Global to push GA events into
skip to main content

Title: Zeolitic imidazolate frameworks for kinetic separation of propane and propene

Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.
Inventors:
; ;
Issue Date:
OSTI Identifier:
1150001
Assignee:
Rutgers, The State University of New Jersey (New Brunswick, NJ) CHO
Patent Number(s):
8,796,462
Application Number:
13/109,614
Contract Number:
FG02-08ER46491
Research Org:
Rutgers, The State University of New Jersey, New Brunswick, NJ (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Works referenced in this record:

Zeolite A imidazolate frameworks
journal, May 2007
  • Hayashi, Hideki; Côté, Adrien P.; Furukawa, Hiroyasu
  • Nature Materials, Vol. 6, Issue 7, p. 501-506
  • DOI: 10.1038/nmat1927

Design and Generation of Extended Zeolitic Metal–Organic Frameworks (ZMOFs): Synthesis and Crystal Structures of Zinc(II) Imidazolate Polymers with Zeolitic Topologies
journal, May 2007
  • Tian, Yun-Qi; Zhao, Yu-Ming; Chen, Zhen-Xia
  • Chemistry - A European Journal, Vol. 13, Issue 15, p. 4146-4154
  • DOI: 10.1002/chem.200700181

Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008
  • Wang, Bo; Côté, Adrien P.; Furukawa, Hiroyasu
  • Nature, Vol. 453, Issue 7192, p. 207-211
  • DOI: 10.1038/nature06900

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008

Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008
  • Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627
  • DOI: 10.1021/ja805222x

A New Zeolitic Topology with Sixteen-Membered Ring and Multidimensional Large Pore Channels
journal, September 2008
  • Wu, Tao; Bu, Xianhui; Liu, Rui
  • Chemistry - A European Journal, Vol. 14, Issue 26, p. 7771-7773
  • DOI: 10.1002/chem.200800736

Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
journal, March 2009
  • Banerjee, Rahul; Furukawa, Hiroyasu; Britt, David
  • Journal of the American Chemical Society, Vol. 131, Issue 11, p. 3875-3877
  • DOI: 10.1021/ja809459e

Zeolitic Boron Imidazolate Frameworks
journal, March 2009
  • Zhang, Jian; Wu, Tao; Zhou, Cong
  • Angewandte Chemie, Vol. 121, Issue 14, p. 2580-2583
  • DOI: 10.1002/ange.200804169

Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies
journal, February 2006
  • Huang, Xiao-Chun; Lin, Yan-Yong; Zhang, Jie-Peng
  • Angewandte Chemie, Vol. 118, Issue 10, p. 1587-1589
  • DOI: 10.1002/ange.200503778

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006
  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment
journal, July 2009
  • Lamia, Nabil; Jorge, Miguel; Granato, Miguel A.
  • Chemical Engineering Science, Vol. 64, Issue 14, p. 3246-3259
  • DOI: 10.1016/j.ces.2009.04.010