Metal-organic frameworks for Xe/Kr separation
Abstract
Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.
- Inventors:
- Issue Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1149694
- Patent Number(s):
- 8784536
- Application Number:
- 13/974,406
- Assignee:
- Northwestern University (Evanston, IL)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- FG02-03ER15457
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Aug 23
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Ryan, Patrick J., Farha, Omar K., Broadbelt, Linda J., Snurr, Randall Q., and Bae, Youn-Sang. Metal-organic frameworks for Xe/Kr separation. United States: N. p., 2014.
Web.
Ryan, Patrick J., Farha, Omar K., Broadbelt, Linda J., Snurr, Randall Q., & Bae, Youn-Sang. Metal-organic frameworks for Xe/Kr separation. United States.
Ryan, Patrick J., Farha, Omar K., Broadbelt, Linda J., Snurr, Randall Q., and Bae, Youn-Sang. Tue .
"Metal-organic frameworks for Xe/Kr separation". United States. https://www.osti.gov/servlets/purl/1149694.
@article{osti_1149694,
title = {Metal-organic frameworks for Xe/Kr separation},
author = {Ryan, Patrick J. and Farha, Omar K. and Broadbelt, Linda J. and Snurr, Randall Q. and Bae, Youn-Sang},
abstractNote = {Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 22 00:00:00 EDT 2014},
month = {Tue Jul 22 00:00:00 EDT 2014}
}
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