Electro-chemical sensors, sensor arrays and circuits
Abstract
An electro-chemical sensor includes a first electrode, a second electrode spaced apart from the first electrode, and a semiconductor channel in electrical contact with the first and second electrodes. The semiconductor channel includes a trapping material. The trapping material reduces an ability of the semiconductor channel to conduct a current of charge carriers by trapping at least some of the charge carriers to localized regions within the semiconductor channel. The semiconductor channel includes at least a portion configured to be exposed to an analyte to be detected, and the trapping material, when exposed to the analyte, interacts with the analyte so as to at least partially restore the ability of the semiconductor channel to conduct the current of charge carriers.
- Inventors:
- Issue Date:
- Research Org.:
- Johns Hopkins Univ., Baltimore, MD (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1136991
- Patent Number(s):
- 8772764
- Application Number:
- 13/725,630
- Assignee:
- The Johns Hopkins University (Baltimore, MD)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- DOE Contract Number:
- FG02-07ER46465
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION
Citation Formats
Katz, Howard E., and Kong, Hoyoul. Electro-chemical sensors, sensor arrays and circuits. United States: N. p., 2014.
Web.
Katz, Howard E., & Kong, Hoyoul. Electro-chemical sensors, sensor arrays and circuits. United States.
Katz, Howard E., and Kong, Hoyoul. Tue .
"Electro-chemical sensors, sensor arrays and circuits". United States. https://www.osti.gov/servlets/purl/1136991.
@article{osti_1136991,
title = {Electro-chemical sensors, sensor arrays and circuits},
author = {Katz, Howard E. and Kong, Hoyoul},
abstractNote = {An electro-chemical sensor includes a first electrode, a second electrode spaced apart from the first electrode, and a semiconductor channel in electrical contact with the first and second electrodes. The semiconductor channel includes a trapping material. The trapping material reduces an ability of the semiconductor channel to conduct a current of charge carriers by trapping at least some of the charge carriers to localized regions within the semiconductor channel. The semiconductor channel includes at least a portion configured to be exposed to an analyte to be detected, and the trapping material, when exposed to the analyte, interacts with the analyte so as to at least partially restore the ability of the semiconductor channel to conduct the current of charge carriers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {7}
}
Works referenced in this record:
Bioluminescent bioreporter integrated circuit detection methods
patent, June 2005
- Simpson, Michael L.; Paulus, Michael J.; Sayler, Gary S.
- US Patent Document 6,905,834
Polymer Semiconductors with High Mobility
patent-application, July 2009
- Pan, Hualong; Wu, Yiliang; Liu, Ping
- US Patent Application 12/013700; 20090181509
Ammonia Nanosensors, and Environmental Control System
patent-application, March 2013
- Briman, Mikhail; Bryant, Craig; Chang, Ying-Lan
- US Patent Application 13/442720; 20130075690
Materials and Applications for Large Area Electronics: Solution-Based Approaches
journal, January 2010
- Arias, Ana Claudia; MacKenzie, J. Devin; McCulloch, Iain
- Chemical Reviews, Vol. 110, Issue 1
Localized Charge Transfer in a Molecularly Doped Conducting Polymer
journal, September 2007
- Aziz, E. F.; Vollmer, A.; Eisebitt, S.
- Advanced Materials, Vol. 19, Issue 20, p. 3257-3260
Modification of electrodes with porphyrin-functionalised conductive polymers
journal, June 1998
- Ballarin, B.; Masiero, S.; Seeber, R.
- Journal of Electroanalytical Chemistry, Vol. 449, Issue 1-2, p. 173-180
Synthesis and Self-Assembly of Copolymers with Pendant Electroactive Units
journal, September 2008
- Barik, Satyananda; Valiyaveettil, Suresh
- Macromolecules, Vol. 41, Issue 17
Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications
journal, December 2011
- Beaujuge, Pierre M.; Fréchet, Jean M. J.
- Journal of the American Chemical Society, Vol. 133, Issue 50, p. 20009-20029
Rapid and Efficient Post-Polymerization Functionalization of Poly(3,4-ethylenedioxythiophene) (PEDOT) Derivatives on an Electrode Surface
journal, August 2001
- Besbes, M.; Trippé, G.; Leviallain, E.
- Advanced Materials, Vol. 13, Issue 16
Optical, Electrochemical, Magnetic, and Conductive Properties of New Polyindolocarbazoles and Polydiindolocarbazoles
journal, January 2006
- Blouin, Nicolas; Michaud, Alexandre; Wakim, Salem
- Macromolecular Chemistry and Physics, Vol. 207, Issue 2
Towards highly oriented polythiophenes incorporating mesogenic or tetrathiafulvalene substituents
journal, January 1991
- Bryce, Martin R.; Chissel, André D.; Gopal, Jaya
- Synthetic Metals, Vol. 39, Issue 3, p. 397-400
Comparison of surface and bulk doping levels in chemical polypyrroles of low, medium and high conductivity
journal, January 2006
- Carrasco, Pedro M.; Cortazar, Milagros; Ochoteco, Estibalitz
- Surface and Interface Analysis, Vol. 39, Issue 1
Printable polythiophene gas sensor array for low-cost electronic noses
journal, July 2006
- Chang, Josephine B.; Liu, Vincent; Subramanian, Vivek
- Journal of Applied Physics, Vol. 100, Issue 1
Synthesis of Conjugated Polymers for Organic Solar Cell Applications
journal, November 2009
- Cheng, Yen-Ju; Yang, Sheng-Hsiung; Hsu, Chain-Shu
- Chemical Reviews, Vol. 109, Issue 11
Electronic sensing of vapors with organic transistors
journal, April 2001
- Crone, B.; Dodabalapur, A.; Gelperin, A.
- Applied Physics Letters, Vol. 78, Issue 15
Organic Thin Film Transistors for Large Area Electronics
journal, January 2002
- Dimitrakopoulos, C.D.; Malenfant, P. R. L.
- Advanced Materials, Vol. 14, Issue 2, p. 99-117
Research progress on polymer–inorganic thermoelectric nanocomposite materials
journal, June 2012
- Du, Yong; Shen, Shirley Z.; Cai, Kefeng
- Progress in Polymer Science, Vol. 37, Issue 6, p. 820-841
Conducting polymers: Efficient thermoelectric materials
journal, February 2011
- Dubey, Nidhi; Leclerc, Mario
- Journal of Polymer Science Part B: Polymer Physics, Vol. 49, Issue 7
Semiconductors for organic transistors
journal, March 2007
- Facchetti, Antonio
- Materials Today, Vol. 10, Issue 3
π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications †
journal, February 2011
- Facchetti, Antonio
- Chemistry of Materials, Vol. 23, Issue 3
The path to ubiquitous and low-cost organic electronic appliances on plastic
journal, April 2004
- Forrest, Stephen R.
- Nature, Vol. 428, Issue 6986, p. 911-918
Improved Syntheses of Carboxytetrathiafulvalene, Formyltetrathiafulvalene and (Hydroxymethyl)tetrathiafulvalene 1 : Versatile Building Blocks for New Functionalised Tetrathiafulvalene Derivatives
journal, January 1994
- Garín, Javier; Orduna, Jesús; Uriel, Santiago
- Synthesis, Vol. 1994, Issue 05
Electrosynthesis of a tetrathiafulvalene-derivatized polythiophene
journal, August 1993
- Thobie-Gautier, Christine; Gorgues, Alain; Jubault, Michel
- Macromolecules, Vol. 26, Issue 16
Conjugated Polymer-Based Organic Solar Cells
journal, April 2007
- Günes, Serap; Neugebauer, Helmut; Sariciftci, Niyazi Serdar
- Chemical Reviews, Vol. 107, Issue 4, p. 1324-1338
Poly(3,6-dihexyl-thieno[3,2-b]thiophene vinylene): Synthesis, Field-Effect Transistors, and Photovoltaic Properties
journal, December 2008
- He, Youjun; Wu, Weiping; Zhao, Guangjing
- Macromolecules, Vol. 41, Issue 24
High thermoelectric performance of poly(2,5-dimethoxyphenylenevinylene) and its derivatives
journal, December 2006
- Hiroshige, Yuji; Ookawa, Makoto; Toshima, Naoki
- Synthetic Metals, Vol. 156, Issue 21-24
Thermoelectric figure-of-merit of iodine-doped copolymer of phenylenevinylene with dialkoxyphenylenevinylene
journal, June 2007
- Hiroshige, Yuji; Ookawa, Makoto; Toshima, Naoki
- Synthetic Metals, Vol. 157, Issue 10-12, p. 467-474
Monolayer‐Dimensional 5,5′‐Bis(4‐hexylphenyl)‐2,2′‐bithiophene Transistors and Chemically Responsive Heterostructures
journal, July 2008
- Huang, Jia; Sun, Jia; Katz, Howard E.
- Advanced Materials, Vol. 20, Issue 13, p. 2567-2572
Molecular Junctions Composed of Oligothiophene Dithiol-Bridged Gold Nanoparticles Exhibiting Photoresponsive Properties
journal, January 2006
- Huang, Wei; Masuda, Gou; Maeda, Seisuke
- Chemistry - A European Journal, Vol. 12, Issue 2, p. 607-619
Hydroxy-Terminated Organic Semiconductor-Based Field-Effect Transistors for Phosphonate Vapor Detection
journal, August 2007
- Huang, Jia; Miragliotta, Joseph; Becknell, Alan
- Journal of the American Chemical Society, Vol. 129, Issue 30
Response diversity and dual response mechanism of organic field-effect transistors with dinitrotoluene vapor
journal, January 2010
- Huang, J.; Dawidczyk, T. J.; Jung, B. J.
- J. Mater. Chem., Vol. 20, Issue 13
Spectroelectrochemistry of Electrogenerated Tetrathiafulvalene-Derivatized Poly(thiophenes): Toward a Rational Design of Organic Conductors with Mixed Conduction
journal, October 1998
- Huchet, Laurent; Akoudad, Said; Levillain, Eric
- The Journal of Physical Chemistry B, Vol. 102, Issue 40
Electrosynthesis of Highly Electroactive Tetrathiafulvalene-Derivatized Polythiophenes
journal, May 1998
- Huchet, Laurent; Akoudad, Said; Roncali, Jean
- Advanced Materials, Vol. 10, Issue 7, p. 541-545
Thermoelectric power and conductivity of different types of polypyrrole
journal, May 1999
- Kemp, N. T.; Kaiser, A. B.; Liu, C.-J.
- Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 9, p. 953-960
Electrical “Turn-On” Response of Poly(3,3‴-didodecylquaterthiophene) and Electron Donor Blend Transistors to 2,4,6-Trinitrotoluene
journal, July 2012
- Kong, Hoyoul; Jung, Byung Jun; Sinha, Jasmine
- Chemistry of Materials, Vol. 24, Issue 14
Supramolecular Structures from Rod−Coil Block Copolymers
journal, December 2001
- Lee, Myongsoo; Cho, Byoung-Ki; Zin, Wang-Cheol
- Chemical Reviews, Vol. 101, Issue 12
Synthesis and Thermoelectric Properties of Polycarbazole, Polyindolocarbazole, and Polydiindolocarbazole Derivatives
journal, April 2007
- Lévesque, Isabelle; Bertrand, Pier-Olivier; Blouin, Nicolas
- Chemistry of Materials, Vol. 19, Issue 8
Humidity effect on electrical performance of organic thin-film transistors
journal, January 2005
- Li, Dawen; Borkent, Evert-Jan; Nortrup, Robert
- Applied Physics Letters, Vol. 86, Issue 4
Tuning Optical Properties and Enhancing Solid-State Emission of Poly(thiophene)s by Molecular Control: A Postfunctionalization Approach
journal, August 2002
- Li, Yuning; Vamvounis, George; Holdcroft, Steven
- Macromolecules, Vol. 35, Issue 18
Self-Assembly of α-Functionalized Terthiophenes on Gold
journal, July 1997
- Liedberg, B.; Yang, Z.; Engquist, I.
- The Journal of Physical Chemistry B, Vol. 101, Issue 31
Development of Dendrimers: Macromolecules for Use in Organic Light-Emitting Diodes and Solar Cells
journal, April 2007
- Lo, Shih-Chun; Burn, Paul L.
- Chemical Reviews, Vol. 107, Issue 4, p. 1097-1116
Polyfluorene-Based Light-Emitting Rod−Coil Block Copolymers
journal, October 2005
- Lu, Su; Liu, Tianxi; Ke, Lin
- Macromolecules, Vol. 38, Issue 20
Univocal Demonstration of the Electrochemically Mediated Binding of Pb 2+ by a Modified Surface Incorporating a TTF-Based Redox-Switchable Ligand
journal, October 2004
- Lyskawa, Joël; Le Derf, Franck; Levillain, Eric
- Journal of the American Chemical Society, Vol. 126, Issue 39
Electrical conductivity and thermoelectric power of polypyrrole with different doping levels
journal, October 1988
- Maddison, D. S.; Unsworth, J.; Roberts, R. B.
- Synthetic Metals, Vol. 26, Issue 1, p. 99-108
Metallic transport properties in electrochemically as-grown and heavily doped polythiophene and poly(3-methylthiophene)
journal, April 1993
- Masubuchi, S.; Kazama, S.; Mizoguchi, K.
- Synthetic Metals, Vol. 57, Issue 2-3, p. 4962-4967
Correlation of Seebeck coefficient and electric conductivity in polyaniline and polypyrrole
journal, March 1998
- Mateeva, N.; Niculescu, H.; Schlenoff, J.
- Journal of Applied Physics, Vol. 83, Issue 6
Conjugated Polymer-Based Chemical Sensors
journal, July 2000
- McQuade, D. Tyler; Pullen, Anthony E.; Swager, Timothy M.
- Chemical Reviews, Vol. 100, Issue 7
Functional Oligothiophenes: Molecular Design for Multidimensional Nanoarchitectures and Their Applications †
journal, March 2009
- Mishra, Amaresh; Ma, Chang-Qi; Bäuerle, Peter
- Chemical Reviews, Vol. 109, Issue 3
Self-assembly of nanoscale cuboctahedra by coordination chemistry
journal, April 1999
- Olenyuk, Bogdan; Whiteford, Jeffery A.; Fechtenkötter, Andreas
- Nature, Vol. 398, Issue 6730, p. 796-799
All jet-printed polymer thin-film transistor active-matrix backplanes
journal, October 2004
- Arias, A. C.; Ready, S. E.; Lujan, R.
- Applied Physics Letters, Vol. 85, Issue 15
Molecular and Supramolecular Architectures of Organic Semiconductors for Field-Effect Transistor Devices and Sensors: A Synthetic Chemical Perspective
journal, December 2010
- Operamolla, Alessandra; Farinola, Gianluca M.
- European Journal of Organic Chemistry, Vol. 2011, Issue 3
Advances in Molecular Design and Synthesis of Regioregular Polythiophenes
journal, September 2008
- Osaka, Itaru; McCullough, Richard D.
- Accounts of Chemical Research, Vol. 41, Issue 9
Metallic properties of transition metal halides doped polyacetylene: The soliton liquid state
journal, April 1991
- Park, Y. W.; Yoon, C. O.; Na, B. C.
- Synthetic Metals, Vol. 41, Issue 1-2, p. 27-32
Structure and morphology: relation to thermopower properties of conductive polymers
journal, November 1991
- Park, Y. W.
- Synthetic Metals, Vol. 45, Issue 2, p. 173-182
Anisotropy of thermoelectric power of stretch-oriented new polyacetylene
journal, February 1994
- Pukacki, Wojciech; Płocharski, Janusz; Roth, Siegmar
- Synthetic Metals, Vol. 62, Issue 3, p. 253-256
Characterization of the conductivity of organic thiols by field emission microscopy and field emission spectroscopy
journal, December 1994
- Purcell, S. T.; Garcia, N.; Binh, Vu Thien
- Journal of the American Chemical Society, Vol. 116, Issue 26, p. 11985-11989
Tuning of the aqueous electroactivity of substituted poly(thiophene)s by ether groups
journal, June 1990
- Roncali, Jean; Shi, Li Hong; Garreau, Robert
- Synthetic Metals, Vol. 36, Issue 2, p. 267-273
Analyte selective response in solution-deposited tetrabenzoporphyrin thin-film field-effect transistor sensors
journal, November 2011
- Royer, James E.; Lee, Sangyeob; Chen, Charlene
- Sensors and Actuators B: Chemical, Vol. 158, Issue 1, p. 333-339
Synthesis and characterization of oligo- and crown ether-substituted polythiophenes-a comparative study
journal, January 1999
- Scheib, Stefan; Bäuerle, Peter
- Journal of Materials Chemistry, Vol. 9, Issue 9
Enhanced Response of n-Channel Naphthalenetetracarboxylic Diimide Transistors to Dimethyl Methylphosphonate Using Phenolic Receptors
journal, September 2007
- See, K. C.; Becknell, A.; Miragliotta, J.
- Advanced Materials, Vol. 19, Issue 20, p. 3322-3327
Simultaneous Increase in Seebeck Coefficient and Conductivity in a Doped Poly(alkylthiophene) Blend with Defined Density of States
journal, March 2010
- Sun, J.; Yeh, M. -L.; Jung, B. J.
- Macromolecules, Vol. 43, Issue 6
Molecular recognition and chemoresistive materials
journal, July 1994
- Swager, Timothy M.; Marsella, Michael J.
- Advanced Materials, Vol. 6, Issue 7-8, p. 595-597
Electron transport in networks of gold nanoparticles connected by oligothiophene molecular wires
journal, January 2006
- Taniguchi, Shin-ichi; Minamoto, Masaru; Matsushita, Michio M.
- Journal of Materials Chemistry, Vol. 16, Issue 34
Polymer–Fullerene Composite Solar Cells
journal, January 2008
- Thompson, Barry C.; Fréchet, Jean M. J.
- Angewandte Chemie International Edition, Vol. 47, Issue 1, p. 58-77
Side-Chain Role in Chemically Sensing Conducting Polymer Field-Effect Transistors
journal, August 2003
- Torsi, L.; Tanese, M. C.; Cioffi, N.
- The Journal of Physical Chemistry B, Vol. 107, Issue 31
Contact effects in organic thin-film transistor sensors
journal, April 2009
- Torsi, Luisa; Marinelli, Francesco; Angione, M. Daniela
- Organic Electronics, Vol. 10, Issue 2, p. 233-239
Conductive polymers as a new type of thermoelectric material
journal, August 2002
- Toshima, Naoki
- Macromolecular Symposia, Vol. 186, Issue 1
Digital-Inverter Amine Sensing via Synergistic Responses by n and p Organic Semiconductors
journal, September 2011
- Tremblay, Noah J.; Jung, Byung Jun; Breysse, Patrick
- Advanced Functional Materials, Vol. 21, Issue 22
Charge Transport, Photovoltaic, and Thermoelectric Properties of Poly(2,7‐Carbazole) and Poly(Indolo[3,2‐b]Carbazole) Derivatives
journal, August 2008
- Wakim, Salem; Aïch, Badrou‐Réda; Tao, Ye
- Polymer Reviews, Vol. 48, Issue 3, p. 432-462
Recent Progress in n-Channel Organic Thin-Film Transistors
journal, January 2010
- Wen, Yugeng; Liu, Yunqi
- Advanced Materials, Vol. 22, Issue 12, p. 1331-1345
Thermoelectric properties of conducting polymers: The case of poly(3-hexylthiophene)
journal, September 2010
- Xuan, Y.; Liu, X.; Desbief, S.
- Physical Review B, Vol. 82, Issue 11
Electronic and Thermoelectric Properties of Polyaniline Organic Semiconductor and Electrical Characterization of Al/PANI MIS Diode
journal, February 2007
- Yakuphanoglu, F.; Şenkal, B. F.
- The Journal of Physical Chemistry C, Vol. 111, Issue 4
Highly polarized electron donors, acceptors and donor–acceptor compounds for organic conductors
journal, January 1998
- Yamashita, Yoshiro; Tomura, Masaaki
- Journal of Materials Chemistry, Vol. 8, Issue 9
Three-Dimensional Electronic Delocalization in Chiral Conjugated Polymers
journal, November 2002
- Zahn, Steffen; Swager, Timothy M.
- Angewandte Chemie, Vol. 114, Issue 22, p. 4399-4404
Humidity sensors based on pentacene thin-film transistors
journal, December 2002
- Zhu, Zheng-Tao; Mason, Jeffrey T.; Dieckmann, Rüdiger
- Applied Physics Letters, Vol. 81, Issue 24
Thermoelectric power and conductivity of iodine‐doped ‘‘new’’ polyacetylene
journal, July 1991
- Zuzok, R.; Kaiser, A. B.; Pukacki, W.
- The Journal of Chemical Physics, Vol. 95, Issue 2