Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications
Abstract
A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.
- Inventors:
- Issue Date:
- Research Org.:
- Georgia Institute of Technology, Atlanta, GA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1159834
- Patent Number(s):
- 8834822
- Application Number:
- 13/212,284
- Assignee:
- Georgia Tech Research Corporation (Atlanta, GA); U.S. Department of Energy (Washington, DC)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Gay, McMahan, Choi, Sunho, and Jones, Christopher W. Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications. United States: N. p., 2014.
Web.
Gay, McMahan, Choi, Sunho, & Jones, Christopher W. Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications. United States.
Gay, McMahan, Choi, Sunho, and Jones, Christopher W. Tue .
"Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications". United States. https://www.osti.gov/servlets/purl/1159834.
@article{osti_1159834,
title = {Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications},
author = {Gay, McMahan and Choi, Sunho and Jones, Christopher W},
abstractNote = {A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {9}
}
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