Self assembled multi-layer nanocomposite of graphene and metal oxide materials

Title: Self assembled multi-layer nanocomposite of graphene and metal oxide materials

Nanocomposite materials having at least two layers, each layer consisting of one metal oxide bonded to at least one graphene layer were developed. The nanocomposite materials will typically have many alternating layers of metal oxides and graphene layers, bonded in a sandwich type construction and will be incorporated into an electrochemical or energy storage device.

Inventors:: Liu, Jun; Choi, Daiwon; Kou, Rong; Nie, Zimin; Wang, Donghai; Yang, Zhenguo

Issue Date:: 2014-09-16

OSTI Identifier:: 1159828

Assignee:: Battelle Memorial Institute (Richland, WA) PNNL

Patent Number(s):: 8,835,046

Application Number:: 12/852,794

Contract Number:: AC06-76RLO1830

Research Org:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org:: USDOE

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Full Text
View Full Text

Other works cited in this record:

Mesoporous composite gels an aerogels
patent, December 2002

Rolison, Debra; Morris, Catherine; Anderson, Michelle
US Patent Document 6,492,014
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6492014

Process for the preparation of metal-containing nanostructured films
patent, February 2006

Lu, Yunfeng; Wang, Donghai
US Patent Document 7,001,669
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7001669

Nanostructured bulk thermoelectric material
patent-application, December 2007

Zhang, Minjuan; Lu, Yunfeng
US Patent Document 7,309,830
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7309830

Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets
patent-application, November 2008

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng
US Patent Application 11/800728; 20080279756
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220080279756%22.PGNR.&OS=DN/20080279756&RS=DN/20080279756

Nano graphene platelet-based composite anode compositions for lithium ion batteries
patent-application, May 2009

Zhamu, Aruna; Jang, Bor
US Patent Application 11/982672; 20090117467
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220090117467%22.PGNR.&OS=DN/20090117467&RS=DN/20090117467

Layer-By-Layer Assemblies of Carbon-Based Nanostructures and Their Applications in Energy Storage and Generation Devices
patent-application, June 2010

Shao-Horn, Yang; Lee, Seung Woo; Yabuuchi, Naoaki
US Patent Application 12/541305; 20100159366
URL: http://appft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PG01&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.html&r=1&f=G&l=50&s1=%2220100159366%22.PGNR.&OS=DN/20100159366&RS=DN/20100159366

Mesoporous tin oxides as lithium intercalation anode materials
journal, January 2002

Yu, Aishui; Frech, Roger
Journal of Power Sources, Vol. 104, Issue 1, p. 97-100
DOI: 10.1016/S0378-7753(01)00901-6

In situ chemical synthesis of SnO₂–graphene nanocomposite as anode materials for lithium-ion batteries
journal, October 2009

Yao, Jane; Shen, Xiaoping; Wang, Bei
Electrochemistry Communications, Vol. 11, Issue 10, p. 1849-1852
DOI: 10.1016/j.elecom.2009.07.035

Carbon-coated mesoporous silica with hydrophobicity and electrical conductivity
journal, January 2008

Nishihara, Hirotomo; Fukura, Yu; Inde, Kouta
Carbon, Vol. 46, Issue 1, p. 48-53
DOI: 10.1016/j.carbon.2007.10.024

Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005

Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
Nature Materials, Vol. 4, Issue 5, p. 366-377
DOI: 10.1038/nmat1368

TiO₂(B) Nanowires as an Improved Anode Material for Lithium-Ion Batteries Containing LiFePO₄ or LiNi_0.5Mn_1.5O₄ Cathodes and a Polymer Electrolyte
journal, October 2006

Armstrong, G.; Armstrong, A. R.; Bruce, P. G.
Advanced Materials, Vol. 18, Issue 19, p. 2597-2600
DOI: 10.1002/adma.200601232

Structural evolution during the reaction of Li with nano-sized rutile type TiO₂ at room temperature
journal, February 2007

Baudrin, E.; Cassaignon, S.; Koelsch, M.
Electrochemistry Communications, Vol. 9, Issue 2, p. 337-342
DOI: 10.1016/j.elecom.2006.09.022

Purification and size-selection of carbon nanotubes
journal, January 1997

Bonard, Jean-Marc; Stora, Thierry; Salvetat, Jean-Paul
Advanced Materials, Vol. 9, Issue 10, p. 827-831
DOI: 10.1002/adma.19970091014

Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper
journal, July 2008

Chen, Haiqun; Müller, Marc B.; Gilmore, Kerry J.
Advanced Materials, Vol. 20, Issue 18, p. 3557-3561
DOI: 10.1002/adma.200800757

Preparation and characterization of graphene oxide paper
journal, July 2007

Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J.
Nature, Vol. 448, Issue 7152, p. 457-460
DOI: 10.1038/nature06016

RuO₂-wired high-rate nanoparticulate TiO₂ (anatase): Suppression of particle growth using silica
journal, June 2008

Erjavec, B.; Dominko, R.; Umek, P.
Electrochemistry Communications, Vol. 10, Issue 6, p. 926-929
DOI: 10.1016/j.elecom.2008.04.006

Superior Electrode Performance of Nanostructured Mesoporous TiO₂ (Anatase) through Efficient Hierarchical Mixed Conducting Networks
journal, August 2007

Guo, Y.-G.; Hu, Y.-S.; Sigle, W.
Advanced Materials, Vol. 19, Issue 16, p. 2087-2091
DOI: 10.1002/adma.200602828

High Lithium Electroactivity of Nanometer-Sized Rutile TiO₂
journal, June 2006

Hu, Y.-S.; Kienle, L.; Guo, Y.-G.
Advanced Materials, Vol. 18, Issue 11, p. 1421-1426
DOI: 10.1002/adma.200502723

Improved Electrode Performance of Porous LiFePO₄ Using RuO₂ as an Oxidic Nanoscale Interconnect
journal, August 2007

Hu, Y.-S.; Guo, Y.-G.; Dominko, R.
Advanced Materials, Vol. 19, Issue 15, p. 1963-1966
DOI: 10.1002/adma.200700697

Self-organizing high-density single-walled carbon nanotube arrays from surfactant suspensions
journal, August 2004

Huang, Limin; Cui, Xiaodong; Dukovic, Gordana
Nanotechnology, Vol. 15, Issue 11, p. 1450-1454
DOI: 10.1088/0957-4484/15/11/012

Template-Free Synthesis of SnO₂ Hollow Nanostructures with High Lithium Storage Capacity
journal, September 2006

Lou, X. W.; Wang, Y.; Yuan, C.
Advanced Materials, Vol. 18, Issue 17, p. 2325-2329
DOI: 10.1002/adma.200600733

Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005

Maier, J.
Nature Materials, Vol. 4, Issue 11, p. 805-815
DOI: 10.1038/nmat1513

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007

McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H.
Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404
DOI: 10.1021/cm0630800

A Mesoporous Nanocomposite of TiO₂ and Carbon Nanotubes as a High-Rate Li-Intercalation Electrode Material
journal, January 2006

Moriguchi, I.; Hidaka, R.; Yamada, H.
Advanced Materials, Vol. 18, Issue 1, p. 69-73
DOI: 10.1002/adma.200501366

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004

Novoselov, K. S.
Science, Vol. 306, Issue 5696, p. 666-669
DOI: 10.1126/science.1102896

Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Peigney, A.; Laurent, Ch.; Flahaut, E.
Carbon, Vol. 39, Issue 4, p. 507-514
DOI: 10.1016/S0008-6223(00)00155-X

Improved electrochemical performance of a LiFePO₄-based composite cathode
journal, August 2001

Prosini, Pier Paolo; Zane, Daniela; Pasquali, Mauro
Electrochimica Acta, Vol. 46, Issue 23, p. 3517-3523
DOI: 10.1016/S0013-4686(01)00631-4

Functionalized graphene sheets for polymer nanocomposites
journal, May 2008

Ramanathan, T.; Abdala, A. A.; Stankovich, S.
Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331
DOI: 10.1038/nnano.2008.96

SnO₂-carbon composites for lithium-ion battery anodes
journal, June 2001

Read, J.; Foster, D.; Wolfenstine, J.
Journal of Power Sources, Vol. 96, Issue 2, p. 277-281
DOI: 10.1016/S0378-7753(00)00569-3

Room temperature synthesis and Li insertion into nanocrystalline rutile TiO₂
journal, August 2006

Reddy, M. Anji; Kishore, M. Satya; Pralong, V.
Electrochemistry Communications, Vol. 8, Issue 8, p. 1299-1303
DOI: 10.1016/j.elecom.2006.05.021

Graphene-based composite materials
journal, July 2006

Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B.
Nature, Vol. 442, Issue 7100, p. 282-286
DOI: 10.1038/nature04969

Characteristics of graphene-layer encapsulated nanoparticles fabricated using laser ablation method
journal, April 2008

Ou, Q.; Tanaka, T.; Mesko, M.
Diamond and Related Materials, Vol. 17, Issue 4-5, p. 664-668
DOI: 10.1016/j.diamond.2007.10.023

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

Tarascon, J.-M.; Armand, M.
Nature, Vol. 414, Issue 6861, p. 359-367
DOI: 10.1038/35104644

Graphene−Silica Composite Thin Films as Transparent Conductors
July 2007

Watcharotone, Supinda; Dikin, Dmitriy A; Stankovich, Sasha
Nano Letters, Vol. 7, Issue 7, p. 1888–1892
DOI: 10.1021/nl070477+

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries
journal, August 2008

Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji
Nano Letters, Vol. 8, Issue 8, p. 2277-2282
DOI: 10.1021/nl800957b

Pseudocapacitive Lithium Storage in TiO₂(B)
journal, March 2005

Zukalová, Markéta; Kalbáč, Martin; Kavan, Ladislav
Chemistry of Materials, Vol. 17, Issue 5, p. 1248-1255
DOI: 10.1021/cm048249t

Li-ion batteries from LiFePO₄ cathode and anatase/graphene composite anode for stationary energy storage
journal, March 2010

Choi, Daiwon; Wang, Donghai; Viswanathan, Vish V.
Electrochemistry Communications, Vol. 12, Issue 3, p. 378-381
DOI: 10.1016/j.elecom.2009.12.039

Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets
journal, November 2007

Gomez-Navarro, Cristina; Weitz, R. Thomas; Bittner, Alexander M.
Nano Letters, Vol. 7, Issue 11, p. 3499-3503
DOI: 10.1021/nl072090c

Oriented Nanostructures for Energy Conversion and Storage
journal, September 2008

Liu, Jun; Cao, Guozhong; Yang, Zhenguo
ChemSusChem, Vol. 1, Issue 8-9, p. 676-697
DOI: 10.1002/cssc.200800087

Self-Assembled TiO ₂ –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion
journal, March 2009

Wang, Donghai; Choi, Daiwon; Li, Juan
ACS Nano, Vol. 3, Issue 4, p. 907-914
DOI: 10.1021/nn900150y

Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage
journal, March 2010

Wang, Donghai; Kou, Rong; Choi, Daiwon
ACS Nano, Vol. 4, Issue 3, p. 1587-1595
DOI: 10.1021/nn901819n

Dispersion of Sn and SnO on carbon anodes
journal, September 2000

Lee, Jim Yang; Zhang, Ruifen; Liu, Zhaolin
Journal of Power Sources, Vol. 90, Issue 1, p. 70-75
DOI: 10.1016/S0378-7753(00)00450-X

Direct synthesis of uniform mesoporous carbons from the carbonization of as-synthesized silica/triblock copolymer nanocomposites
journal, January 2004

Kim, Jaeyun; Lee, Jinwoo; Hyeon, Taeghwan
Carbon, Vol. 42, Issue 12-13, p. 2711-2719
DOI: 10.1016/j.carbon.2004.06.018

Similar records in DOepatents and OSTI.GOV collections:

Self assembled multi-layer nanocomposite of graphene and metal oxide materials

Patent Liu, Jun ; Aksay, Ilhan A ; Choi, Daiwon ; Kou, Rong ; Nie, Zimin ; Wang, Donghai ; Yang, Zhenguo

Nanocomposite materials having at least two layers, each layer consisting of one metal oxide bonded to at least one graphene layer were developed. The nanocomposite materials will typically have many alternating layers of metal oxides and graphene layers, bonded in a sandwich type construction and will be incorporated into an electrochemical or energy storage device.
Full Text Available October 2013
Self assembled multi-layer nanocomposite of graphene and metal oxide materials

Patent Liu, Jun ; Aksay, Ilhan A ; Choi, Daiwon ; Kou, Rong ; Nie, Zimin ; Wang, Donghai ; Yang, Zhenguo

Nanocomposite materials having at least two layers, each layer consisting of one metal oxide bonded to at least one graphene layer were developed. The nanocomposite materials will typically have many alternating layers of metal oxides and graphene layers, bonded in a sandwich type construction and will be incorporated into an electrochemical or energy storage device.
Full Text Available April 2015
Nanocomposite of graphene and metal oxide materials

Patent Liu, Jun ; Aksay, Ilhan A. ; Choi, Daiwon ; Wang, Donghai ; Yang, Zhenguo

Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10C.
Full Text Available September 2012
Nanocomposite of graphene and metal oxide materials

Patent Liu, Jun ; Aksay, Ilhan A. ; Choi, Daiwon ; Wang, Donghai ; Yang, Zhenguo

Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10 C.
Full Text Available October 2013
Nanocomposite of graphene and metal oxide materials

Patent Liu, Jun ; Aksay, Ilhan A. ; Choi, Daiwon ; Wang, Donghai ; Yang, Zhenguo

Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10 C.
Full Text Available June 2015