary single-source precursors for polycrystalline thin-film solar cells
journal, January 2002

  • Banger, Kulbinder K.; Hollingsworth, Jennifer A.; Harris, Jerry D.
  • Applied Organometallic Chemistry, Vol. 16, Issue 11, p. 617-627
  • DOI: 10.1002/aoc.362

A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I−III−VI Semiconductors
journal, December 2003

  • Banger, Kulbinder K.; Jin, Michael H. -C.; Harris, Jerry D.
  • Inorganic Chemistry, Vol. 42, Issue 24
  • DOI: 10.1021/ic034802h

Synthesis and Characterization of the First Liquid Single-Source Precursors for the Deposition of Ternary Chalcopyrite (CuInS 2 ) Thin Film Materials
journal, November 2001

  • Banger, Kulbinder K.; Cowen, Jonathan; Hepp, Aloysius F.
  • Chemistry of Materials, Vol. 13, Issue 11
  • DOI: 10.1021/cm010507o

Optimization of Microwave Digestion for Mercury Determination in Marine Biological Samples by Cold Vapour Atomic Absorption Spectrometry
journal, April 2006

  • Cardellicchio, Nicola; di Leo, Antonella; Giandomenico, Santina
  • Annali di Chimica, Vol. 96, Issue 3-4
  • DOI: 10.1002/adic.200690016

Synthesis and Characterization of Colloidal CuInS 2 Nanoparticles from a Molecular Single-Source Precursor
journal, August 2004

  • Castro, Stephanie L.; Bailey, Sheila G.; Raffaelle, Ryne P.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 33
  • DOI: 10.1021/jp049107p

Nanocrystalline Chalcopyrite Materials (CuInS 2 and CuInSe 2 ) via Low-Temperature Pyrolysis of Molecular Single-Source Precursors
journal, August 2003

  • Castro, Stephanie L.; Bailey, Sheila G.; Raffaelle, Ryne P.
  • Chemistry of Materials, Vol. 15, Issue 16
  • DOI: 10.1021/cm034161o

One-Pot Synthesis of Copper−Indium Sulfide Nanocrystal Heterostructures with Acorn, Bottle, and Larva Shapes
journal, March 2006

  • Choi, Sang-Hyun; Kim, Eung-Gyu; Hyeon, Taeghwan
  • Journal of the American Chemical Society, Vol. 128, Issue 8
  • DOI: 10.1021/ja0577342

Phase Transformation of Biphasic Cu 2 S−CuInS 2 to Monophasic CuInS 2 Nanorods
journal, April 2009

  • Connor, Stephen T.; Hsu, Ching-Mei; Weil, Benjamin D.
  • Journal of the American Chemical Society, Vol. 131, Issue 13
  • DOI: 10.1021/ja809901u

Sol-Gel TiO2 thin films sensitized with the mulberry pigment cyanidin
journal, December 2007


Novel Bimetallic Thiocarboxylate Compounds as Single-Source Precursors to Binary and Ternary Metal Sulfide Materials
journal, June 2003

  • Deivaraj, Theivanayagam C.; Park, Jin-Ho; Afzaal, Mohammad
  • Chemistry of Materials, Vol. 15, Issue 12
  • DOI: 10.1021/cm031027v

Single-source precursors to ternary silver indium sulfide materials
journal, October 2001

  • Deivaraj, Theivanayagam C.; Park, Jin-Ho; Afzaal, Mohammmad
  • Chemical Communications, Issue 22
  • DOI: 10.1039/B106923C

Surface structure of CuGaSe2 (001)
journal, June 2005


Comparison of three optimized digestion methods for rapid determination of chemical oxygen demand: Closed microwaves, open microwaves and ultrasound irradiation
journal, March 2006

  • Domini, Claudia E.; Hidalgo, Montserrat; Marken, Frank
  • Analytica Chimica Acta, Vol. 561, Issue 1-2, p. 210-217
  • DOI: 10.1016/j.aca.2006.01.022

A facile route to the synthesis of CuInS2 nanoparticles
journal, August 2006


Microwave-assisted alkaline digestion combined with microwave-assisted distillation for the determination of iodide and total iodine in edible seaweed by catalytic spectrophotometry
journal, June 2005

  • Gamallo-Lorenzo, Diego; Barciela-Alonso, María del Carmen; Moreda-Piñeiro, Antonio
  • Analytica Chimica Acta, Vol. 542, Issue 2, p. 287-295
  • DOI: 10.1016/j.aca.2005.04.002

Green chemistry: Efficient epoxides ring-opening with 1-butanol under microwave irradiation
journal, June 2006

  • García-Vidal, Jesús A.; Durán-Valle, Carlos J.; Ferrera-Escudero, Santiago
  • Applied Surface Science, Vol. 252, Issue 17, p. 6064-6066
  • DOI: 10.1016/j.apsusc.2005.11.003

Rapid synthesis and size control of CuInS2 semi-conductor nanoparticles using microwave irradiation
journal, October 2007

  • Gardner, Joseph S.; Shurdha, Endrit; Wang, Chongmin
  • Journal of Nanoparticle Research, Vol. 10, Issue 4
  • DOI: 10.1007/s11051-007-9294-7

Microwave-Enhanced Reaction Rates for Nanoparticle Synthesis
journal, November 2005

  • Gerbec, Jeffrey A.; Magana, Donny; Washington, Aaron
  • Journal of the American Chemical Society, Vol. 127, Issue 45
  • DOI: 10.1021/ja052463g

Perspectives for dye-sensitized nanocrystalline solar cells
journal, January 2000


Microwave-Assisted Polyol Synthesis of CuInTe 2 and CuInSe 2 Nanoparticles
journal, November 2003

  • Grisaru, Haviv; Palchik, Oleg; Gedanken, Aharon
  • Inorganic Chemistry, Vol. 42, Issue 22
  • DOI: 10.1021/ic0342853

Physico-chemical characterisation of Cu(In,Al)Se2 thin film for solar cells obtained by a selenisation process
journal, June 2005


Synthesis of mixed copper-indium chalcogenolates. Single-source precursors for the photovoltaic materials CuInQ2 (Q = S, Se)
journal, February 1993

  • Hirpo, Wakgari; Dhingra, Sandeep; Sutorik, Anthony C.
  • Journal of the American Chemical Society, Vol. 115, Issue 4, p. 1597-1599
  • DOI: 10.1021/ja00057a067

Synthesis of mixed copper-indium chalcogenolates. Single-source precursors for the photovoltaic materials CuInQ2 (Q = S, Se)
journal, February 1993

  • Hirpo, Wakgari; Dhingra, Sandeep; Sutorik, Anthony C.
  • Journal of the American Chemical Society, Vol. 115, Issue 4, p. 1597-1599
  • DOI: 10.1021/ja00057a067

CdSe Nanocrystal Rods/Poly(3-hexylthiophene) Composite Photovoltaic Devices
journal, August 1999


Synthesis of CuInSe<sub>2</sub> and CuInGaSe<sub>2</sub> Nanoparticles by Solvothermal Route
journal, March 2004


Preparation and characterization of CuInS2 thin films completely converted from CuInSe2 by sulfurization
journal, June 2005


Increasing the Efficiency of Ideal Solar Cells by Photon Induced Transitions at Intermediate Levels
journal, June 1997


Changes in carrier dynamics induced by proton irradiation in quantum dots
journal, March 2002

  • Marcinkevičius, S.; Leon, R.; Čechavičius, B.
  • Physica B: Condensed Matter, Vol. 314, Issue 1-4, p. 203-206
  • DOI: 10.1016/S0921-4526(01)01361-8

Influence of Calcination Temperature on the Microstructure of Porous TiO<sub>2</sub> Film
journal, January 2008


Synthesis and Characterization of Indium Oxide Nanoparticles
journal, June 2001

  • Murali, Amith; Barve, Anirudha; Leppert, Valerie J.
  • Nano Letters, Vol. 1, Issue 6
  • DOI: 10.1021/nl010013q

Preparation of Ultrafine Chalcopyrite Nanoparticles via the Photochemical Decomposition of Molecular Single-Source Precursors
journal, June 2006

  • Nairn, Justin J.; Shapiro, Pamela J.; Twamley, Brendan
  • Nano Letters, Vol. 6, Issue 6
  • DOI: 10.1021/nl060661f

Synthesis of Metastable Wurtzite CuInSe 2 Nanocrystals
journal, March 2010

  • Norako, Michelle E.; Brutchey, Richard L.
  • Chemistry of Materials, Vol. 22, Issue 5
  • DOI: 10.1021/cm100341r

Optimisation of microwave assisted digestion of sediments and determination of Sn and Hg
journal, April 2006


Microwave assisted synthesis – a critical technology overview
journal, January 2004

  • Nüchter, M.; Ondruschka, B.; Bonrath, W.
  • Green Chem., Vol. 6, Issue 3
  • DOI: 10.1039/B310502D

Microwave-Assisted Chemical Reactions
journal, December 2003

  • Nüchter, M.; Müller, U.; Ondruschka, B.
  • Chemical Engineering & Technology, Vol. 26, Issue 12, p. 1207-1216
  • DOI: 10.1002/ceat.200301836

An efficient synthesis of 4,4′,5,5′-tetraiododibenzo-24-crown-8 and its highly conjugated derivatives
journal, January 2006


Synthesis and Characterization of Nanostructured Wurtzite CuInS 2 : A New Cation Disordered Polymorph of CuInS 2
journal, February 2009

  • Qi, Yunxia; Liu, Qiangchun; Tang, Kaibin
  • The Journal of Physical Chemistry C, Vol. 113, Issue 10
  • DOI: 10.1021/jp807987t

Pulsed-Spray Radiofrequency Plasma Enhanced Chemical Vapor Deposition of CuInS2 Thin Films
journal, April 2006

  • Rodriguez, Rene G.; Pulsipher, Daniel J. V.; Lau, Lisa D.
  • Plasma Chemistry and Plasma Processing, Vol. 26, Issue 2
  • DOI: 10.1007/s11090-006-9018-2

Enhanced Radiation Hardness of InAs/GaAs Quantum Dot Structures
journal, March 2001


A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control
journal, January 2009

  • Sun, Chivin; Gardner, Joseph S.; Shurdha, Endrit
  • Journal of Nanomaterials, Vol. 2009
  • DOI: 10.1155/2009/748567

Semiconductor Nanoparticles on Solid Substrates:  Film Structure, Intermolecular Interactions, and Polyelectrolyte Effects
journal, September 2002

  • Tang, Zhiyong; Wang, Ying; Kotov, Nicholas A.
  • Langmuir, Vol. 18, Issue 18
  • DOI: 10.1021/la025601d

Birth of a new macromolecular architecture: dendrimers as quantized building blocks for nanoscale synthetic polymer chemistry
journal, March 2005


Birth of a new macromolecular architecture: dendrimers as quantized building blocks for nanoscale synthetic polymer chemistry
journal, March 2005


Radiation hard multi-quantum well InP/InAsP. Solar cells for space applications
journal, January 2000


Synthesis of Monodispersed Wurtzite Structure CuInSe 2 Nanocrystals and Their Application in High-Performance Organic−Inorganic Hybrid Photodetectors
journal, September 2010

  • Wang, Jian-Jun; Wang, Yong-Qing; Cao, Fei-Fei
  • Journal of the American Chemical Society, Vol. 132, Issue 35
  • DOI: 10.1021/ja1057955

Nanometer-sized semiconductor clusters: materials synthesis, quantum size effects, and photophysical properties
journal, January 1991

  • Wang, Ying; Herron, N.
  • The Journal of Physical Chemistry, Vol. 95, Issue 2, p. 525-532
  • DOI: 10.1021/j100155a009

Synthesis of CuInS 2 Nanocubes by a Wet Chemical Process
journal, September 2005

  • Wei, Qinglian; Mu, Jin
  • Journal of Dispersion Science and Technology, Vol. 26, Issue 5
  • DOI: 10.1081/DIS-200057631

Applications of microwave dielectric heating in environment-related heterogeneous gas-phase catalytic systems
journal, August 2006


Microwave Assisted Preparation of CdSe, PbSe, and Cu 2 - x Se Nanoparticles
journal, August 2000

  • Zhu, Junjie; Palchik, O.; Chen, Siguang
  • The Journal of Physical Chemistry B, Vol. 104, Issue 31
  • DOI: 10.1021/jp001488t

Solution synthesis of high-quality CuInS2 quantum dots as sensitizers for TiO2 photoelectrodes
journal, January 2010

  • Li, Tzung-Luen; Teng, Hsisheng
  • Journal of Materials Chemistry, Vol. 20, Issue 18
  • DOI: 10.1039/B927279H