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Title: Method of producing gaseous products using a downflow reactor

Reactor systems and methods are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems and methods are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.
Inventors:
; ;
Issue Date:
OSTI Identifier:
1159836
Assignee:
Virent, Inc. (Madison, WI) GFO
Patent Number(s):
8,834,587
Application Number:
13/539,861
Contract Number:
FG36-05GO15046
Research Org:
Virent, Inc., Madison, WI (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
22 GENERAL STUDIES OF NUCLEAR REACTORS

Other works cited in this record:

Conversion of alcohols, mercaptans, sulfides, halides and/or amines
patent, July 1975

Integrated process for converting methanol to gasoline and distillates
patent, January 1993

Synthesis method of chemical industrial raw material and high-octane fuel, and high-octane fuel composition
patent, November 2001

Low-temperature hydrogen production from oxygenated hydrocarbons
patent, March 2004

Low-temperature hydrocarbon production from oxygenated hydrocarbons
patent, October 2005

Low-temperature hydrogen production from oxygenated hydrocarbons
patent, November 2005

Low-temperature hydrogen production from oxygenated hydrocarbons
patent, November 2005

Low-temperature hydrogen production from oxygenated hydrocarbons
patent, November 2009

Highly Dispersed Metal Catalysts
patent-application, January 2010

Acidity of Keggin-Type Heteropolycompounds Evaluated by Catalytic Probe Reactions, Sorption Microcalorimetry, and Density Functional Quantum Chemical Calculations
journal, December 1998
  • Bardin, Billy B.; Bordawekar, Shailendra V.; Neurock, Matthew
  • The Journal of Physical Chemistry B, Vol. 102, Issue 52, p. 10817-10825
  • DOI: 10.1021/jp982345y

Single-reactor process for sequential aldol-condensation and hydrogenation of biomass-derived compounds in water
journal, June 2006
  • Barrett, C. J.; Chheda, J. N.; Huber, G. W.
  • Applied Catalysis B: Environmental, Vol. 66, Issue 1-2, p. 111-118
  • DOI: 10.1016/j.apcatb.2006.03.001

Distribution of methanol and catalysts between biodiesel and glycerin phases
journal, January 2005
  • Chiu, Chuang-Wei; Goff, Michael J.; Suppes, Galen J.
  • AIChE Journal, Vol. 51, Issue 4, p. 1274-1278
  • DOI: 10.1002/aic.10385

Low-pressure hydrogenolysis of glycerol to propylene glycol
journal, March 2005
  • Dasari, Mohanprasad A.; Kiatsimkul, Pim-Pahn; Sutterlin, Willam R.
  • Applied Catalysis A: General, Vol. 281, Issue 1-2, p. 225-231
  • DOI: 10.1016/j.apcata.2004.11.033

A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts
journal, March 2005
  • Davda, R. R.; Shabaker, J. W.; Huber, G. W.
  • Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 171-186
  • DOI: 10.1016/j.apcatb.2004.04.027

Aqueous-phase reforming of ethylene glycol on silica-supported metal catalysts
journal, June 2003

Catalytic Reforming of Oxygenated Hydrocarbons for Hydrogen with Low Levels of Carbon Monoxide
journal, September 2003
  • Davda, Rupali R.; Dumesic, James A.
  • Angewandte Chemie, Vol. 115, Issue 34, p. 4202-4205
  • DOI: 10.1002/ange.200351664

Performance of RuSn catalysts supported on different oxides in the selective hydrogenation of dimethyl adipate
journal, October 2005

Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks
journal, April 2004
  • Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.
  • Industrial & Engineering Chemistry Research, Vol. 43, Issue 9, p. 1999-2004
  • DOI: 10.1021/ie034303o

Catalytic Conversion of Cellulose into Sugar Alcohols
journal, August 2006
  • Fukuoka, Atsushi; Dhepe, Paresh L.
  • Angewandte Chemie International Edition, Vol. 45, Issue 31, p. 5161-5163
  • DOI: 10.1002/anie.200601921

Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates
journal, June 2005
  • Huber, George W.; Chheda, Juben N.; Barrett, Christopher J.
  • Science, Vol. 308, Issue 5727, p. 1446-1450
  • DOI: 10.1126/science.1111166

Renewable Alkanes by Aqueous-Phase Reforming of Biomass-Derived Oxygenates
journal, March 2004
  • Huber, George W.; Cortright, Randy D.; Dumesic, James A.
  • Angewandte Chemie International Edition, Vol. 43, Issue 12, p. 1549-1551
  • DOI: 10.1002/anie.200353050

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006
  • Huber, George W.; Iborra, Sara; Corma, Avelino
  • Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098
  • DOI: 10.1021/cr068360d

Selective hydrogenation over ruthenium catalysts
journal, July 1995

Glycerol conversion in the aqueous solution under hydrogen over Ru/C + an ion-exchange resin and its reaction mechanism
journal, June 2006
  • Miyazawa, Tomohisa; Kusunoki, Yohei; Kunimori, Kimio
  • Journal of Catalysis, Vol. 240, Issue 2, p. 213-221
  • DOI: 10.1016/j.jcat.2006.03.023

Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates
journal, June 2007
  • Román-Leshkov, Yuriy; Barrett, Christopher J.; Liu, Zhen Y.
  • Nature, Vol. 447, Issue 7147, p. 982-985
  • DOI: 10.1038/nature05923

Conversion of hydrocarbons and alcohols for fuel cells
journal, March 2002

Aqueous-phase reforming of oxygenated hydrocarbons over Sn-modified Ni catalysts
journal, February 2004
  • Shabaker, J. W.; Huber, G. W.; Dumesic, J. A.
  • Journal of Catalysis, Vol. 222, Issue 1, p. 180-191
  • DOI: 10.1016/j.jcat.2003.10.022

Role of catalyst preparation on determining selective sites for hydrogenation of dimethyl adipate over RuSn/Al2O3
journal, July 2006
  • Silva, Adriana M.; Santos, Onélia A. A.; Morales, Marco A.
  • Journal of Molecular Catalysis A: Chemical, Vol. 253, Issue 1-2, p. 62-69
  • DOI: 10.1016/j.molcata.2006.03.005

Catalytic steam reforming of biomass-derived oxygenates: acetic acid and hydroxyacetaldehyde
journal, August 1996

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