Global to push GA events into
skip to main content

Title: Preparation of functionalized zeolitic frameworks

The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.
Inventors:
; ; ; ; ;
Issue Date:
OSTI Identifier:
1150640
Assignee:
The Regents of the University of California (Oakland, CA); The Regents of the University of Michigan (Ann Arbor, MI) CHO
Patent Number(s):
8,809,546
Application Number:
13/630,554
Contract Number:
FG02-06ER15813
Research Org:
University of California, Oakland, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Works referenced in this record:

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010
  • Phan, Anh; Doonan, Christian J.; Uribe-Romo, Fernando J.
  • Accounts of Chemical Research, Vol. 43, Issue 1, p. 58-67
  • DOI: 10.1021/ar900116g

Reticular synthesis and the design of new materials
journal, June 2003
  • Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
  • Nature, Vol. 423, Issue 6941, p. 705-714
  • DOI: 10.1038/nature01650

Sputtered boron films on silicon surface barrier detectors
journal, June 1967

Thin-film-coated bulk GaAs detectors for thermal and fast neutron measurements
journal, June 2001
  • McGregor, D. S.; Klann, R. T.; Gersch, H. K.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 466, Issue 1, p. 126-141
  • DOI: 10.1016/S0168-9002(01)00835-X

Design considerations for thin film coated semiconductor thermal neutron detectors—I: basics regarding alpha particle emitting neutron reactive films
journal, March 2003
  • McGregor, D. S.; Hammig, M. D.; Yang, Y.-H.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 500, Issue 1-3, p. 272-308
  • DOI: 10.1016/S0168-9002(02)02078-8

New surface morphology for low stress thin-film-coated thermal neutron detectors
journal, August 2002
  • McGregor, D. S.; Klann, R. T.; Gersch, H. K.
  • IEEE Transactions on Nuclear Science, Vol. 49, Issue 4, p. 1999-2004
  • DOI: 10.1109/TNS.2002.801697

A new neutron detector development based on silicon semiconductor and 6LiF converter
journal, June 1997

A neutron detector to monitor the intensity of transmitted neutrons for small-angle neutron scattering instruments
journal, June 2003
  • De Lurgio, Patrick M.; Klann, Raymond T.; Fink, Charles L.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 505, Issue 1-2, p. 46-49
  • DOI: 10.1016/S0168-9002(03)01017-9

The effect of incremental gamma-ray doses and incremental neutron fluences upon the performance of self-biased 10B-coated high-purity epitaxial GaAs thermal neutron detectors
journal, August 2002
  • Gersch, H. K.; McGregor, D. S.; Simpson, P. A.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 489, Issue 1-3, p. 85-98
  • DOI: 10.1016/S0168-9002(02)00793-3

Designs for thin-film-coated semiconductor thermal neutron detectors
conference, January 2002

Recent results from thin-film-coated semiconductor neutron detectors
conference, January 2003
  • McGregor, Douglas S.; Klann, Raymond T.; Sanders, Jeffrey D.
  • International Symposium on Optical Science and Technology, Vol. 4784
  • DOI: 10.1117/12.455697

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
  • Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
  • Nature, Vol. 427, Issue 6974, p. 523-527
  • DOI: 10.1038/nature02311

Porous Metal−Organic Polyhedra:  25 Å Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks
journal, May 2001
  • Eddaoudi, M.; Kim, Jaheon; Wachter, J. B.
  • Journal of the American Chemical Society, Vol. 123, Issue 18, p. 4368-4369
  • DOI: 10.1021/ja0104352

Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
journal, March 1997
  • Yaghi, O. M.; Davis, Charles E.; Li, Guangming
  • Journal of the American Chemical Society, Vol. 119, Issue 12, p. 2861-2868
  • DOI: 10.1021/ja9639473

From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999
  • Reineke, Theresa M.; Eddaoudi, Mohamed; Fehr, Michael
  • Journal of the American Chemical Society, Vol. 121, Issue 8, p. 1651-1657
  • DOI: 10.1021/ja983577d

An Open-Framework Germanate with Polycubane-Like Topology
journal, March 1999

A Microporous Lanthanide-Organic Framework
journal, September 1999

Tertiary Building Units:  Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1)
October 2001
  • Chae, Hee K.; Eddaoudi, Mohamed; Kim, Jaheon
  • Journal of the American Chemical Society, Vol. 123, Issue 46, p. 11482-11483
  • DOI: 10.1021/ja011692+

1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal–organic frameworks
journal, November 2001
  • Braun, Matthew E.; Steffek, Cory D.; Kim, Jaheon
  • Chemical Communications, Vol. 0, Issue 24, p. 2532-2533
  • DOI: 10.1039/B108031H

Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:  A Framework Deliberately Designed To Have the NbO Structure Type
journal, January 2002
  • Eddaoudi, Mohamed; Kim, Jaheon; O'Keeffe, Michael
  • Journal of the American Chemical Society, Vol. 124, Issue 3, p. 376-377
  • DOI: 10.1021/ja017154e

Crystal engineering of binary metal imidazolate and triazolate frameworks
journal, January 2006
  • Zhang, Jie-Peng; Chen, Xiao-Ming
  • Chemical Communications, Vol. 0, Issue 16, p. 1689-1699
  • DOI: 10.1039/B516367F

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006
  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Synthesis and Characterization of Zirconogermanates
journal, September 2003
  • Plévert, Jacques; Sanchez-Smith, Rebeca; Gentz, Travis M.
  • Inorganic Chemistry, Vol. 42, Issue 19, p. 5954-5959
  • DOI: 10.1021/ic034298g

Computation of Aromatic C3N4 Networks and Synthesis of the Molecular Precursor N(C3N3)3Cl6
journal, September 2003
  • Vodak, David T.; Kim, Kibum; Iordanidis, Lykourgos
  • Chemistry - A European Journal, Vol. 9, Issue 17, p. 4197-4201
  • DOI: 10.1002/chem.200304829

Three-periodic nets and tilings: regular and quasiregular nets
journal, December 2002
  • Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 1, p. 22-27
  • DOI: 10.1107/S0108767302018494

Three-periodic nets and tilings: semiregular nets
journal, October 2003
  • Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 6, p. 515-525
  • DOI: 10.1107/S0108767303017100

[Cd16In64S134]44-: 31-Å Tetrahedron with a Large Cavity
journal, April 2003
  • Li, Hailian; Kim, Jaheon; O'Keeffe, Michael
  • Angewandte Chemie International Edition, Vol. 42, Issue 16, p. 1819-1821
  • DOI: 10.1002/anie.200250748

Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology
journal, August 2003
  • Chae, Hee K.; Kim, Jaheon; Friedrichs, Olaf Delgado
  • Angewandte Chemie International Edition, Vol. 42, Issue 33, p. 3907-3909
  • DOI: 10.1002/anie.200351546

Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters
journal, February 2003
  • Plévert, Jacques; Gentz, Travis M.; Groy, Thomas L.
  • Chemistry of Materials, Vol. 15, Issue 3, p. 714-718
  • DOI: 10.1021/cm020469o

Design of New Materials for Methane Storage
journal, March 2004
  • Düren, Tina; Sarkisov, Lev; Yaghi, Omar M.
  • Langmuir, Vol. 20, Issue 7, p. 2683-2689
  • DOI: 10.1021/la0355500

Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004
  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667
  • DOI: 10.1021/ja049408c

Metal–organic frameworks: a new class of porous materials
journal, August 2004

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005
  • Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed
  • Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518
  • DOI: 10.1021/ja045123o

van der Waals Volumes and Radii
journal, March 1964
  • Bondi, A.
  • The Journal of Physical Chemistry, Vol. 68, Issue 3, p. 441-451
  • DOI: 10.1021/j100785a001

Positions of cations and molecules in zeolites with the faujasite-type framework I. Dehydrated Ca-exchanged faujasite
journal, August 1968

Aerogels—Airy Materials: Chemistry, Structure, and Properties
journal, February 1998

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Variable Pore Size, Variable Chemical Functionality, and an Example of Reactivity within Porous Phenylacetylene Silver Salts
journal, September 1999
  • Kiang, Y.-H.; Gardner, Geoffrey B.; Lee, Stephen
  • Journal of the American Chemical Society, Vol. 121, Issue 36, p. 8204-8215
  • DOI: 10.1021/ja991100b

Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000
  • Eddaoudi, Mohamed; Li, Hailian; Yaghi, O. M.
  • Journal of the American Chemical Society, Vol. 122, Issue 7, p. 1391-1397
  • DOI: 10.1021/ja9933386

A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4′-bipyridine)2}n]
journal, June 2000

Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry
journal, June 2000
  • Yaghi, O. M.; O'Keeffe, M.; Kanatzidis, M.
  • Journal of Solid State Chemistry, Vol. 152, Issue 1, p. 1-2
  • DOI: 10.1006/jssc.2000.8733

Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1
journal, May 2000
  • Reineke, Theresa M.; Eddaoudi, Mohamed; Moler, David
  • Journal of the American Chemical Society, Vol. 122, Issue 19, p. 4843-4844
  • DOI: 10.1021/ja000363z

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001
  • Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
  • Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
  • DOI: 10.1021/ar000034b

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures
journal, August 2001
  • Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.
  • Journal of the American Chemical Society, Vol. 123, Issue 34, p. 8239-8247
  • DOI: 10.1021/ja010825o

Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks
journal, January 2002

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

Syntheses and Characterization of Microporous Coordination Polymers with Open Frameworks
journal, February 2002
  • Seki, K.; Mori, W.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 6, p. 1380-1385
  • DOI: 10.1021/jp0130416

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003
  • Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed
  • Science, Vol. 300, Issue 5622, p. 1127-1129
  • DOI: 10.1126/science.1083440