Process for production of a metal hydride
Abstract
A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.
- Inventors:
- Issue Date:
- Research Org.:
- Rohm and Haas Company, Philadelphia, PA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1150093
- Patent Number(s):
- 8802051
- Application Number:
- 13/053,350
- Assignee:
- Rohm and Haas Company (Philadelphia, PA); Dow Global Technologies LLC (Midland, MI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- FC36-05GO15053
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Allen, Nathan Tait, Butterick, III, Robert, Chin, Arthur Achhing, Millar, Dean Michael, and Molzahn, David Craig. Process for production of a metal hydride. United States: N. p., 2014.
Web.
Allen, Nathan Tait, Butterick, III, Robert, Chin, Arthur Achhing, Millar, Dean Michael, & Molzahn, David Craig. Process for production of a metal hydride. United States.
Allen, Nathan Tait, Butterick, III, Robert, Chin, Arthur Achhing, Millar, Dean Michael, and Molzahn, David Craig. Tue .
"Process for production of a metal hydride". United States. https://www.osti.gov/servlets/purl/1150093.
@article{osti_1150093,
title = {Process for production of a metal hydride},
author = {Allen, Nathan Tait and Butterick, III, Robert and Chin, Arthur Achhing and Millar, Dean Michael and Molzahn, David Craig},
abstractNote = {A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {8}
}
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