Redox shuttles for lithium ion batteries

Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

Title: Redox shuttles for lithium ion batteries

Abstract

Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

Inventors:: Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

Issue Date:: 2014-11-04

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1163213

Patent Number(s):: 8877390

Application Number:: 13/113,499

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/13 - Ultracapacitors, supercapacitors, double-layer capacitors

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0568 - characterised by the solutes
H01M10/052 - Li-accumulators

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0569 - characterised by the solvents
H01M10/4235 - {Safety or regulating additives or arrangements in electrodes, separators or electrolyte
H01M2300/0025 - Organic electrolyte
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0567 - characterised by the additives

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T10/70 - Energy storage for electromobility

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G11/64 - characterised by additives
H01G9/038 - {Electrolytes specially adapted for double-layer capacitors}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M2300/0028 - characterised by the solvent

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DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 May 23

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Weng, Wei, Zhang, Zhengcheng, and Amine, Khalil. Redox shuttles for lithium ion batteries.  United States: N. p., 2014. 
        Web.

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                    Weng, Wei, Zhang, Zhengcheng, & Amine, Khalil. Redox shuttles for lithium ion batteries.  United States.

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                    Weng, Wei, Zhang, Zhengcheng, and Amine, Khalil. Tue .  
        "Redox shuttles for lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1163213.

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@article{osti_1163213,

  title        = {Redox shuttles for lithium ion batteries},

  author       = {Weng, Wei and Zhang, Zhengcheng and Amine, Khalil},

  abstractNote = {Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {11}

}

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Works referenced in this record:

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries
journal, January 2005

Chen, Jun; Buhrmester, Claudia; Dahn, J. R.
Electrochemical and Solid-State Letters, Vol. 8, Issue 1
https://doi.org/10.1149/1.1836119

Bifunctional electrolyte additive for lithium-ion batteries
journal, April 2007

Chen, Zonghai; Amine, K.
Electrochemistry Communications, Vol. 9, Issue 4, p. 703-707
https://doi.org/10.1016/j.elecom.2006.11.002

Redox shuttles for safer lithium-ion batteries
journal, October 2009

Chen, Zonghai; Qin, Yan; Amine, Khalil
Electrochimica Acta, Vol. 54, Issue 24, p. 5605-5613
https://doi.org/10.1016/j.electacta.2009.05.017

Understanding the Stability of Aromatic Redox Shuttles for Overcharge Protection of Lithium-Ion Cells
journal, January 2006

Chen, Zonghai; Wang, Qingzheng; Amine, K.
Journal of The Electrochemical Society, Vol. 153, Issue 12
https://doi.org/10.1149/1.2352048

High-Potential Redox Shuttle for Use in Lithium-Ion Batteries
journal, January 2009

Moshurchak, L. M.; Lamanna, W. M.; Bulinski, Mike
Journal of The Electrochemical Society, Vol. 156, Issue 4, p. A309-A312
https://doi.org/10.1149/1.3077578

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Similar Records

Title: Redox shuttles for lithium ion batteries

Abstract

Citation Formats

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries journal, January 2005

Bifunctional electrolyte additive for lithium-ion batteries journal, April 2007

Redox shuttles for safer lithium-ion batteries journal, October 2009

Understanding the Stability of Aromatic Redox Shuttles for Overcharge Protection of Lithium-Ion Cells journal, January 2006

High-Potential Redox Shuttle for Use in Lithium-Ion Batteries journal, January 2009

Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries
journal, January 2005

Bifunctional electrolyte additive for lithium-ion batteries
journal, April 2007

Redox shuttles for safer lithium-ion batteries
journal, October 2009

Understanding the Stability of Aromatic Redox Shuttles for Overcharge Protection of Lithium-Ion Cells
journal, January 2006

High-Potential Redox Shuttle for Use in Lithium-Ion Batteries
journal, January 2009