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Title: Processes and systems for the production of propylene glycol from glycerol

Abstract

Processes and systems for converting glycerol to propylene glycol are disclosed. The glycerol feed is diluted with propylene glycol as the primary solvent, rather than water which is typically used. The diluted glycerol feed is sent to a reactor where the glycerol is converted to propylene glycol (as well as other byproducts) in the presence of a catalyst. The propylene glycol-containing product from the reactor is recycled as a solvent for the glycerol feed.

Inventors:
; ;
Issue Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1167456
Patent Number(s):
8937202
Application Number:
12/711,053
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
DOE Contract Number:  
AC06-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 2010 Feb 23
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Frye, John G, Oberg, Aaron A, and Zacher, Alan H. Processes and systems for the production of propylene glycol from glycerol. United States: N. p., 2015. Web.
Frye, John G, Oberg, Aaron A, & Zacher, Alan H. Processes and systems for the production of propylene glycol from glycerol. United States.
Frye, John G, Oberg, Aaron A, and Zacher, Alan H. Tue . "Processes and systems for the production of propylene glycol from glycerol". United States. https://www.osti.gov/servlets/purl/1167456.
@article{osti_1167456,
title = {Processes and systems for the production of propylene glycol from glycerol},
author = {Frye, John G and Oberg, Aaron A and Zacher, Alan H},
abstractNote = {Processes and systems for converting glycerol to propylene glycol are disclosed. The glycerol feed is diluted with propylene glycol as the primary solvent, rather than water which is typically used. The diluted glycerol feed is sent to a reactor where the glycerol is converted to propylene glycol (as well as other byproducts) in the presence of a catalyst. The propylene glycol-containing product from the reactor is recycled as a solvent for the glycerol feed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {1}
}

Works referenced in this record:

Catalysts and process for hydrogenolysis of sugar alcohols to polyols
patent, September 2001


Methods of making pyrrolidones
patent, March 2004


Hydrogenolysis of 6-carbon sugars and other organic compounds
patent, January 2005


Methods of producing compounds from plant material
patent, January 2006


Textured catalysts and methods of making textured catalysts
patent, March 2007


Process for producing cyclic compounds
patent, April 2007


Process for the conversion of glycerol to propylene glycol and amino alcohols
patent, November 2009


Synthesis of Liquid Fuels and Chemicals from Oxygenated Hydrocarbons
patent-application, September 2008


Renewable Chemical Production from Novel Fatty Acid Feedstocks
patent-application, June 2010


    Works referencing / citing this record:

    Processes and systems for the production of propylene glycol from glycerol
    patent, January 2015