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Title: Preparation of metal-triazolate frameworks

Abstract

The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

Inventors:
; ; ;
Issue Date:
Research Org.:
Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1160213
Patent Number(s):
8852320
Application Number:
13/354,574
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
DOE Contract Number:  
SC0001342
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Jan 20
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Yaghi, Omar M, Uribe-Romo, Fernando J, Gandara-Barragan, Felipe, and Britt, David K. Preparation of metal-triazolate frameworks. United States: N. p., 2014. Web.
Yaghi, Omar M, Uribe-Romo, Fernando J, Gandara-Barragan, Felipe, & Britt, David K. Preparation of metal-triazolate frameworks. United States.
Yaghi, Omar M, Uribe-Romo, Fernando J, Gandara-Barragan, Felipe, and Britt, David K. Tue . "Preparation of metal-triazolate frameworks". United States. https://www.osti.gov/servlets/purl/1160213.
@article{osti_1160213,
title = {Preparation of metal-triazolate frameworks},
author = {Yaghi, Omar M and Uribe-Romo, Fernando J and Gandara-Barragan, Felipe and Britt, David K},
abstractNote = {The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {10}
}

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Works referenced in this record:

Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997

  • Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
  • Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651
  • https://doi.org/10.1021/ja9715760

Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
journal, March 2009


High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes
journal, January 2011


Tailored Porous Materials
journal, October 1999


1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal–organic frameworks
journal, November 2001


Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009


Ring-Opening Reactions within Porous Metal−Organic Frameworks
journal, July 2010


Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
  • https://doi.org/10.1021/ja8036096

Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework
journal, August 2005


Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology
journal, August 2003


Tertiary Building Units:  Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1)
October 2001


A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
journal, February 2006


Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate)
journal, November 2000


High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005


Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates
journal, June 2009


Transformation of a Metal−Organic Framework from the NbO to PtS Net
journal, January 2005


Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework
journal, August 2011


Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition
journal, July 2012


Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008)
journal, April 2008


Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds
journal, February 2010


In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues
journal, December 2009


Industrial applications of metal–organic frameworks
journal, January 2009


Three-periodic nets and tilings: edge-transitive binodal structures
journal, August 2006


What do we know about three-periodic nets?
journal, August 2005


Taxonomy of periodic nets and the design of materials
journal, January 2007


The CdSO4, rutile, cooperite and quartz dual nets: interpenetration and catenation
journal, January 2003


Three-periodic nets and tilings: regular and quasiregular nets
journal, December 2002


Three-periodic nets and tilings: semiregular nets
journal, October 2003


Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls
journal, December 2003


Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity
journal, January 2008


Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:  A Framework Deliberately Designed To Have the NbO Structure Type
journal, January 2002


Geometric requirements and examples of important structures in the assembly of square building blocks
journal, April 2002


Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000


A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers
journal, July 2005


Positronium formation in porous materials for antihydrogen production
journal, April 2010


Isomers of Metal–Organic Complex Arrays
journal, June 2012


Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal–organic frameworks
journal, January 2007


Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
journal, September 2009

  • Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.
  • Journal of the American Chemical Society, Vol. 131, Issue 38, p. 13613-13615
  • https://doi.org/10.1021/ja904189d

Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs
journal, March 2010


MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011


Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids
journal, January 2005


Polymer-Induced Heteronucleation for the Discovery of New Extended Solids
journal, April 2006


Topological Control in Heterometallic Metal−Organic Frameworks by Anion Templating and Metalloligand Design
journal, November 2006


Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007


Zeolite A imidazolate frameworks
journal, May 2007


Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
journal, February 2007


Metal-organic frameworks—New materials for hydrogen storage
journal, April 2007


Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air
journal, March 2009


A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008


An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids
journal, January 2002


Synthesis and Gas Sorption Properties of a Metal-Azolium Framework (MAF) Material
journal, November 2009


[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity
journal, April 2003


20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001


An Open-Framework Germanate with Polycubane-Like Topology
journal, March 1999


Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate)
journal, March 1998


Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998


Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000


Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework
journal, June 1999


Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86
journal, August 1998


Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999


Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998


Hydrogen storage in metal-organic and covalent-organic frameworks by spillover
journal, January 2007


A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers
journal, January 2011


MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
journal, September 2007


Rotaxanes as ligands: from molecules to materials
journal, January 2007


Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009


Porphyrin-based nanoporous network polymers
journal, October 2002


Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833
  • https://doi.org/10.1021/jp1044139

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005


A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010


Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation
journal, October 2011


NMR and X-ray Study Revealing the Rigidity of Zeolitic Imidazolate Frameworks
journal, June 2012


Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011


Non-carboxylate based metal-organic frameworks (MOFs) and related aspects
journal, June 2009


Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005


Synthesis, Structure Determination, and Hydrogen Sorption Studies of New Metal−Organic Frameworks Using Triazole and Naphthalenedicarboxylic Acid
journal, March 2007


Hyperpolarized 129Xe Nuclear Magnetic Resonance Studies of Isoreticular Metal-Organic Frameworks
journal, April 2007


Ammonia Vapor Removal by Cu3(BTC)2 and Its Characterization by MAS NMR
journal, August 2009


Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010


A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
journal, December 2001


Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters
journal, February 2003


Synthesis and Characterization of Zirconogermanates
journal, September 2003


Site-Specific CO2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network
journal, December 2011


A Microporous Lanthanide-Organic Framework
journal, September 1999


From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999


Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1
journal, May 2000


Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks
journal, January 2002


Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910
  • https://doi.org/10.1021/ja0542690

Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
journal, August 2005


Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004

  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667
  • https://doi.org/10.1021/ja049408c

Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005


Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction
journal, January 2006


A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks
journal, April 2006


Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network
journal, October 2006


Hydrogen Storage in New Metal–Organic Frameworks
journal, June 2012

  • Tranchemontagne, David J.; Park, Kyo Sung; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13143-13151
  • https://doi.org/10.1021/jp302356q

Role of Exposed Metal Sites in Hydrogen Storage in MOFs
journal, July 2008


Computation of Aromatic C3N4 Networks and Synthesis of the Molecular Precursor N(C3N3)3Cl6
journal, September 2003


One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)
journal, May 2002

  • Vodak, David T.; Braun, Matthew; Iordanidis, Lykourgos
  • Journal of the American Chemical Society, Vol. 124, Issue 18, p. 4942-4943
  • https://doi.org/10.1021/ja017683i

A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework
journal, November 2008


Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008


Structural study of new hydrocarbon nano-crystals by energy-filtered electron diffraction
journal, January 2004


A Molecular Railroad with Large Pores:  Synthesis and Structure of Ni(4,4‘-bpy)2.5(H2O)2(ClO4)2·1.5(4,4‘-bpy)·2H2O
journal, September 1997


Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
journal, January 1996


Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks
journal, January 1995


Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion
journal, May 1997


Mutually Interpenetrating Sheets and Channels in the Extended Structure of [Cu(4,4′-bpy)Cl]
journal, February 1995


Reticular Chemistry and Metal-Organic Frameworks for Clean Energy
journal, September 2009


Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
journal, March 1997


Synthesis and Structure of a Metal-Organic Solid Having the Cadmium(II) Sulfate Net
journal, January 1996


Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4
journal, July 1995


T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3
journal, January 1996


Two Novel Triazole-Based Metal - Organic Frameworks Consolidated by a Flexible Dicarboxylate Co-ligand: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties
journal, January 2008


Syntheses, Structures, and Porous/Luminescent Properties of Silver 3-Alkyl-1,2,4-Triazolate Frameworks with Rare 3-Connected Topologies
journal, March 2011


Exceptional Framework Flexibility and Sorption Behavior of a Multifunctional Porous Cuprous Triazolate Framework
journal, May 2008


Rigid-Strut-Containing Crown Ethers and [2]Catenanes for Incorporation into Metal-Organic Frameworks
journal, November 2009


Isomeric Zinc(II) Triazolate Frameworks with 3-Connected Networks: Syntheses, Structures, and Sorption Properties
journal, April 2009