Gel polymer electrolytes for batteries

Balsara, Nitash Pervez; Eitouni, Hany Basam; Gur, Ilan; Singh, Mohit; Hudson, William

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Title: Gel polymer electrolytes for batteries

Abstract

Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains--one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1.times.10.sup.-4 S cm.sup.-1 at 25.degree. C.

Inventors:: Balsara, Nitash Pervez; Eitouni, Hany Basam; Gur, Ilan; Singh, Mohit; Hudson, William

Issue Date:: 2014-11-18

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1164002

Patent Number(s):: 8889301

Application Number:: 12/812,214

Assignee:: Seeo, Inc. (Hayward, CA)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M2300/0085 - Immobilising or gelification of electrolyte

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Show less

DOE Contract Number:: AC02-05CH11231

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Balsara, Nitash Pervez, Eitouni, Hany Basam, Gur, Ilan, Singh, Mohit, and Hudson, William. Gel polymer electrolytes for batteries.  United States: N. p., 2014. 
        Web.

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                    Balsara, Nitash Pervez, Eitouni, Hany Basam, Gur, Ilan, Singh, Mohit, & Hudson, William. Gel polymer electrolytes for batteries.  United States.

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                    Balsara, Nitash Pervez, Eitouni, Hany Basam, Gur, Ilan, Singh, Mohit, and Hudson, William. Tue .  
        "Gel polymer electrolytes for batteries".  United States.  https://www.osti.gov/servlets/purl/1164002.

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@article{osti_1164002,

  title        = {Gel polymer electrolytes for batteries},

  author       = {Balsara, Nitash Pervez and Eitouni, Hany Basam and Gur, Ilan and Singh, Mohit and Hudson, William},

  abstractNote = {Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains--one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1.times.10.sup.-4 S cm.sup.-1 at 25.degree. C.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {11}

}

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Similar Records

Title: Gel polymer electrolytes for batteries

Abstract

Citation Formats

Electrolyte permeable diaphragm patent, January 1982

High-impact polyester/styrene-maleic anhydride copolymer blends patent, April 1986

Ion conductors patent, August 1991

Ionically conductive material having a block copolymer as the solvent patent, June 1996

Ionically conductive polymer gels patent, June 1997

Blended polymer gel electrolytes patent, August 1997

Lithium secondary battery, polymer gel electrolyte and binder for use in lithium secondary batteries patent, May 2002

Solid electrolyte secondary battery patent, January 2003

Pentacyclic anion salts or tetrazapentalene derivatives and their uses as ionic conducting materials patent, December 2004

Actuator element and production method therefor patent, January 2008

Ion gels and electronic devices utilizing ion gels patent, August 2011

Polymer electrolyte, intercalation compounds and electrodes for batteries patent-application, April 2002

Photoelectric conversion device and photo cell patent-application, November 2003

Method and apparatus for fine particle liquid suspension feed for thermal spray system and coatings formed therefrom patent-application, December 2006

Ion Gels and Electronic Devices Utilizing Ion Gels patent-application, August 2008

Solid Electrolyte Material Manufacturable by Polymer Processing Methods patent-application, March 2009

Blends of POSS−PEO( n =4) 8 and High Molecular Weight Poly(ethylene oxide) as Solid Polymer Electrolytes for Lithium Batteries journal, April 2007

Nature and properties of ionomer assemblies. II journal, December 2005

Characteristics of gel electrolytes formed by self-aggregating comb-shaped polyethers with end-functionalised side chains journal, January 2004

Physically crosslinked gel electrolytes based on a self-assembling ABA triblock copolymer journal, November 2002

Fabrication of all solid-state lithium polymer secondary batteries using PEG-borate/aluminate ester as plasticizer for polymer electrolyte journal, May 2007

A study of plasticization effects in poly(vinyl chloride) journal, March 1997

Electrolyte permeable diaphragm
patent, January 1982

High-impact polyester/styrene-maleic anhydride copolymer blends
patent, April 1986

Ion conductors
patent, August 1991

Ionically conductive material having a block copolymer as the solvent
patent, June 1996

Ionically conductive polymer gels
patent, June 1997

Blended polymer gel electrolytes
patent, August 1997

Lithium secondary battery, polymer gel electrolyte and binder for use in lithium secondary batteries
patent, May 2002

Solid electrolyte secondary battery
patent, January 2003

Pentacyclic anion salts or tetrazapentalene derivatives and their uses as ionic conducting materials
patent, December 2004

Actuator element and production method therefor
patent, January 2008

Ion gels and electronic devices utilizing ion gels
patent, August 2011

Polymer electrolyte, intercalation compounds and electrodes for batteries
patent-application, April 2002

Photoelectric conversion device and photo cell
patent-application, November 2003

Method and apparatus for fine particle liquid suspension feed for thermal spray system and coatings formed therefrom
patent-application, December 2006

Ion Gels and Electronic Devices Utilizing Ion Gels
patent-application, August 2008

Solid Electrolyte Material Manufacturable by Polymer Processing Methods
patent-application, March 2009

Blends of POSS−PEO( n =4) ₈ and High Molecular Weight Poly(ethylene oxide) as Solid Polymer Electrolytes for Lithium Batteries
journal, April 2007

Nature and properties of ionomer assemblies. II
journal, December 2005

Characteristics of gel electrolytes formed by self-aggregating comb-shaped polyethers with end-functionalised side chains
journal, January 2004

Physically crosslinked gel electrolytes based on a self-assembling ABA triblock copolymer
journal, November 2002

Fabrication of all solid-state lithium polymer secondary batteries using PEG-borate/aluminate ester as plasticizer for polymer electrolyte
journal, May 2007

A study of plasticization effects in poly(vinyl chloride)
journal, March 1997