Redox shuttles for lithium ion batteries

Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

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Title: Redox shuttles for lithium ion batteries

Abstract

Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

Inventors:: Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

Issue Date:: Tue Nov 04 00:00:00 EST 2014

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1163213

Patent Number(s):: 8877390

Application Number:: 13/113,499

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Show more

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G11/64 - characterised by additives

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0567 - characterised by the additives
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M10/4235 - {Safety or regulating additives or arrangements in electrodes, separators or electrolyte
H01M2300/0025 - Organic electrolyte
H01M2300/0028 - characterised by the solvent

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage
Y02E60/13 - Ultracapacitors, supercapacitors, double-layer capacitors

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T10/70 - Energy storage for electromobility

Show less

DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 May 23

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Weng, Wei, Zhang, Zhengcheng, and Amine, Khalil. Redox shuttles for lithium ion batteries.  United States: N. p., 2014. 
        Web.

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                    Weng, Wei, Zhang, Zhengcheng, & Amine, Khalil. Redox shuttles for lithium ion batteries.  United States.

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                    Weng, Wei, Zhang, Zhengcheng, and Amine, Khalil. Tue .  
        "Redox shuttles for lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1163213.

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@article{osti_1163213,

  title        = {Redox shuttles for lithium ion batteries},

  author       = {Weng, Wei and Zhang, Zhengcheng and Amine, Khalil},

  abstractNote = {Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Nov 04 00:00:00 EST 2014},

  month        = {Tue Nov 04 00:00:00 EST 2014}

}

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Redox shuttles for lithium ion batteries

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An electrolyte may include compounds of general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y, and at least one of R.sup.8, R.sup.9, R.sup.10, and R.sup.11 is other than H.
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Similar Records

Title: Redox shuttles for lithium ion batteries

Abstract

Citation Formats

Manually operable display device patent, June 1996

Non-aqueous electrolyte secondary battery patent, January 1998

Non-aqueous electrolyte secondary cell having shuttle agent patent, June 1998

Lithium based compounds useful as electrodes and method for preparing same patent, January 1999

Chemical overcharge protection of lithium and lithium-ion secondary batteries patent, January 1999

Overcharge protection systems for rechargeable batteries patent, March 1999

Nickel--containing compounds useful as electrodes and method for preparing same patent, May 1999

Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection patent, December 1999

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes patent, April 2000

Hydrocarbon treatment of carbonaceous materials patent, November 2000

Electrode for a lithium battery patent, March 2001

Electrode material and compositions including same patent, July 2001

Electrolyte for a rechargeable cell patent, May 2002

Electrode compositions with high coulombic efficiencies patent, August 2002

Non-aqueous electrolyte and lithium secondary battery using the same patent, January 2003

Electrode compositions having improved cycling behavior patent, December 2003

Lithium-ion batteries patent, January 2004

Amorphous electrode compositions patent, March 2004

Cathode compositions for lithium-ion batteries patent, November 2005

Cathode compositions for lithium-ion batteries patent, July 2006

Solid state synthesis of lithium ion battery cathode material patent, May 2007

Long life lithium batteries with stabilized electrodes patent, March 2009

Long life lithium batteries with stabilized electrodes patent, June 2011

Cathode compositions for lithium-ion batteries patent-application, February 2003

Grain boundary materials as electrodes for lithium ion cells patent-application, November 2003

Cathode composition for rechargeable lithium battery patent-application, June 2004

Nonaqueous electrolytic solution and lithium secondary batteries patent-application, June 2004

Amorphous electrode compositions patent-application, July 2004

Method of producing lithium ion cathode materials patent-application, September 2004

Long life lithium batteries with stabilized electrodes patent-application, January 2005

Multi-phase, silicon-containing electrode for a lithium-ion battery patent-application, February 2005

Redox shuttle for rechargeable lithium-ion cell patent-application, October 2005

Diode laser array beam homogenizer patent-application, March 2006

Anode composition for lithium ion battery patent-application, March 2006

Novel redox shuttles for overcharge protection of lithium batteries patent-application, September 2006

N-oxide redox shuttles for rechargeable lithium-ion cell patent-application, November 2006

Overcharge protection for electrochemical cells patent-application, March 2007

Battery patent-application, December 2008

Redbox shuttles for high voltage cathodes patent-application, November 2009

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries journal, January 2005

Bifunctional electrolyte additive for lithium-ion batteries journal, April 2007

Redox shuttles for safer lithium-ion batteries journal, October 2009

Understanding the Stability of Aromatic Redox Shuttles for Overcharge Protection of Lithium-Ion Cells journal, January 2006

High-Potential Redox Shuttle for Use in Lithium-Ion Batteries journal, January 2009

Manually operable display device
patent, June 1996

Non-aqueous electrolyte secondary battery
patent, January 1998

Non-aqueous electrolyte secondary cell having shuttle agent
patent, June 1998

Lithium based compounds useful as electrodes and method for preparing same
patent, January 1999

Chemical overcharge protection of lithium and lithium-ion secondary batteries
patent, January 1999

Overcharge protection systems for rechargeable batteries
patent, March 1999

Nickel--containing compounds useful as electrodes and method for preparing same
patent, May 1999

Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection
patent, December 1999

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes
patent, April 2000

Hydrocarbon treatment of carbonaceous materials
patent, November 2000

Electrode for a lithium battery
patent, March 2001

Electrode material and compositions including same
patent, July 2001

Electrolyte for a rechargeable cell
patent, May 2002

Electrode compositions with high coulombic efficiencies
patent, August 2002

Non-aqueous electrolyte and lithium secondary battery using the same
patent, January 2003

Electrode compositions having improved cycling behavior
patent, December 2003

Lithium-ion batteries
patent, January 2004

Amorphous electrode compositions
patent, March 2004

Cathode compositions for lithium-ion batteries
patent, November 2005

Cathode compositions for lithium-ion batteries
patent, July 2006

Solid state synthesis of lithium ion battery cathode material
patent, May 2007

Long life lithium batteries with stabilized electrodes
patent, March 2009

Long life lithium batteries with stabilized electrodes
patent, June 2011

Cathode compositions for lithium-ion batteries
patent-application, February 2003

Grain boundary materials as electrodes for lithium ion cells
patent-application, November 2003

Cathode composition for rechargeable lithium battery
patent-application, June 2004

Nonaqueous electrolytic solution and lithium secondary batteries
patent-application, June 2004

Amorphous electrode compositions
patent-application, July 2004

Method of producing lithium ion cathode materials
patent-application, September 2004

Long life lithium batteries with stabilized electrodes
patent-application, January 2005

Multi-phase, silicon-containing electrode for a lithium-ion battery
patent-application, February 2005

Redox shuttle for rechargeable lithium-ion cell
patent-application, October 2005

Diode laser array beam homogenizer
patent-application, March 2006

Anode composition for lithium ion battery
patent-application, March 2006

Novel redox shuttles for overcharge protection of lithium batteries
patent-application, September 2006

N-oxide redox shuttles for rechargeable lithium-ion cell
patent-application, November 2006

Overcharge protection for electrochemical cells
patent-application, March 2007

Battery
patent-application, December 2008

Redbox shuttles for high voltage cathodes
patent-application, November 2009

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries
journal, January 2005

Bifunctional electrolyte additive for lithium-ion batteries
journal, April 2007

Redox shuttles for safer lithium-ion batteries
journal, October 2009

Understanding the Stability of Aromatic Redox Shuttles for Overcharge Protection of Lithium-Ion Cells
journal, January 2006

High-Potential Redox Shuttle for Use in Lithium-Ion Batteries
journal, January 2009