Methods and systems for thermodynamic evaluation of battery state of health

Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

Title: Methods and systems for thermodynamic evaluation of battery state of health

Abstract

Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

Inventors:: Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

Issue Date:: 2014-12-02

Research Org.:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1164680

Patent Number(s):: 8901892

Application Number:: 13/866,985

Assignee:: California Institute of Technology (Pasadena, CA)

Patent Classifications (CPCs):: G - PHYSICS G01 - MEASURING G01R - MEASURING ELECTRIC VARIABLES

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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G - PHYSICS G01 - MEASURING G01R - MEASURING ELECTRIC VARIABLES
G01R31/382 - Arrangements for monitoring battery or accumulator variables, e.g. SoC
G01R31/392 - Determining battery ageing or deterioration, e.g. state of health

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/443 - {in response to temperature}
H01M10/48 - Accumulators combined with arrangements for measuring, testing or indicating condition, e.g. level or density of the electrolyte
H01M10/486 - {for measuring temperature}
H01M10/657 - by electric or electromagnetic means
H01M10/6571 - Resistive heaters
H01M10/6572 - Peltier elements or thermoelectric devices

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: FG03-00ER15035

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Apr 19

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 30 DIRECT ENERGY CONVERSION

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                    Yazami, Rachid, McMenamin, Joseph, Reynier, Yvan, and Fultz, Brent T. Methods and systems for thermodynamic evaluation of battery state of health.  United States: N. p., 2014. 
        Web.

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                    Yazami, Rachid, McMenamin, Joseph, Reynier, Yvan, & Fultz, Brent T. Methods and systems for thermodynamic evaluation of battery state of health.  United States.

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                    Yazami, Rachid, McMenamin, Joseph, Reynier, Yvan, and Fultz, Brent T. Tue .  
        "Methods and systems for thermodynamic evaluation of battery state of health".  United States.  https://www.osti.gov/servlets/purl/1164680.

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@article{osti_1164680,

  title        = {Methods and systems for thermodynamic evaluation of battery state of health},

  author       = {Yazami, Rachid and McMenamin, Joseph and Reynier, Yvan and Fultz, Brent T},

  abstractNote = {Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {12}

}

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Works referencing / citing this record:

Methods and systems for charging electrochemical cells
patent, June 2015

Yazami, Rachid
US Patent Document 9,065,292
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9065292

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The elevated temperature performance of the LiMn₂O₄/C system: failure and solutions
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Surface treatments of Li_1+xMn_2−xO₄ spinels for improved elevated temperature performance
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Thermodynamic Aspects of the Reaction of Lithium with SnP[sub 2]O[sub 7] Based Positive Electrodes
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Capacity fading of Li_xMn₂O₄ spinel electrodes studied by XRD and electroanalytical techniques
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Kinetics and thermodynamics of the lithium insertion reaction in spinel phase Li_xMn₂O₄
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Effect of sintering temperature on the characteristics of carbons based on mesocarbon microbeads
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Mathematical modeling of secondary lithium batteries
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Electrochemical-Calorimetric Studies of Lithium-Ion Cells
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Thermal study on single electrodes in lithium-ion battery
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Lithium alloy negative electrodes
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Crystal structure and cathode performance dependence on oxygen content of LiMn1.5Ni0.5O4 as a cathode material for secondary lithium batteries
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Molecular thermodynamics approach for phase behaviors of solid polymer electrolytes/salt system in lithium secondary battery on the nonrandom mixing effect: Applicability of the group-contribution method
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Phase behaviors of solid polymer electrolytes/salt system in lithium secondary battery by group-contribution method: The pressure effect
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Thermodynamic and kinetic approaches to lithium intercalation into a Li_1−δMn₂O₄ electrode using Monte Carlo simulation
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Structural determination of Li _1−y Ni _0.5 Mn _0.5 O ₂ (y = 0.5) using a combination of Rietveld analysis and the maximum entropy method
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First principles predictions for intercalation behaviour
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Theoretical dependences of the free energyand chemical potential upon compositionin intercalation systems with repulsiveinteraction between guest ions
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Electrochemical intercalation of lithium into hexagonal tungsten trioxide
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