Alloys of clathrate allotropes for rechargeable batteries

Chan, Candace K; Miller, Michael A; Chan, Kwai S

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Title: Alloys of clathrate allotropes for rechargeable batteries

Abstract

The present disclosure is directed at an electrode for a battery wherein the electrode comprises clathrate alloys of silicon, germanium or tin. In method form, the present disclosure is directed at methods of forming clathrate alloys of silicon, germanium or tin which methods lead to the formation of empty cage structures suitable for use as electrodes in rechargeable type batteries.

Inventors:: Chan, Candace K; Miller, Michael A; Chan, Kwai S

Issue Date:: 2014-12-09

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1165134

Patent Number(s):: 8906551

Application Number:: 13/452,403

Assignee:: Southwest Research Institute (San Antonio, TX)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C - CHEMISTRY C22 - METALLURGY C22C - ALLOYS

Show more

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B33/00 - Silicon

C - CHEMISTRY C22 - METALLURGY C22C - ALLOYS
C22C1/00 - Making alloys

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/134 - Electrodes based on metals, Si or alloys
H01M4/38 - of elements or alloys
H01M4/386 - {Silicon or alloys based on silicon}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Show less

DOE Contract Number:: AC0205CH11231

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Apr 20

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats


                    Chan, Candace K, Miller, Michael A, and Chan, Kwai S. Alloys of clathrate allotropes for rechargeable batteries.  United States: N. p., 2014. 
        Web.

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                    Chan, Candace K, Miller, Michael A, & Chan, Kwai S. Alloys of clathrate allotropes for rechargeable batteries.  United States.

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                    Chan, Candace K, Miller, Michael A, and Chan, Kwai S. Tue .  
        "Alloys of clathrate allotropes for rechargeable batteries".  United States.  https://www.osti.gov/servlets/purl/1165134.

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@article{osti_1165134,

  title        = {Alloys of clathrate allotropes for rechargeable batteries},

  author       = {Chan, Candace K and Miller, Michael A and Chan, Kwai S},

  abstractNote = {The present disclosure is directed at an electrode for a battery wherein the electrode comprises clathrate alloys of silicon, germanium or tin. In method form, the present disclosure is directed at methods of forming clathrate alloys of silicon, germanium or tin which methods lead to the formation of empty cage structures suitable for use as electrodes in rechargeable type batteries.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {12}

}

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Patent:

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Works referencing / citing this record:

Hybrid silicon and carbon clathrates
patent, February 2017

Chan, Kwai S.; Miller, Michael A.
US Patent Document 9,564,633
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9564633

Nitrogen substituted carbon and silicon clathrates
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Chan, Kwai S.; Miller, Michael A.
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Similar Records

Title: Alloys of clathrate allotropes for rechargeable batteries

Abstract

Citation Formats

Clathrate compounds and processes for production thereof patent, September 1998

Wide-band-gap Si in open fourfold-coordinated clathrate structures journal, March 1994

High-pressure properties of group IV clathrates journal, September 2005

Thermoelectric materials fabricated from clathrate compounds and other materials which form an inclusion complex and method for optimizing selected thermoelectric properties patent, February 2001

Superconductivity in Doped s p 3 Semiconductors: The Case of the Clathrates journal, December 2003

Chemical diffusion in intermediate phases in the lithium-silicon system journal, May 1981

Low Temperature Synthesis of Insertion Oxides for Lithium Batteries journal, October 1998

In Situ Optical Observations of Particle Motion in Alloy Negative Electrodes for Li-Ion Batteries journal, January 2006

Phonon density of states of silicon clathrates: Characteristic width narrowing effect with respect to the diamond phase journal, April 1999

Clathrate Compounds and Method of Manufacturing patent-application, September 2008

A New Class of Low Compressibility Materials: Clathrates of Silicon and Related Materials journal, January 2002

Small particle size multiphase Li-alloy anodes for lithium-ionbatteries journal, September 1996

Lithium-Ion Batteries book, January 2009

Clathrate compounds, manufacture thereof, and thermoelectric materials, thermoelectric modules, semiconductor materials and hard materials based thereon patent, September 2004

Clathrate Allotropes For Rechargeable Batteries patent-application, November 2012

Isotropic Volume Expansion of Particles of Amorphous Metallic Alloys in Composite Negative Electrodes for Li-Ion Batteries journal, January 2007

Decrepitation model for capacity loss during cycling of alloys in rechargeable electrochemical systems journal, January 2000

A vacuum deposited Si film having a Li extraction capacity over 2000 mAh/g with a long cycle life journal, April 2004

Pyrolytic carbon-coated silicon/Carbon Nanotube composites: promising application for Li-ion batteries journal, January 2008

Structured Silicon Anodes for Lithium Battery Applications journal, January 2003

Silicon Clathrate Anodes For Lithium-Ion Batteries patent-application, January 2012

Thermoelectric conversion material, and method for manufacturing same patent, February 2003

Clathrate compounds and method of manufacturing patent, May 2009

Si Electrodes for Li-Ion Batteries—A New Way to Look at an Old Problem journal, January 2008

Highly Reversible Lithium Storage in Nanostructured Silicon journal, January 2003

Clathrate compounds and manufacturing method thereof patent, October 2002

Crystalline-Amorphous Core−Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes journal, January 2009

In Situ AFM Measurements of the Expansion and Contraction of Amorphous Sn-Co-C Films Reacting with Lithium journal, January 2007

Electrochemical Insertion of Lithium into Multiwalled Carbon Nanotube/Silicon Composites Produced by Ballmilling journal, January 2006

Synthesis of a Si-clathrate compound, Sr8GaxSi46−x, and its electrical resistivity measurements journal, March 2002

Composite anode material of silicon/graphite/carbon nanotubes for Li-ion batteries journal, June 2006

Method of making silicon clathrates patent, July 2002

Device for Energy Conversion, Electrical Switching, and Thermal Switching patent-application, September 2011

Nanoscale Solar Cell Configuration patent-application, October 2011

High-performance lithium battery anodes using silicon nanowires journal, December 2007

Failure Modes of Silicon Powder Negative Electrode in Lithium Secondary Batteries journal, January 2004

Clathrate compounds, manufacture thereof, and thermoelectric materials, thermoelectric modules, semiconductor materials and hard materials based thereon patent-application, October 2003

Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries journal, December 2008

Phase stability and chemical composition dependence of the thermoelectric properties of the type-I clathrate Ba8AlxSi46−x (8≤x≤15) journal, May 2011

Carbanions. III. Cleavage of Tetraalkylammonium Halides by Sodium in Liquid Ammonia journal, September 1959

Clathrate allotropes for rechargeable batteries patent, May 2014

Hybrid silicon and carbon clathrates patent, February 2017

Nitrogen substituted carbon and silicon clathrates patent, June 2016

Clathrate compounds and processes for production thereof
patent, September 1998

Wide-band-gap Si in open fourfold-coordinated clathrate structures
journal, March 1994

High-pressure properties of group IV clathrates
journal, September 2005

Thermoelectric materials fabricated from clathrate compounds and other materials which form an inclusion complex and method for optimizing selected thermoelectric properties
patent, February 2001

Superconductivity in Doped $s p^{3}$ Semiconductors: The Case of the Clathrates
journal, December 2003

Chemical diffusion in intermediate phases in the lithium-silicon system
journal, May 1981

Low Temperature Synthesis of Insertion Oxides for Lithium Batteries
journal, October 1998

In Situ Optical Observations of Particle Motion in Alloy Negative Electrodes for Li-Ion Batteries
journal, January 2006

Phonon density of states of silicon clathrates: Characteristic width narrowing effect with respect to the diamond phase
journal, April 1999

Clathrate Compounds and Method of Manufacturing
patent-application, September 2008

A New Class of Low Compressibility Materials: Clathrates of Silicon and Related Materials
journal, January 2002

Small particle size multiphase Li-alloy anodes for lithium-ionbatteries
journal, September 1996

Lithium-Ion Batteries
book, January 2009

Clathrate compounds, manufacture thereof, and thermoelectric materials, thermoelectric modules, semiconductor materials and hard materials based thereon
patent, September 2004

Clathrate Allotropes For Rechargeable Batteries
patent-application, November 2012

Isotropic Volume Expansion of Particles of Amorphous Metallic Alloys in Composite Negative Electrodes for Li-Ion Batteries
journal, January 2007

Decrepitation model for capacity loss during cycling of alloys in rechargeable electrochemical systems
journal, January 2000

A vacuum deposited Si film having a Li extraction capacity over 2000 mAh/g with a long cycle life
journal, April 2004

Pyrolytic carbon-coated silicon/Carbon Nanotube composites: promising application for Li-ion batteries
journal, January 2008

Structured Silicon Anodes for Lithium Battery Applications
journal, January 2003

Silicon Clathrate Anodes For Lithium-Ion Batteries
patent-application, January 2012

Thermoelectric conversion material, and method for manufacturing same
patent, February 2003

Clathrate compounds and method of manufacturing
patent, May 2009

Si Electrodes for Li-Ion Batteries—A New Way to Look at an Old Problem
journal, January 2008

Highly Reversible Lithium Storage in Nanostructured Silicon
journal, January 2003

Clathrate compounds and manufacturing method thereof
patent, October 2002

Crystalline-Amorphous Core−Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes
journal, January 2009

In Situ AFM Measurements of the Expansion and Contraction of Amorphous Sn-Co-C Films Reacting with Lithium
journal, January 2007

Electrochemical Insertion of Lithium into Multiwalled Carbon Nanotube/Silicon Composites Produced by Ballmilling
journal, January 2006

Synthesis of a Si-clathrate compound, Sr₈Ga_xSi_46−x, and its electrical resistivity measurements
journal, March 2002

Composite anode material of silicon/graphite/carbon nanotubes for Li-ion batteries
journal, June 2006

Method of making silicon clathrates
patent, July 2002

Device for Energy Conversion, Electrical Switching, and Thermal Switching
patent-application, September 2011

Nanoscale Solar Cell Configuration
patent-application, October 2011

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Failure Modes of Silicon Powder Negative Electrode in Lithium Secondary Batteries
journal, January 2004

Clathrate compounds, manufacture thereof, and thermoelectric materials, thermoelectric modules, semiconductor materials and hard materials based thereon
patent-application, October 2003

Three-Dimensional Porous Silicon Particles for Use in High-Performance Lithium Secondary Batteries
journal, December 2008

Phase stability and chemical composition dependence of the thermoelectric properties of the type-I clathrate Ba₈Al_xSi_46−x (8≤x≤15)
journal, May 2011

Carbanions. III. Cleavage of Tetraalkylammonium Halides by Sodium in Liquid Ammonia
journal, September 1959

Clathrate allotropes for rechargeable batteries
patent, May 2014

Hybrid silicon and carbon clathrates
patent, February 2017

Nitrogen substituted carbon and silicon clathrates
patent, June 2016