Synthesis of polyoxometalate-loaded epoxy composites

Anderson, Benjamin J

Advanced Search OptionsAdvanced Search queries use a traditional Term Search. For more info, see our FAQ.

All Fields:

Patent Title:

Abstract:

Assignee:

Inventor(s):

Patent Number:

Patent Classification (CPC):

All Classifications
A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
E03 - water supply
E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
E21 - earth drilling
E99 - subject matter not otherwise provided for in this section
F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
G10 - musical instruments
G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
G99 - subject matter not otherwise provided for in this section
H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
H99 - subject matter not otherwise provided for in this section
Y - new / cross sectional technologies
Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

More Options ...

Title: Synthesis of polyoxometalate-loaded epoxy composites

Abstract

The synthesis of a polyoxometalate-loaded epoxy uses a one-step cure by applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin. Such polyoxometalate-loaded epoxy composites afford the cured epoxy unique properties imparted by the intrinsic properties of the polyoxometalate. For example, polyoxometalate-loaded epoxy composites can be used as corrosion resistant epoxy coatings, for encapsulation of electronics with improved dielectric properties, and for structural applications with improved mechanical properties.

Inventors:: Anderson, Benjamin J

Issue Date:: 2014-10-07

Research Org.:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1160134

Patent Number(s):: 8853350

Application Number:: 13/625,969

Assignee:: Sandia Corporation (Albuquerque, NM)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

Show more

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G59/685 - {Carboxylates}

Show less

DOE Contract Number:: AC04-94AL85000

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Sep 25

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Anderson, Benjamin J. Synthesis of polyoxometalate-loaded epoxy composites.  United States: N. p., 2014. 
        Web.

Copy to clipboard


                    Anderson, Benjamin J. Synthesis of polyoxometalate-loaded epoxy composites.  United States.

Copy to clipboard


                    Anderson, Benjamin J. Tue .  
        "Synthesis of polyoxometalate-loaded epoxy composites".  United States.  https://www.osti.gov/servlets/purl/1160134.

Copy to clipboard


                    
@article{osti_1160134,

  title        = {Synthesis of polyoxometalate-loaded epoxy composites},

  author       = {Anderson, Benjamin J},

  abstractNote = {The synthesis of a polyoxometalate-loaded epoxy uses a one-step cure by applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin. Such polyoxometalate-loaded epoxy composites afford the cured epoxy unique properties imparted by the intrinsic properties of the polyoxometalate. For example, polyoxometalate-loaded epoxy composites can be used as corrosion resistant epoxy coatings, for encapsulation of electronics with improved dielectric properties, and for structural applications with improved mechanical properties.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {10}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Intermediate for composite material
patent, July 1986

Asai, Hajime; Nakao, Fujio
US Patent Document 4,603,157
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4603157

Heteropolyacids — new efficient initiators of cationic polymerization
journal, May 1989

Bednarek, Melania; Brzezińska, Krystyna; Stasiński, Jacek
Die Makromolekulare Chemie, Vol. 190, Issue 5, p. 929-938
https://doi.org/10.1002/macp.1989.021900502

Epoxy prepolymers cured with boron trifluoride‐amine complexes, 2. Polymerization mechanisms
journal, June 1990

Bouillon, Nelly; Pascault, Jean‐Pierre; Tighzert, Lan
Die Makromolekulare Chemie, Vol. 191, Issue 6, p. 1417-1433
https://doi.org/10.1002/macp.1990.021910620

Epoxy polymerization initiated by BF₃–amine complexes. I. Synthesis and characterization of BF₃–amine complexes and BF3–amine complexes dissolved in γ–butyrolactone
journal, July 1993

Chabanne, Philippe; Tighzert, Lan; Pascault, Jean-Pierre
Journal of Applied Polymer Science, Vol. 49, Issue 4, p. 685-699
https://doi.org/10.1002/app.1993.070490414

Monoepoxy polymerization initiated by BF₃-amine complexes in bulk. II. Influence of water and by-products on polymer formation
journal, August 1994

Chabanne, Philippe; Tighzert, Lan; Pascault, Jean-Pierre
Journal of Applied Polymer Science, Vol. 53, Issue 6, p. 769-785
https://doi.org/10.1002/app.1994.070530607

An Acidity Scale for Brönsted Acids Including H ₃ PW ₁₂ O ₄₀
journal, August 1997

Drago, Russell S.; Dias, José A.; Maier, Thomas O.
Journal of the American Chemical Society, Vol. 119, Issue 33
https://doi.org/10.1021/ja9639123

Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates
journal, February 1998

Gouzerh, Pierre; Proust, Anna
Chemical Reviews, Vol. 98, Issue 1
https://doi.org/10.1021/cr960393d

Alkali metal salts and ammonium salts of Keggin-type heteropolyacids as solid acid catalysts for liquid-phase Friedel-Crafts reactions
journal, November 1995

Izumi, Y.; Ogawa, M.; Urabe, K.
Applied Catalysis A: General, Vol. 132, Issue 1
https://doi.org/10.1016/0926-860X(95)00167-0

A Survey of Applications of Polyoxometalates
journal, February 1998

Katsoulis, Dimitris E.
Chemical Reviews, Vol. 98, Issue 1
https://doi.org/10.1021/cr960398a

Cationic activated monomer polymerization of heterocyclic monomers
journal, December 1999

Kubisa, P.; Penczek, S.
Progress in Polymer Science, Vol. 24, Issue 10, p. 1409-1437
https://doi.org/10.1016/S0079-6700(99)00028-3

Polyoxometalates: Building Blocks for Functional Nanoscale Systems
journal, March 2010

Long, De-Liang; Tsunashima, Ryo; Cronin, Leroy
Angewandte Chemie International Edition, Vol. 49, Issue 10, p. 1736-1758
https://doi.org/10.1002/anie.200902483

Cationic polymerization of diglycidyl ether of Bisphenol A. II. theory
journal, March 1997

Matejka, L.; Dusek, K.; Chabanne, P.
Journal of Polymer Science Part A: Polymer Chemistry, Vol. 35, Issue 4, p. 651-663
https://doi.org/10.1002/(SICI)1099-0518(199703)35:4<651::AID-POLA7>3.0.CO;2-S

Copolymerization of trioxane with phenylglycidylether
journal, February 1988

Mateva, R.; Sirashki, G.
Journal of Polymer Science Part A: Polymer Chemistry, Vol. 26, Issue 2
https://doi.org/10.1002/pola.1988.080260215

Thermoinitiated cationic polymerization of epoxy resins by sulfonium salts
journal, November 1986

Morio, Kazuhiko; Murase, Hisashi; Tsuchiya, Hiroshi
Journal of Applied Polymer Science, Vol. 32, Issue 7, p. 5727-5732
https://doi.org/10.1002/app.1986.070320705

Cationic cure of epoxy resin initiated by methylanilinium salts as a latent thermal initiator
journal, January 2001

Park, Soo-Jin; Kim, Taek-Jin; Lee, Jae-Rock
Journal of Polymer Science Part B: Polymer Physics, Vol. 39, Issue 20
https://doi.org/10.1002/polb.1211

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science
journal, January 2008

Proust, Anna; Thouvenot, René; Gouzerh, Pierre
Chemical Communications, Issue 16
https://doi.org/10.1039/B715502F

Heterocyclic amine salts of Keggin heteropolyacids used as catalyst for the selective oxidation of sulfides to sulfoxides
journal, February 2008

Sathicq, Angel G.; Romanelli, Gustavo P.; Palermo, Valeria
Tetrahedron Letters, Vol. 49, Issue 9, p. 1441-1444
https://doi.org/10.1016/j.tetlet.2008.01.009

Polyimide/polyoxometalate copolymer thin films: synthesis, thermal and dielectric properties
journal, January 2009

Tan, Lin; Liu, Shumei; Zeng, Fang
Polymers for Advanced Technologies
https://doi.org/10.1002/pat.1454

The linear relations and living feature in cationic ring-opening copolymerization of epoxy/THF system
journal, January 2008

Wu, Qili; Li, Liang; Yu, Yingfeng
Colloid and Polymer Science, Vol. 286, Issue 6-7
https://doi.org/10.1007/s00396-007-1832-4

Simultaneous cationic polymerization and esterification of epoxy/anhydride system in the presence of polyoxometalate catalyst
journal, March 2010

Yu, Yingfeng; Zhong, Xinhui; Su, Huihang
Polymer, Vol. 51, Issue 7, p. 1563-1571
https://doi.org/10.1016/j.polymer.2010.02.007

One-Component, Low-Temperature, and Fast Cure Epoxy Encapsulant With High Refractive Index for LED Applications
journal, August 2008

Yan Zhou,
IEEE Transactions on Advanced Packaging, Vol. 31, Issue 3
https://doi.org/10.1109/TADVP.2008.924233

Similar Records in DOE Patents and OSTI.GOV collections:

Photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts

Patent Hill, Craig L.; Gueletii, Iourii V.; Song, Jie; ...

This disclosure relates to photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. In certain embodiments, the disclosure relates to compositions comprising water, a complex of a tetra-metal oxide cluster and VW.sub.9O.sub.34 ligands, and a photosensitizer. Typically, the metal oxide cluster is Co. In certain embodiments, the disclosure relates to electrodes and other devices comprising water oxidation catalysts disclosed herein and uses in generating fuels and electrical power from solar energy.
Full Text Available
High performance, rapid thermal/UV curing epoxy resin for additive manufacturing of short and continuous carbon fiber epoxy composites

Patent Lewicki, James

An additive manufacturing resin system including an additive manufacturing print head; a continuous carbon fiber or short carbon fibers operatively connected to the additive manufacturing print head; and a tailored resin operatively connected to the print head, wherein the tailored resin has a resin mass and wherein the tailored resin includes an epoxy component, a filler component, a catalyst component, and a chain extender component; wherein the epoxy component is 70-95% of the resin mass, wherein the filler component is 1-20% of the resin mass, wherein the catalyst component is 0.1-10% of the resin mass, and wherein the chain extendermore » component is 0-50% of the resin mass. « less
Full Text Available
High performance, rapid thermal/UV curing epoxy resin for additive manufacturing of short and continuous carbon fiber epoxy composites

Patent Lewicki, James

An additive manufacturing resin system includes a container; a build platform in the container; a build platform drive; an additive manufacturing resin that forms an additive manufacturing resin bath; an additive manufacturing print head; a build material supply connected to the additive manufacturing print head; an infill resin in the container, wherein the infill resin is supported by the additive manufacturing resin bath; a computer controller; and an extruded material that forms the product, wherein the infill resin at least partially surrounds the extruded material that forms the product. An infill resin supply provides the infill resin into the containermore » « less
Full Text Available
Method of making superhydrophobic/superoleophilic paints, epoxies, and composites

Patent Simpson, John T.; Hunter, Scott Robert

Superhydrophobic paints and epoxies comprising superoleophilic particles and surfaces and methods of making the same are described. The superoleophilic particles can include porous particles having a hydrophobic coating layer deposited thereon. superoleophilic particles.
Full Text Available
Epoxy-borax-coal tar composition for a radiation protective, burn resistant drum liner and centrifugal casting method

Patent Taylor, Robert S [Livermore, CA]; Boyer, Norman W [Livermore, CA]

A boron containing burn resistant, low level radiation protection material useful, for example, as a liner for radioactive waste disposal and storage, a component for neutron absorber, and a shield for a neutron source. The material is basically composed of Borax in the range of 25-50%, coal tar in the range of 25-37.5%, with the remainder being an epoxy resin mix. A preferred composition is 50% Borax, 25% coal tar and 25% epoxy resin. The material is not susceptible to burning and is about 1/5 the cost of existing radiation protection material utilized in similar applications.
Full Text Available

Similar Records

Title: Synthesis of polyoxometalate-loaded epoxy composites

Abstract

Citation Formats

Intermediate for composite material patent, July 1986

Heteropolyacids — new efficient initiators of cationic polymerization journal, May 1989

Epoxy prepolymers cured with boron trifluoride‐amine complexes, 2. Polymerization mechanisms journal, June 1990

Epoxy polymerization initiated by BF3–amine complexes. I. Synthesis and characterization of BF3–amine complexes and BF3–amine complexes dissolved in γ–butyrolactone journal, July 1993

Monoepoxy polymerization initiated by BF3-amine complexes in bulk. II. Influence of water and by-products on polymer formation journal, August 1994

An Acidity Scale for Brönsted Acids Including H 3 PW 12 O 40 journal, August 1997

Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates journal, February 1998

Alkali metal salts and ammonium salts of Keggin-type heteropolyacids as solid acid catalysts for liquid-phase Friedel-Crafts reactions journal, November 1995

A Survey of Applications of Polyoxometalates journal, February 1998

Cationic activated monomer polymerization of heterocyclic monomers journal, December 1999

Polyoxometalates: Building Blocks for Functional Nanoscale Systems journal, March 2010

Cationic polymerization of diglycidyl ether of Bisphenol A. II. theory journal, March 1997

Copolymerization of trioxane with phenylglycidylether journal, February 1988

Thermoinitiated cationic polymerization of epoxy resins by sulfonium salts journal, November 1986

Cationic cure of epoxy resin initiated by methylanilinium salts as a latent thermal initiator journal, January 2001

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science journal, January 2008

Heterocyclic amine salts of Keggin heteropolyacids used as catalyst for the selective oxidation of sulfides to sulfoxides journal, February 2008

Polyimide/polyoxometalate copolymer thin films: synthesis, thermal and dielectric properties journal, January 2009

The linear relations and living feature in cationic ring-opening copolymerization of epoxy/THF system journal, January 2008

Simultaneous cationic polymerization and esterification of epoxy/anhydride system in the presence of polyoxometalate catalyst journal, March 2010

One-Component, Low-Temperature, and Fast Cure Epoxy Encapsulant With High Refractive Index for LED Applications journal, August 2008

Intermediate for composite material
patent, July 1986

Heteropolyacids — new efficient initiators of cationic polymerization
journal, May 1989

Epoxy prepolymers cured with boron trifluoride‐amine complexes, 2. Polymerization mechanisms
journal, June 1990

Epoxy polymerization initiated by BF₃–amine complexes. I. Synthesis and characterization of BF₃–amine complexes and BF3–amine complexes dissolved in γ–butyrolactone
journal, July 1993

Monoepoxy polymerization initiated by BF₃-amine complexes in bulk. II. Influence of water and by-products on polymer formation
journal, August 1994

An Acidity Scale for Brönsted Acids Including H ₃ PW ₁₂ O ₄₀
journal, August 1997

Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates
journal, February 1998

Alkali metal salts and ammonium salts of Keggin-type heteropolyacids as solid acid catalysts for liquid-phase Friedel-Crafts reactions
journal, November 1995

A Survey of Applications of Polyoxometalates
journal, February 1998

Cationic activated monomer polymerization of heterocyclic monomers
journal, December 1999

Polyoxometalates: Building Blocks for Functional Nanoscale Systems
journal, March 2010

Cationic polymerization of diglycidyl ether of Bisphenol A. II. theory
journal, March 1997

Copolymerization of trioxane with phenylglycidylether
journal, February 1988

Thermoinitiated cationic polymerization of epoxy resins by sulfonium salts
journal, November 1986

Cationic cure of epoxy resin initiated by methylanilinium salts as a latent thermal initiator
journal, January 2001

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science
journal, January 2008

Heterocyclic amine salts of Keggin heteropolyacids used as catalyst for the selective oxidation of sulfides to sulfoxides
journal, February 2008

Polyimide/polyoxometalate copolymer thin films: synthesis, thermal and dielectric properties
journal, January 2009

The linear relations and living feature in cationic ring-opening copolymerization of epoxy/THF system
journal, January 2008

Simultaneous cationic polymerization and esterification of epoxy/anhydride system in the presence of polyoxometalate catalyst
journal, March 2010

One-Component, Low-Temperature, and Fast Cure Epoxy Encapsulant With High Refractive Index for LED Applications
journal, August 2008