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Title: Reducing carbon dioxide to products

Abstract

A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

Inventors:
; ; ;
Issue Date:
Research Org.:
Liquid Light, Inc., Monmouth Junction, NJ (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1159937
Patent Number(s):
8,845,878
Application Number:
13/787,304
Assignee:
Liquid Light, Inc. (Monmouth Junction, NJ)
DOE Contract Number:  
SC0006201
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Cole, Emily Barton, Sivasankar, Narayanappa, Parajuli, Rishi, and Keets, Kate A. Reducing carbon dioxide to products. United States: N. p., 2014. Web.
Cole, Emily Barton, Sivasankar, Narayanappa, Parajuli, Rishi, & Keets, Kate A. Reducing carbon dioxide to products. United States.
Cole, Emily Barton, Sivasankar, Narayanappa, Parajuli, Rishi, and Keets, Kate A. Tue . "Reducing carbon dioxide to products". United States. https://www.osti.gov/servlets/purl/1159937.
@article{osti_1159937,
title = {Reducing carbon dioxide to products},
author = {Cole, Emily Barton and Sivasankar, Narayanappa and Parajuli, Rishi and Keets, Kate A},
abstractNote = {A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {9}
}

Patent:

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Works referenced in this record:

A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential
journal, July 1994

  • Seshadri, Gayatri; Lin, Chao; Bocarsly, Andrew B.
  • Journal of Electroanalytical Chemistry, Vol. 372, Issue 1-2, p. 145-150
  • DOI: 10.1016/0022-0728(94)03300-5

Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008


Adsorption Study of CO 2 on Reticulated Vitreous Carbon (RVC) Covered with Platinum
journal, January 1985

  • Czerwinski, Andrzej; Sobkowski, Jerzy; Marassi, Roberto
  • Analytical Letters, Vol. 18, Issue 14
  • DOI: 10.1080/00032718508064473

Palladium and cobalt complexes of substituted quinoline, bipyridine and phenanthroline as catalysts for electrochemical reduction of carbon dioxide
journal, January 1997


Enhanced formation of ethylene and alcohols at ambient temperature and pressure in electrochemical reduction of carbon dioxide at a copper electrode
journal, January 1988

  • Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro
  • Journal of the Chemical Society, Chemical Communications, Issue 1
  • DOI: 10.1039/C39880000017

High Rate Gas Phase CO[sub 2] Reduction to Ethylene and Methane Using Gas Diffusion Electrodes
journal, January 1990

  • Cook, Ronald L.
  • Journal of The Electrochemical Society, Vol. 137, Issue 2
  • DOI: 10.1149/1.2086515

Electrode-confined catalyst systems for use in optical-to-chemical energy conversion
journal, May 1985

  • Daube, Karen A.; Harrison, D. Jed; Mallouk, Thomas E.
  • Journal of Photochemistry, Vol. 29, Issue 1-2, p. 71-88
  • DOI: 10.1016/0047-2670(85)87062-3

Electrochemical and Surface Studies of Carbon Dioxide Reduction to Methane and Ethylene at Copper Electrodes in Aqueous Solutions
journal, January 1989

  • DeWulf, David W.
  • Journal of The Electrochemical Society, Vol. 136, Issue 6, p. 1686-1691
  • DOI: 10.1149/1.2096993

Electrochemical reduction of CO and H2 from carbon dioxide in aqua-solution
journal, March 2010

  • Lee, Sung-Woo; Lee, Jea-Keun; Lee, Kyoung-Hag
  • Current Applied Physics, Vol. 10, Issue 2, p. S51-S54
  • DOI: 10.1016/j.cap.2009.11.040

Electrochemical Reduction of CO 2 in a Mixed Supercritical Fluid
journal, February 2000

  • Abbott, Andrew P.; Eardley, Christopher A.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 4
  • DOI: 10.1021/jp9932867

The Electroreduction of Carbon Dioxide and Formic Acid on Tin and Indium Electrodes
journal, January 1983

  • Kapusta, S.
  • Journal of The Electrochemical Society, Vol. 130, Issue 3
  • DOI: 10.1149/1.2119761

Electrochemical hydrodimerization of formaldehyde to ethylene glycol
journal, October 1991

  • Weinberg, N. L.; Mazur, D. J.
  • Journal of Applied Electrochemistry, Vol. 21, Issue 10
  • DOI: 10.1007/BF01042456

Effects of process conditions and electrode material on reaction pathways for carbon dioxide electroreduction with particular reference to formate formation
journal, December 2003


Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. I. Reduction at lead, indium- and tin-impregnated electrodes
journal, November 1987

  • Mahmood, M. N.; Masheder, D.; Harty, C. J.
  • Journal of Applied Electrochemistry, Vol. 17, Issue 6
  • DOI: 10.1007/BF01023599

The electrochemical reduction of aqueous carbon dioxide to methanol at molybdenum electrodes with low overpotentials
journal, June 1986

  • Summers, David P.; Leach, Steven; Frese, Karl W.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 205, Issue 1-2, p. 219-232
  • DOI: 10.1016/0022-0728(86)90233-0

Electrochemical Reduction of Carbon Dioxide to Methane, Methanol, and CO on Ru Electrodes
journal, January 1985

  • Frese, K. W.
  • Journal of The Electrochemical Society, Vol. 132, Issue 1
  • DOI: 10.1149/1.2113780

Reduction of CO[sub 2] on n-GaAs Electrodes and Selective Methanol Synthesis
journal, January 1984

  • Frese, K. W.
  • Journal of The Electrochemical Society, Vol. 131, Issue 11
  • DOI: 10.1149/1.2115351

Electrochemical synthesis of urea at gas-diffusion electrodes
journal, January 1998

  • Shibata, Masami; Yoshida, Kohji; Furuya, Nagakazu
  • Journal of Electroanalytical Chemistry, Vol. 442, Issue 1-2, p. 67-72
  • DOI: 10.1016/S0022-0728(97)00504-4

Simultaneous reduction of carbon dioxide and nitrate ions at gas-diffusion electrodes with various metallophthalocyanine catalysts
journal, November 2003


A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
journal, August 2006


Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. II. Reduction at metal phthalocyanine-impregnated electrodes
journal, November 1987

  • Mahmood, M. N.; Masheder, D.; Harty, C. J.
  • Journal of Applied Electrochemistry, Vol. 17, Issue 6
  • DOI: 10.1007/BF01023606

Homogeneous Electron Transfer Catalysis of the Electrochemical Reduction of Carbon Dioxide. Do Aromatic Anion Radicals React in an Outer-Sphere Manner?
journal, January 1996

  • Gennaro, Armando; Isse, Abdirisak A.; Savéant, Jean-Michel
  • Journal of the American Chemical Society, Vol. 118, Issue 30
  • DOI: 10.1021/ja960605o

Electrochemical reduction of CO2 on platinum electrodes in acid solutions
journal, November 1963


Hydrogen overpotential for transition metals and alloys, and its interpretation using an electronic model
journal, March 1993


The electrolytic reduction of carbon dioxide to formic acid
journal, September 1971


Temperature Dependence of the Probability of Chain Growth for Hydrocarbon Formation by Electrochemical Reduction of CO 2
journal, November 2001

  • Ougitani, Yasushi; Aizawa, Tatuya; Sonoyama, Noriyuki
  • Bulletin of the Chemical Society of Japan, Vol. 74, Issue 11
  • DOI: 10.1246/bcsj.74.2119

High performance RuPd catalysts for CO2 reduction at gas-diffusion electrodes
journal, June 1997

  • Furuya, Nagakazu; Yamazaki, Tsuyoshi; Shibata, Masami
  • Journal of Electroanalytical Chemistry, Vol. 431, Issue 1, p. 39-41
  • DOI: 10.1016/S0022-0728(97)00159-9

An Approach to Ideal Semiconductor Electrodes for Efficient Photoelectrochemical Reduction of Carbon Dioxide by Modification with Small Metal Particles
journal, February 1998

  • Hinogami, R.; Nakamura, Y.; Yae, S.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 6
  • DOI: 10.1021/jp972663h

Reversible interconversion of carbon dioxide and formate by an electroactive enzyme
journal, July 2008

  • Reda, T.; Plugge, C. M.; Abram, N. J.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 31, p. 10654-10658
  • DOI: 10.1073/pnas.0801290105

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
journal, August 1994

  • Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
  • Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839
  • DOI: 10.1016/0013-4686(94)85172-7

PRODUCTION OF CO AND CH 4 IN ELECTROCHEMICAL REDUCTION OF CO 2 AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION
journal, November 1985

  • Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin
  • Chemistry Letters, Vol. 14, Issue 11
  • DOI: 10.1246/cl.1985.1695

Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution
journal, June 1986

  • Hori, Yoshio; Kikuchi, Katsuhei; Murata, Akira
  • Chemistry Letters, Vol. 15, Issue 6
  • DOI: 10.1246/cl.1986.897

Step density dependence of co2 reduction rate on Pt(S)-[n(111) × (111)] single crystal electrodes
journal, June 1996


Catalytic Activity of CO 2 Reduction on Pt Single-Crystal Electrodes:  Pt(S)-[ n (111)×(111)], Pt(S)-[ n (111)×(100)], and Pt(S)-[ n (100)×(111)]
journal, October 1997

  • Hoshi, Nagahiro; Suzuki, Toshitake; Hori, Yoshio
  • The Journal of Physical Chemistry B, Vol. 101, Issue 42
  • DOI: 10.1021/jp971294m

Photoelectrochemical reduction products of carbon dioxide at metal coated p-GaP photocathodes in non-aqueous electrolytes
journal, March 1989

  • Ikeda, Shoichiro; Saito, Yasuhisa; Yoshida, Makoto
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 260, Issue 2, p. 335-345
  • DOI: 10.1016/0022-0728(89)87148-7

Electrochemical Reduction of Carbon Dioxide at Various Metal Electrodes in Aqueous Potassium Hydrogen Carbonate Solution
journal, September 1990

  • Noda, Hidetomo; Ikeda, Shoichiro; Oda, Yoshiyuki
  • Bulletin of the Chemical Society of Japan, Vol. 63, Issue 9, p. 2459-2462
  • DOI: 10.1246/bcsj.63.2459

Electrochemical Conversion of Carbon Dioxide to Formate in Alkaline Polymer Electrolyte Membrane Cells
journal, January 2011

  • Narayanan, S. R.; Haines, B.; Soler, J.
  • Journal of The Electrochemical Society, Vol. 158, Issue 2, p. A167-A173
  • DOI: 10.1149/1.3526312

Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders
journal, February 1979

  • Inoue, Tooru; Fujishima, Akira; Konishi, Satoshi
  • Nature, Vol. 277, Issue 5698
  • DOI: 10.1038/277637a0

Long-term activation of the copper cathode in the course of CO2 reduction
journal, August 1994


Photoelectrocatalytic reduction of CO2 in LiOH/methanol at metal-modified p-InP electrodes
journal, April 2006

  • Kaneco, Satoshi; Katsumata, Hideyuki; Suzuki, Tohru
  • Applied Catalysis B: Environmental, Vol. 64, Issue 1-2, p. 139-145
  • DOI: 10.1016/j.apcatb.2005.11.012

Reduction of CO2 and CO to methane on Cu foil electrodes
journal, April 1988

  • Kim, J. J.; Summers, D. P.; Frese, K. W.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 245, Issue 1-2, p. 223-244
  • DOI: 10.1016/0022-0728(88)80071-8

Reduction of adsorbed Co on a Ni electrode in connection with the electrochemical reduction of CO2
journal, July 1993


A photoelectrochemical approach to splitting carbon dioxide for a manned mission to Mars
journal, October 2001

  • Breedlove, Brian K.; Ferrence, Gregory M.; Washington, John
  • Materials & Design, Vol. 22, Issue 7, p. 577-584
  • DOI: 10.1016/S0261-3069(01)00018-8

Dinuclear Nickel Complexes as Catalysts for Electrochemical Reduction of Carbon Dioxide
journal, January 2005

  • Simón-Manso, Eugenio; Kubiak, Clifford P.
  • Organometallics, Vol. 24, Issue 1
  • DOI: 10.1021/om0494723

Remarkable decrease in overpotential of oxalate formation in electrochemical CO 2 reduction by a metal–sulfide cluster
journal, January 1995

  • Kushi, Yoshinori; Nagao, Hirotaka; Nishioka, Takanori
  • J. Chem. Soc., Chem. Commun., Issue 12
  • DOI: 10.1039/C39950001223

Photochemical Reduction of Carbon Dioxide to Methanol Using ZnS Microcrystallite as a Photocatalyst in the Presence of Methanol Dehydrogenase
journal, January 1994

  • Kuwabata, Susumu
  • Journal of The Electrochemical Society, Vol. 141, Issue 6
  • DOI: 10.1149/1.2054952

Electrochemical Synthesis of Urea at Gas-Diffusion Electrodes
journal, January 1998

  • Shibata, Masami
  • Journal of The Electrochemical Society, Vol. 145, Issue 7
  • DOI: 10.1149/1.1838641

Electrochemical Synthesis of Methanol from CO[sub 2] in High-Pressure Electrolyte
journal, January 1997

  • Li, Jianwei
  • Journal of The Electrochemical Society, Vol. 144, Issue 12
  • DOI: 10.1149/1.1838179

Carbon dioxide reduction at low temperature on various metal electrodes
journal, March 1989

  • Azuma, Masashi; Hashimoto, Kazuhito; Hiramoto, Masahiro
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 260, Issue 2, p. 441-445
  • DOI: 10.1016/0022-0728(89)87158-X

Metal-Free Activation of CO2 by Mesoporous Graphitic Carbon Nitride
journal, April 2007

  • Goettmann, Frédéric; Thomas, Arne; Antonietti, Markus
  • Angewandte Chemie International Edition, Vol. 46, Issue 15, p. 2717-2720
  • DOI: 10.1002/anie.200603478

Electroreduction of carbon dioxide: Part II. The mechanism of reduction in aprotic solvents
journal, July 1985

  • Vassiliev, Yu. B.; Bagotzky, V. S.; Khazova, O. A.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 189, Issue 2, p. 295-309
  • DOI: 10.1016/0368-1874(85)80074-5

Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH
journal, January 2010

  • Whipple, Devin T.; Finke, Eryn C.; Kenis, Paul J. A.
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 9
  • DOI: 10.1149/1.3456590

Effect of Gaseous Impurities on the Electrochemical Reduction of CO
conference, January 2009

  • Zhai, Yumei; Chiachiarelli, Leo; Sridhar, Narasi
  • 215th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3220175

Nitrogen-rich polymers for the electrocatalytic reduction of CO2
journal, December 2010


Electroreduction of carbon dioxide on platinum single crystal electrodes: electrochemical and in situ FTIR studies
journal, November 1990

  • Nikolic, B. Z.; Huang, H.; Gervasio, D.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 295, Issue 1-2, p. 415-423
  • DOI: 10.1016/0022-0728(90)85033-2

Pulsed Electroreduction of CO[sub 2] on Copper Electrodes
journal, January 1993

  • Shiratsuchi, Ryuichi
  • Journal of The Electrochemical Society, Vol. 140, Issue 12
  • DOI: 10.1149/1.2221113

Electrocatalytic generation of C2 and C3 compounds from carbon dioxide on a cobalt complex-immobilized dual-film electrode
journal, January 1993

  • Ogura, Kotaro; Mine, Kenichi; Yano, Jun
  • Journal of the Chemical Society, Chemical Communications, Issue 1
  • DOI: 10.1039/C39930000020

Electrochemical reduction of carbon dioxide on hydrogen-storing materials
journal, March 1994

  • Ohkawa, Kiyomi; Noguchi, Yoshikazu; Nakayama, Sumie
  • Journal of Electroanalytical Chemistry, Vol. 367, Issue 1-2, p. 165-173
  • DOI: 10.1016/0022-0728(93)03011-D

Electrochemical approaches to alleviation of the problem of carbon dioxide accumulation
journal, January 2001

  • Sánchez-Sánchez, C. M.; Montiel, V.; Tryk, D. A.
  • Pure and Applied Chemistry, Vol. 73, Issue 12
  • DOI: 10.1351/pac200173121917

A study of the production of glyoxylic acid by the electrochemical reduction of oxalic acid solutions
journal, February 1974

  • Pickett, D. J.; Yap, K. S.
  • Journal of Applied Electrochemistry, Vol. 4, Issue 1
  • DOI: 10.1007/BF00615902

Photoelectrochemical pumping of enzymatic CO2 reduction
journal, May 1984

  • Parkinson, Bruce A.; Weaver, Paul F.
  • Nature, Vol. 309, Issue 5964
  • DOI: 10.1038/309148a0

Molecular catalysts in photoelectrochemical cells: Study of an efficient system for the selective photoelectroreduction of CO2: p-GaP or p-GaAs/Ni(cyclam)2+, aqueous medium
journal, September 1989

  • Petit, Jean-Pierre; Chartier, Pierre; Beley, Marc
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 269, Issue 2, p. 267-281
  • DOI: 10.1016/0022-0728(89)85137-X

Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3
journal, January 1997

  • Popić, J. P.; Avramov-Ivić, M. L.; Vuković, N. B.
  • Journal of Electroanalytical Chemistry, Vol. 421, Issue 1-2, p. 105-110
  • DOI: 10.1016/S0022-0728(96)04823-1

Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction
journal, December 2010

  • Whipple, Devin T.; Kenis, Paul J. A.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458
  • DOI: 10.1021/jz1012627

The electrochemical reduction of CO2 to oxalate at a Pt electrode immersed in acetonitrile and coated with polyvinylalcohol[Ni(dppm)2Cl2]
journal, May 1995

  • Christensen, P. A.; Higgins, S. J.
  • Journal of Electroanalytical Chemistry, Vol. 387, Issue 1-2, p. 127-132
  • DOI: 10.1016/0022-0728(95)03949-H

Electrochemical reduction of CO2 on RuO2/TiO2 nanotubes composite modified Pt electrode
journal, May 2005


High-yield reduction of carbon dioxide into formic acid by zero-valent metal/metal oxide redox cycles
journal, January 2011

  • Jin, Fangming; Gao, Ying; Jin, Yujia
  • Energy & Environmental Science, Vol. 4, Issue 3
  • DOI: 10.1039/C0EE00661K

Electroreduction of carbon dioxide: Part III. Adsorption and reduction of CO2 on platinum
journal, July 1985

  • Vassiliev, Yu. B.; Bagotzky, V. S.; Osetrova, N. V.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 189, Issue 2, p. 311-324
  • DOI: 10.1016/0368-1874(85)80075-7

CO2 Reduction on Rh single crystal electrodes and the structural effect
journal, October 1995

  • Hoshi, Nagahiro; Ito, Hiroki; Suzuki, Toshitake
  • Journal of Electroanalytical Chemistry, Vol. 395, Issue 1-2, p. 309-312
  • DOI: 10.1016/0022-0728(95)04267-R

Macrocyclic [N42-] Coordinated Nickel Complexes as Catalysts for the Formation of Oxalate by Electrochemical Reduction of Carbon Dioxide
journal, November 2000

  • Rudolph, Manfred; Dautz, Sylvana; Jäger, Ernst-Gottfried
  • Journal of the American Chemical Society, Vol. 122, Issue 44, p. 10821-10830
  • DOI: 10.1021/ja001254n

Electrochemical reduction of supercritical carbon dioxide in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate
journal, December 2004

  • Zhao, Guoying; Jiang, Tao; Han, Buxing
  • The Journal of Supercritical Fluids, Vol. 32, Issue 1-3, p. 287-291
  • DOI: 10.1016/j.supflu.2003.12.015

Carbon Dioxide Reduction to Alcohols using Perovskite-Type Electrocatalysts
journal, January 1993

  • Schwartz, Michael
  • Journal of The Electrochemical Society, Vol. 140, Issue 3
  • DOI: 10.1149/1.2056131

Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide
journal, July 1987

  • Ikeda, Shoichiro; Takagi, Takehiko; Ito, Kaname
  • Bulletin of the Chemical Society of Japan, Vol. 60, Issue 7, p. 2517-2522
  • DOI: 10.1246/bcsj.60.2517

Towards Solar Fuels from Water and CO 2
journal, February 2010


Photo-aided reduction of carbon dioxide to carbon monoxide
journal, October 1983

  • Taniguchi, Isao; Aurian-Blajeni, Benedict; Bockris, John O'M.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 157, Issue 1, p. 179-182
  • DOI: 10.1016/S0022-0728(83)80389-1

The mediation of the photoelectrochemical reduction of carbon dioxide by ammonium ions
journal, February 1984

  • Taniguchi, Isao; Aurian-Blajeni, Benedict; Bockris, John O'M.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 161, Issue 2, p. 385-388
  • DOI: 10.1016/S0022-0728(84)80195-3

Effects of electrolytes on the photoelectrochemical reduction of carbon dioxide at illuminated p-type cadmium telluride and p-type indium phosphide electrodes in aqueous solutions
journal, July 1988

  • Yoneyama, Hiroshi; Sugimura, Kenji; Kuwabata, Susumu
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2, p. 143-153
  • DOI: 10.1016/0022-0728(88)80355-3

Electroreduction of carbon dioxide
journal, July 1985

  • Vassiliev, Yu. B.; Bagotsky, V. S.; Osetrova, N. V.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 189, Issue 2, p. 271-294
  • DOI: 10.1016/0368-1874(85)80073-3

Design of Alloy Electrocatalysts for CO[sub 2] Reduction
journal, January 1991

  • Watanabe, Masahiro
  • Journal of The Electrochemical Society, Vol. 138, Issue 11
  • DOI: 10.1149/1.2085417

Photocatalytic reduction of carbon dioxide with metal-loaded SiC powders
journal, June 1988

  • Yamamura, Soichiro; Kojima, Hiroyuki; Iyoda, Jun
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 247, Issue 1-2, p. 333-337
  • DOI: 10.1016/0022-0728(88)80154-2

The electrochemistry of indium
journal, February 1975

  • Piercy, R.; Hampson, N. A.
  • Journal of Applied Electrochemistry, Vol. 5, Issue 1
  • DOI: 10.1007/BF00625955

Electrochemical behaviour of indium in H2SO4
journal, March 1976

  • Watanabe, C. K.; Nobe, K.
  • Journal of Applied Electrochemistry, Vol. 6, Issue 2
  • DOI: 10.1007/BF00615382

Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte
journal, July 1995

  • Hara, Kohjiro; Kudo, Akihiko; Sakata, Tadayoshi
  • Journal of Electroanalytical Chemistry, Vol. 391, Issue 1-2, p. 141-147
  • DOI: 10.1016/0022-0728(95)03935-A

Voltammetry of carbon dioxide: Part I. A general survey of voltammetry at different electrode materials in different solvents
journal, June 1983

  • Eggins, Brian R.; McNeill, Joanne
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 148, Issue 1, p. 17-24
  • DOI: 10.1016/S0022-0728(83)80127-2

High-Rate Solar Photocatalytic Conversion of CO 2 and Water Vapor to Hydrocarbon Fuels
journal, February 2009

  • Varghese, Oomman K.; Paulose, Maggie; LaTempa, Thomas J.
  • Nano Letters, Vol. 9, Issue 2
  • DOI: 10.1021/nl803258p

Multielectron Storage and Photo-Induced Electron Transfer in Oligonuclear Complexes Containing Ruthenium(II) Terpyridine and Ferrocene Building Blocks
journal, May 2006

  • Heinze, Katja; Hempel, Klaus; Beckmann, Manuela
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 10
  • DOI: 10.1002/ejic.200501078

Bimetallic redox sites for photochemical CO2 splitting in mesoporous silicate sieve
journal, February 2006


Four-Electron Photochemistry of Dirhodium Fluorophosphine Compounds
journal, June 1999

  • Heyduk, Alan F.; Macintosh, Ann M.; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 121, Issue 21
  • DOI: 10.1021/ja9902017

Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles
journal, November 2009

  • Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang
  • Nature Chemistry, Vol. 2, Issue 1
  • DOI: 10.1038/nchem.468

Water Suppression That Works. Excitation Sculpting Using Arbitrary Wave-Forms and Pulsed-Field Gradients
journal, February 1995

  • Hwang, T. L.; Shaka, A. J.
  • Journal of Magnetic Resonance, Series A, Vol. 112, Issue 2
  • DOI: 10.1006/jmra.1995.1047

On the study of adsorbed species at platinum from methanol, formic acid and reduced carbon dioxide via in situ FT-ir spectroscopy
journal, September 1992


Nickel-based tri-reforming catalyst for the production of synthesis gas
journal, November 2007


Electrochemical reduction of CO2 at an activated silver electrode
journal, December 1994

  • Kostecki, R.; Augustynski, J.
  • Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 98, Issue 12, p. 1510-1515
  • DOI: 10.1002/bbpc.19940981203

The mechanism of the Cannizzaro reaction of Formaldehyde
journal, January 1954

  • Martin, Rjl
  • Australian Journal of Chemistry, Vol. 7, Issue 4
  • DOI: 10.1071/CH9540335

The kinetics and mechanism of methanol synthesis by hydrogenation of CO2 over a Zn-deposited Cu(111) surface
journal, July 1997


Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
journal, April 1964

  • Nicholson, R. S.; Shain, Irving
  • Analytical Chemistry, Vol. 36, Issue 4, p. 706-723
  • DOI: 10.1021/ac60210a007

Kinetics of Electrochemical Reduction of Carbon Dioxide on a Gold Electrode in Phosphate Buffer Solutions
journal, July 1995

  • Noda, Hidetomo; Ikeda, Shoichiro; Yamamoto, Akio
  • Bulletin of the Chemical Society of Japan, Vol. 68, Issue 7
  • DOI: 10.1246/bcsj.68.1889

Electrocatalytic reduction of carbon dioxide to methanol Part IV. Assessment of the current—potential curves leading to reduction
journal, July 1986

  • Ogura, Kotaro; Takagi, Mitsugu
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 206, Issue 1-2, p. 209-216
  • DOI: 10.1016/0022-0728(86)90269-X

Bioinspired Energy Conversion Systems for Hydrogen Production and Storage
journal, March 2008

  • Fukuzumi, Shunichi
  • European Journal of Inorganic Chemistry, Vol. 2008, Issue 9, p. 1351-1362
  • DOI: 10.1002/ejic.200701369

Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
journal, January 2010


The production of oxalic acid from CO2 and H2O
journal, November 1981

  • Fischer, J.; Lehmann, Th.; Heitz, E.
  • Journal of Applied Electrochemistry, Vol. 11, Issue 6
  • DOI: 10.1007/BF00615179

Oxygen and hydrogen photocatalysis by two-electron mixed-valence coordination compounds
journal, July 2005

  • Rosenthal, Joel; Bachman, Julien; Dempsey, Jillian L.
  • Coordination Chemistry Reviews, Vol. 249, Issue 13-14, p. 1316-1326
  • DOI: 10.1016/j.ccr.2005.03.034

High-Resolution X-Ray Photoemission Spectrum of the Valence Bands of Gold
journal, June 1972


The mechanism of electrocatalytic oxidation of formic acid on Pt (100) and Pt (111) in sulphuric acid solution: an emirs study
journal, January 1988

  • Sun, S. G.; Clavilier, J.; Bewick, A.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 240, Issue 1-2, p. 147-159
  • DOI: 10.1016/0022-0728(88)80319-X

Adsorption and reduction of formic acid on p-type silicon electrodes
journal, December 1986

  • Szklarczyk, Marek; Sobkowski, Jerzy; Pacocha, Jolanta
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 215, Issue 1-2, p. 307-316
  • DOI: 10.1016/0022-0728(86)87024-3

Photo-catalytic CO2 reduction using sol–gel derived titania-supported zinc-phthalocyanine
journal, December 2007


Multi-electron reduction of CO2 via RuCO2, C(O)OH, CO, CHO, and CH2OH species
journal, March 2002


Ruthenium Formyl Complexes as the Branch Point in Two- and Multi-Electron Reductions of CO2
journal, October 1995

  • Toyohara, Kiyotsuna; Nagao, Hirotaka; Mizukawa, Tetsunori
  • Inorganic Chemistry, Vol. 34, Issue 22
  • DOI: 10.1021/ic00126a003

Production of syngas plus oxygen from CO2 in a gas-diffusion electrode-based electrolytic cell
journal, August 2002


Electrochemical reduction of butyraldehyde in the presence of CO2
journal, July 2002


The role of Li-ion battery electrolyte reactivity in performance decline and self-discharge
journal, June 2003


Electrochemical Synthesis of Urea at Gas-Diffusion Electrodes
journal, January 1998

  • Shibata, Masami
  • Journal of The Electrochemical Society, Vol. 145, Issue 2
  • DOI: 10.1149/1.1838309

The electrochemical reduction of organic acids
journal, August 1971

  • Harrison, J. A.; Shoesmith, D. W.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 32, Issue 1, p. 125-135
  • DOI: 10.1016/S0022-0728(71)80239-5

Selective formation of HCO2− and C2O42− in electrochemical reduction of CO2 catalyzed by mono- and di-nuclear ruthenium complexes
journal, January 1998

  • Ali, Md. Meser; Sato, Hiroyasu; Ali, Md. Meser
  • Chemical Communications, Issue 2
  • DOI: 10.1039/A707363A

A metal-free polymeric photocatalyst for hydrogen production from water under visible light
journal, November 2008

  • Wang, Xinchen; Maeda, Kazuhiko; Thomas, Arne
  • Nature Materials, Vol. 8, Issue 1
  • DOI: 10.1038/nmat2317

Reduction of Carbon Dioxide to Methanol on n- and p-GaAs and p-InP. Effect of Crystal Face, Electrolyte and Current Density
journal, January 1983

  • Canfield, D.
  • Journal of The Electrochemical Society, Vol. 130, Issue 8
  • DOI: 10.1149/1.2120090

The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism Study
journal, September 2010

  • Huang, Fang; Lu, Gang; Zhao, Lili
  • Journal of the American Chemical Society, Vol. 132, Issue 35
  • DOI: 10.1021/ja103531z

Electrochemical reduction of CO2 on a polyaniline electrode under ambient conditions and at high pressure in methanol
journal, November 2002


Electrocatalytic Recycling of CO 2 and Small Organic Molecules
journal, October 2009

  • Lee, Jaeyoung; Kwon, Youngkook; Machunda, Revocatus L.
  • Chemistry - An Asian Journal, Vol. 4, Issue 10
  • DOI: 10.1002/asia.200900055

Electrochemical reduction of high pressure CO2 at Pb, Hg and In electrodes in an aqueous KHCO3 solution
journal, September 1995

  • Todoroki, Makoto; Hara, Kohjiro; Kudo, Akihiko
  • Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2, p. 199-203
  • DOI: 10.1016/0022-0728(95)04010-L

Electrocatalytic Carbon Dioxide Activation: The Rate-Determining Step of Pyridinium-Catalyzed CO2 Reduction
journal, February 2011

  • Morris, Amanda J.; McGibbon, Robert T.; Bocarsly, Andrew B.
  • ChemSusChem, Vol. 4, Issue 2, p. 191-196
  • DOI: 10.1002/cssc.201000379

Electrochemical measurement on the photoelectrochemical reduction of aqueous carbon dioxide on p-Gallium phosphide and p-Gallium arsenide semiconductor electrodes
journal, March 1983


Photocatalytic reduction of carbon dioxide into gaseous hydrocarbon using TiO2 pellets
journal, June 2006


Electrochemical Reduction of Carbon Dioxide in Water: Analysis of Reaction Mechanism on Ruthenium-Titanium-Oxide
journal, January 1992

  • Bandi, A.
  • Journal of The Electrochemical Society, Vol. 139, Issue 6
  • DOI: 10.1149/1.2069464

A study by electrochemically modulated infrared reflectance spectroscopy of the electrosorption of formic acid at a platinum electrode
journal, June 1983

  • Beden, B.; Bewick, A.; Lamy, C.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 148, Issue 1, p. 147-160
  • DOI: 10.1016/S0022-0728(83)80137-5

A high-resolution investigation of proton coupled and decoupled 13C FT NMR spectra of 15N-pyrrole
journal, September 1975

  • Bundgaard, T.; Jakobsen, H. J.; Rahkamaa, E. J.
  • Journal of Magnetic Resonance (1969), Vol. 19, Issue 3, p. 345-356
  • DOI: 10.1016/0022-2364(75)90049-9

Catalysis Research of Relevance to Carbon Management:  Progress, Challenges, and Opportunities
journal, April 2001

  • Arakawa, Hironori; Aresta, Michele; Armor, John N.
  • Chemical Reviews, Vol. 101, Issue 4
  • DOI: 10.1021/cr000018s

Applications of real-time infrared spectroscopy to electrocatalysis at bimetallic surfaces
journal, April 1992


The reduction of formaldehyde
journal, April 1972

  • Clarke, S.; Harrison, J. A.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 36, Issue 1, p. 109-115
  • DOI: 10.1016/S0022-0728(72)80450-9

Activation of Carbon Dioxide by Bicyclic Amidines
journal, November 2004

  • Pérez, Eduardo R.; Santos, Regina H. A.; Gambardella, Maria T. P.
  • The Journal of Organic Chemistry, Vol. 69, Issue 23
  • DOI: 10.1021/jo049243q

The Electro-Reduction of Carbon Dioxide in a Continuous Reactor
journal, October 2005


Electrochemical reduction of carbon dioxide to ethylene with high Faradaic efficiency at a Cu electrode in CsOH/methanol
journal, September 1999


Electrochemical activation of carbon dioxide for synthesis of dimethyl carbonate in an ionic liquid
journal, April 2009


The electrolytic reduction of carbon dioxide and monoxide for the production of carboxylic acids
journal, November 1984

  • Goodridge, F.; Presland, G.
  • Journal of Applied Electrochemistry, Vol. 14, Issue 6
  • DOI: 10.1007/BF00615269

Tin Oxide Dependence of the CO 2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts
journal, January 2012

  • Chen, Yihong; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 4
  • DOI: 10.1021/ja2108799

Electrochemical conversion of carbon dioxide to formic acid on Pb in KOH/methanol electrolyte at ambient temperature and pressure
journal, December 1998


Electrochemical Reduction of Carbon Dioxide I. Effects of the Electrolyte on the Selectivity and Activity with Sn Electrode
journal, January 2012

  • Wu, Jingjie; Risalvato, Frank G.; Ke, Fu-Sheng
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.049207jes