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Title: Methods for the synthesis of deuterated acrylate salts

Abstract

A method for synthesizing a deuterated acrylate of the Formula (1), the method comprising: (i) deuterating a propiolate compound of Formula (2) to a methyne-deuterated propiolate compound of Formula (3) in the presence of a base and D.sub.2O: and (ii) reductively deuterating the methyne-deuterated propiolate compound of Formula (3) in a reaction solvent in the presence of deuterium gas and a palladium-containing catalyst to afford the deuterated acrylate of the Formula (1). The resulting deuterated acrylate compounds, derivatives thereof, and polymers derived therefrom are also described.

Inventors:
; ;
Issue Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1157504
Patent Number(s):
8,829,238
Application Number:
13/611,927
Assignee:
UT-Battelle, LLC (Oak Ridge, TN)
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Yang, Jun, Bonnesen, Peter V., and Hong, Kunlun. Methods for the synthesis of deuterated acrylate salts. United States: N. p., 2014. Web.
Yang, Jun, Bonnesen, Peter V., & Hong, Kunlun. Methods for the synthesis of deuterated acrylate salts. United States.
Yang, Jun, Bonnesen, Peter V., and Hong, Kunlun. Tue . "Methods for the synthesis of deuterated acrylate salts". United States. https://www.osti.gov/servlets/purl/1157504.
@article{osti_1157504,
title = {Methods for the synthesis of deuterated acrylate salts},
author = {Yang, Jun and Bonnesen, Peter V. and Hong, Kunlun},
abstractNote = {A method for synthesizing a deuterated acrylate of the Formula (1), the method comprising: (i) deuterating a propiolate compound of Formula (2) to a methyne-deuterated propiolate compound of Formula (3) in the presence of a base and D.sub.2O: and (ii) reductively deuterating the methyne-deuterated propiolate compound of Formula (3) in a reaction solvent in the presence of deuterium gas and a palladium-containing catalyst to afford the deuterated acrylate of the Formula (1). The resulting deuterated acrylate compounds, derivatives thereof, and polymers derived therefrom are also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {9}
}

Patent:

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