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Title: Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.
Issue Date:
OSTI Identifier:
Colorado School of Mines (Golden, CO) GFO
Patent Number(s):
Application Number:
Contract Number:
Research Org:
Colorado School of Mines, Golden, CO (USA)
Sponsoring Org:
Country of Publication:
United States

Works referenced in this record:

Palladium–ruthenium membranes for hydrogen separation fabricated by electroless co-deposition
journal, August 2009
  • Gade, Sabina K.; Keeling, Matthew K.; Davidson, Alexander P.
  • International Journal of Hydrogen Energy, Vol. 34, Issue 15, p. 6484-6491
  • DOI: 10.1016/j.ijhydene.2009.06.037

The effect of CO and O2 on hydrogen permeation through a palladium membrane
journal, January 2000

Applications of catalytic inorganic membrane reactors to refinery products
journal, September 1998

Membrane catalysis: Where is it now, what needs to be done?
journal, August 1995

Preparation of highly dispersed catalytic metals Platinum supported on silica gel
journal, April 1968

Composition and operation of hydrogen-selective amorphous alloy membranes
journal, November 2006
  • Dolan, M. D.; Dave, N. C.; Ilyushechkin, A. Y.
  • Journal of Membrane Science, Vol. 285, Issue 1-2, p. 30-55
  • DOI: 10.1016/j.memsci.2006.09.014

The influence of intercrystalline defects on hydrogen activity and transport in nickel
journal, August 1995

Solution of hydrogen in palladium/copper alloys
journal, February 1977
  • Fisher, D.; Chisdes, D. M.; Flanagan, Ted B.
  • Journal of Solid State Chemistry, Vol. 20, Issue 2, p. 149-158
  • DOI: 10.1016/0022-4596(77)90062-7

Solubility of hydrogen (1 atm, 298 K) in some copper/palladium alloys
journal, March 1975

Unsupported palladium alloy foil membranes fabricated by electroless plating
journal, May 2008
  • Gade, Sabina K.; Thoen, Paul M.; Way, J. Douglas
  • Journal of Membrane Science, Vol. 316, Issue 1-2, p. 112-118
  • DOI: 10.1016/j.memsci.2007.08.022

Preparation and characterization of palladium composite membranes for hydrogen removal in hydrocarbon dehydrogenation membrane reactors
journal, May 2001

A comparative study of hydrogen permeabilities and solubilities in some palladium solid solution alloys
journal, October 1978

Fabrication of ultrathin metallic membranes on ceramic supports by sputter deposition
journal, February 1995

Hydrogen permeation properties through composite membranes of platinum supported on porous alumina
journal, February 2000

Characterization of electroless plated palladium–silver alloy membranes
journal, June 1999

Characterising palladium–silver and palladium–nickel alloy membranes using SEM, XRD and PIXE
journal, September 1999
  • Keuler, J. N.; Lorenzen, L.; Sanderson, R. D.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 158, Issue 1-4, p. 678-682
  • DOI: 10.1016/S0168-583X(99)00326-2

Preparation of supported thin palladium-silver alloy membranes and their characteristics for hydrogen separation
journal, December 1991

Grain boundary segregation, stress and stretch: Effects on hydrogen absorption in nanocrystalline palladium
journal, February 2007

Preparation of Pd/ceramic composite membrane 1. Improvement of the conventional preparation technique
journal, February 1996

The effect of carbon monoxide and steam on the hydrogen permeability of a Pd/stainless steel membrane
journal, January 2000

Composition control and hydrogen permeation characteristics of sputter deposited palladium–silver membranes
journal, August 1999

The permeability of hydrogen in bulk palladium at elevated temperatures and pressures
journal, February 2003
  • Morreale, Bryan D.; Ciocco, Michael V.; Enick, Robert M.
  • Journal of Membrane Science, Vol. 212, Issue 1-2, p. 87-97
  • DOI: 10.1016/S0376-7388(02)00456-8

Preparation of a palladium alloy composite membrane supported in a porous stainless steel by vacuum electrodeposition
journal, February 1999

Composite PdTa metal membranes for hydrogen separation
journal, March 1996

The influence of alloy composition on the H2 flux of composite PdCu membranes
journal, September 2002

Studies of the oxidation of palladium complexes by the advanced oxidation processPretreatment of model catalysts for precious metal analysis
journal, September 2006

High-temperature membrane reactors: potential and problems
journal, July 1999
  • Saracco, G.; Neomagus, H. W. J. P.; Versteeg, G. F.
  • Chemical Engineering Science, Vol. 54, Issue 13-14, p. 1997-2017
  • DOI: 10.1016/S0009-2509(99)00009-3

Simultaneous deposition of Pd and Ag on porous stainless steel by electroless plating
journal, March 1993

Fabrication of thin metallic membranes by MOCVD and sputtering
journal, October 1997

Novel preparation of Pd/Vycor composite membranes
journal, August 1995

Novel preparation techniques for thin metal-ceramic composite membranes
journal, September 1995
  • Lun Yeung, King; Varma, Arvind
  • AIChE Journal, Vol. 41, Issue 9, p. 2131-2139
  • DOI: 10.1002/aic.690410912

High temperature PEM fuel cells
journal, October 2006

Preparation and characterization of palladium-based composite membranes by electroless plating and magnetron sputtering
journal, February 2000

Preparation of palladium composite membranes by modified electroless plating procedure
journal, May 1998