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Title: Electrodes including a polyphosphazene cyclomatrix, methods of forming the electrodes, and related electrochemical cells

An electrode comprising a polyphosphazene cyclomatrix and particles within pores of the polyphosphazene cyclomatrix. The polyphosphazene cyclomatrix comprises a plurality of phosphazene compounds and a plurality of cross-linkages. Each phosphazene compound of the plurality of phosphazene compounds comprises a plurality of phosphorus-nitrogen units, and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. Each phosphorus-nitrogen unit is bonded to an adjacent phosphorus-nitrogen unit. Each cross-linkage of the plurality of cross-linkages bonds at least one pendant group of one phosphazene compound of the plurality of phosphazene compounds with the at least one pendant group of another phosphazene compound of the plurality of phosphazene compounds. A method of forming a negative electrode and an electrochemical cell are also described.
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Issue Date:
OSTI Identifier:
Battelle Energy Alliance, LLC (Idaho Falls, ID) INL
Patent Number(s):
Application Number:
Contract Number:
Resource Relation:
Patent File Date: 2012 Jan 27
Research Org:
Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Org:
Country of Publication:
United States

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Synthesis and characterization of poly{hexakis[(methyl)(4-hydroxyphenoxy)]cyclotriphosphazene}
journal, January 2001
  • Luther, Thomas A.; Stewart, Frederick F.; Lash, Robert P.
  • Journal of Applied Polymer Science, Vol. 82, Issue 14, p. 3439-3446
  • DOI: 10.1002/app.2205

Reactions and polymerization of hexa-[3-tert-butyl-4- hydroxyphenoxy]cyclotriphosphazene: A new method for the preparation of soluble cyclomatrix phosphazene polymers
journal, January 2001

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