Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

Title: Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

Abstract

The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

Inventors:: Way, J. Douglas; Hatlevik, Oyvind

Issue Date:: 2014-07-15

Research Org.:: Colorado School of Mines, Golden, CO (USA)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1144976

Patent Number(s):: 878058

Application Number:: 13/183,579

Assignee:: Colorado School of Mines (Golden, CO)

Patent Classifications (CPCs):: A - HUMAN NECESSITIES A01 - AGRICULTURE A01J - MANUFACTURE OF DAIRY PRODUCTS

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A - HUMAN NECESSITIES A01 - AGRICULTURE A01J - MANUFACTURE OF DAIRY PRODUCTS
A01J5/04 - with pneumatic manipulation of teats

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DOE Contract Number:: FG36-05GO15093

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

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                    Way, J. Douglas, and Hatlevik, Oyvind. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same.  United States: N. p., 2014. 
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                    Way, J. Douglas, & Hatlevik, Oyvind. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same.  United States.

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                    Way, J. Douglas, and Hatlevik, Oyvind. Tue .  
        "Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same".  United States.  https://www.osti.gov/servlets/purl/1144976.

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@article{osti_1144976,

  title        = {Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same},

  author       = {Way, J. Douglas and Hatlevik, Oyvind},

  abstractNote = {The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {7}

}

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Title: Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

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Method for forming supported palladium membrane used for hydrogen purification patent-application, May 2005

Atomic layer deposition of noble metals patent-application, May 2006

Sulfur-Resistant composite Metal Membranes patent-application, February 2008

Hydrogen Purification Membranes, Components and Fuel Processing Systems Containing the Same patent-application, September 2008

Composite Palladium Membrane Having Long-Term Stability for Hydrogen Separation patent-application, January 2009

Unsupported Palladium Alloy Membranes and Methods of Making Same patent-application, July 2009

Hydrogen Separation Membrane and Permselective Membrane Reactor patent-application, April 2010

Effect of hydrogen-sulfide on the hydrogen permeance of palladium?copper alloys at elevated temperatures journal, October 2004

Palladium–ruthenium membranes for hydrogen separation fabricated by electroless co-deposition journal, August 2009

Spontaneous Ordering of Oxide Nanostructures journal, March 2000

Irreversible poisoning of Pd-Ag membranes journal, November 1994

The effect of CO and O2 on hydrogen permeation through a palladium membrane journal, January 2000

Applications of catalytic inorganic membrane reactors to refinery products journal, September 1998

Membrane catalysis: Where is it now, what needs to be done? journal, August 1995

Methane Steam Reforming Analysis in a Palladium-Based Catalytic Membrane Reactor journal, August 1997

Preparation of highly dispersed catalytic metals Platinum supported on silica gel journal, April 1968

Alloys of palladium with metals of the platinum group as hydrogen-permeable membrane components at high temperatures of gas separation journal, January 1993

Hydrogen Transport through Tubular Membranes of Palladium-Coated Tantalum and Niobium journal, January 1996

Effects of electroless plating chemistry on the synthesis of palladium membranes journal, February 2001

Catalytic Dehydrogenation of Propane in Hydrogen Permselective Membrane Reactors journal, January 1996

Preparation and characterization of a composite palladium-ceramic membrane journal, December 1993

An economic feasibility study for water gas shift membrane reactor journal, January 2001

Composition and operation of hydrogen-selective amorphous alloy membranes journal, November 2006

The influence of intercrystalline defects on hydrogen activity and transport in nickel journal, August 1995

Solution of hydrogen in palladium/copper alloys journal, February 1977

Solubility of hydrogen (1 atm, 298 K) in some copper/palladium alloys journal, March 1975

Unsupported palladium alloy foil membranes fabricated by electroless plating journal, May 2008

Membrane catalysis journal, July 1999

Preparation and characterization of palladium composite membranes for hydrogen removal in hydrocarbon dehydrogenation membrane reactors journal, May 2001

A comparative study of hydrogen permeabilities and solubilities in some palladium solid solution alloys journal, October 1978

Fabrication of ultrathin metallic membranes on ceramic supports by sputter deposition journal, February 1995

Hydrogen permeation properties through composite membranes of platinum supported on porous alumina journal, February 2000

Stability and hydrogen permeation behavior of supported platinum membranes in presence of hydrogen sulfide journal, September 1999

Characterization of electroless plated palladium–silver alloy membranes journal, June 1999

Characterising palladium–silver and palladium–nickel alloy membranes using SEM, XRD and PIXE journal, September 1999

Developing a heating procedure to optimise hydrogen permeance through Pd–Ag membranes of thickness less than 2.2 μm journal, January 2002

Preparation of supported thin palladium-silver alloy membranes and their characteristics for hydrogen separation journal, December 1991

Pd and Pd–Cu membranes: inhibition of H permeation by HS journal, June 2005

Grain boundary segregation, stress and stretch: Effects on hydrogen absorption in nanocrystalline palladium journal, February 2007

Preparation of Pd/ceramic composite membrane 1. Improvement of the conventional preparation technique journal, February 1996

The effect of carbon monoxide and steam on the hydrogen permeability of a Pd/stainless steel membrane journal, January 2000

Composition control and hydrogen permeation characteristics of sputter deposited palladium–silver membranes journal, August 1999

The permeability of hydrogen in bulk palladium at elevated temperatures and pressures journal, February 2003

Hydrogen separation by Pd alloy composite membranes: introduction of diffusion barrier journal, October 2001

Preparation of a palladium alloy composite membrane supported in a porous stainless steel by vacuum electrodeposition journal, February 1999

A New Preparation Technique for Pd/Alumina Membranes with Enhanced High-Temperature Stability journal, May 1999

Innovations in Palladium Membrane Research journal, July 2002

Composite PdTa metal membranes for hydrogen separation journal, March 1996

Diffusion of Hydrogen in Copper‐Palladium Alloys journal, February 1966

The influence of alloy composition on the H2 flux of composite PdCu membranes journal, September 2002

Studies of the oxidation of palladium complexes by the advanced oxidation processPretreatment of model catalysts for precious metal analysis journal, September 2006

Economics and simulation of fluidized bed membrane reforming journal, September 1998

High-temperature membrane reactors: potential and problems journal, July 1999

Simultaneous deposition of Pd and Ag on porous stainless steel by electroless plating journal, March 1993

Cu-Pd (Copper-Palladium) journal, April 1991

Hydrogen permeable palladium-silver alloy membrane supported on porous ceramics journal, March 1991

Separation of hydrogen through palladium thin film supported on a porous glass tube journal, March 1991

State-of-the-Art of Supported Metal Membranes for Gas Separation journal, January 1999

Preparation of a Palladium Composite Membrane by an Improved Electroless Plating Technique journal, February 2000

Fabrication of thin metallic membranes by MOCVD and sputtering journal, October 1997

Novel preparation of Pd/Vycor composite membranes journal, August 1995

Novel preparation techniques for thin metal-ceramic composite membranes journal, September 1995

High temperature PEM fuel cells journal, October 2006

Preparation and characterization of palladium-based composite membranes by electroless plating and magnetron sputtering journal, February 2000

Preparation of palladium composite membranes by modified electroless plating procedure journal, May 1998

Method of preparing composite gas separation membranes from perfluoropolymers
patent, April 2003

Process for Preparing Palladium Alloy Composite Membranes for Use in Hydrogen Separation, Palladium Alloy Composite Membranes and Products Incorporating or Made from the Membranes
patent-application, October 2003

Method for curing defects in the fabrication of a composite gas separation module
patent-application, December 2004

Method for forming supported palladium membrane used for hydrogen purification
patent-application, May 2005

Atomic layer deposition of noble metals
patent-application, May 2006

Sulfur-Resistant composite Metal Membranes
patent-application, February 2008

Hydrogen Purification Membranes, Components and Fuel Processing Systems Containing the Same
patent-application, September 2008

Composite Palladium Membrane Having Long-Term Stability for Hydrogen Separation
patent-application, January 2009

Unsupported Palladium Alloy Membranes and Methods of Making Same
patent-application, July 2009

Hydrogen Separation Membrane and Permselective Membrane Reactor
patent-application, April 2010

Effect of hydrogen-sulfide on the hydrogen permeance of palladium?copper alloys at elevated temperatures
journal, October 2004

Palladium–ruthenium membranes for hydrogen separation fabricated by electroless co-deposition
journal, August 2009

Spontaneous Ordering of Oxide Nanostructures
journal, March 2000

Irreversible poisoning of Pd-Ag membranes
journal, November 1994

The effect of CO and O₂ on hydrogen permeation through a palladium membrane
journal, January 2000

Applications of catalytic inorganic membrane reactors to refinery products
journal, September 1998

Membrane catalysis: Where is it now, what needs to be done?
journal, August 1995

Methane Steam Reforming Analysis in a Palladium-Based Catalytic Membrane Reactor
journal, August 1997

Preparation of highly dispersed catalytic metals Platinum supported on silica gel
journal, April 1968

Alloys of palladium with metals of the platinum group as hydrogen-permeable membrane components at high temperatures of gas separation
journal, January 1993

Hydrogen Transport through Tubular Membranes of Palladium-Coated Tantalum and Niobium
journal, January 1996

Effects of electroless plating chemistry on the synthesis of palladium membranes
journal, February 2001

Catalytic Dehydrogenation of Propane in Hydrogen Permselective Membrane Reactors
journal, January 1996

Preparation and characterization of a composite palladium-ceramic membrane
journal, December 1993

An economic feasibility study for water gas shift membrane reactor
journal, January 2001

Composition and operation of hydrogen-selective amorphous alloy membranes
journal, November 2006

The influence of intercrystalline defects on hydrogen activity and transport in nickel
journal, August 1995

Solution of hydrogen in palladium/copper alloys
journal, February 1977

Solubility of hydrogen (1 atm, 298 K) in some copper/palladium alloys
journal, March 1975

Unsupported palladium alloy foil membranes fabricated by electroless plating
journal, May 2008

Membrane catalysis
journal, July 1999

Preparation and characterization of palladium composite membranes for hydrogen removal in hydrocarbon dehydrogenation membrane reactors
journal, May 2001

A comparative study of hydrogen permeabilities and solubilities in some palladium solid solution alloys
journal, October 1978

Fabrication of ultrathin metallic membranes on ceramic supports by sputter deposition
journal, February 1995

Hydrogen permeation properties through composite membranes of platinum supported on porous alumina
journal, February 2000

Stability and hydrogen permeation behavior of supported platinum membranes in presence of hydrogen sulfide
journal, September 1999

Characterization of electroless plated palladium–silver alloy membranes
journal, June 1999

Characterising palladium–silver and palladium–nickel alloy membranes using SEM, XRD and PIXE
journal, September 1999

Developing a heating procedure to optimise hydrogen permeance through Pd–Ag membranes of thickness less than 2.2 μm
journal, January 2002

Preparation of supported thin palladium-silver alloy membranes and their characteristics for hydrogen separation
journal, December 1991

Pd and Pd–Cu membranes: inhibition of H permeation by HS
journal, June 2005

Grain boundary segregation, stress and stretch: Effects on hydrogen absorption in nanocrystalline palladium
journal, February 2007

Preparation of Pd/ceramic composite membrane 1. Improvement of the conventional preparation technique
journal, February 1996

The effect of carbon monoxide and steam on the hydrogen permeability of a Pd/stainless steel membrane
journal, January 2000

Composition control and hydrogen permeation characteristics of sputter deposited palladium–silver membranes
journal, August 1999

The permeability of hydrogen in bulk palladium at elevated temperatures and pressures
journal, February 2003

Hydrogen separation by Pd alloy composite membranes: introduction of diffusion barrier
journal, October 2001

Preparation of a palladium alloy composite membrane supported in a porous stainless steel by vacuum electrodeposition
journal, February 1999

A New Preparation Technique for Pd/Alumina Membranes with Enhanced High-Temperature Stability
journal, May 1999

Innovations in Palladium Membrane Research
journal, July 2002

Composite PdTa metal membranes for hydrogen separation
journal, March 1996

Diffusion of Hydrogen in Copper‐Palladium Alloys
journal, February 1966

The influence of alloy composition on the H₂ flux of composite PdCu membranes
journal, September 2002

Studies of the oxidation of palladium complexes by the advanced oxidation processPretreatment of model catalysts for precious metal analysis
journal, September 2006

Economics and simulation of fluidized bed membrane reforming
journal, September 1998

High-temperature membrane reactors: potential and problems
journal, July 1999

Simultaneous deposition of Pd and Ag on porous stainless steel by electroless plating
journal, March 1993

Cu-Pd (Copper-Palladium)
journal, April 1991

Hydrogen permeable palladium-silver alloy membrane supported on porous ceramics
journal, March 1991

Separation of hydrogen through palladium thin film supported on a porous glass tube
journal, March 1991

State-of-the-Art of Supported Metal Membranes for Gas Separation
journal, January 1999

Preparation of a Palladium Composite Membrane by an Improved Electroless Plating Technique
journal, February 2000

Fabrication of thin metallic membranes by MOCVD and sputtering
journal, October 1997

Novel preparation of Pd/Vycor composite membranes
journal, August 1995

Novel preparation techniques for thin metal-ceramic composite membranes
journal, September 1995

High temperature PEM fuel cells
journal, October 2006

Preparation and characterization of palladium-based composite membranes by electroless plating and magnetron sputtering
journal, February 2000

Preparation of palladium composite membranes by modified electroless plating procedure
journal, May 1998