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Title: Gas sensor incorporating a porous framework

Abstract

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
Univ. of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1132801
Patent Number(s):
8735161
Application Number:
13/936,315
Assignee:
The Regents of the University of California (Oakland, CA); BASF SE (Ludwigshafen, DE)
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
DOE Contract Number:  
FG02-08ER15935
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Jul 08
Country of Publication:
United States
Language:
English
Subject:
47 OTHER INSTRUMENTATION

Citation Formats

Yaghi, Omar M, Czaja, Alexander U, Wang, Bo, Galatsis, Kosmas, Wang, Kang L, and Furukawa, Hiroyasu. Gas sensor incorporating a porous framework. United States: N. p., 2014. Web.
Yaghi, Omar M, Czaja, Alexander U, Wang, Bo, Galatsis, Kosmas, Wang, Kang L, & Furukawa, Hiroyasu. Gas sensor incorporating a porous framework. United States.
Yaghi, Omar M, Czaja, Alexander U, Wang, Bo, Galatsis, Kosmas, Wang, Kang L, and Furukawa, Hiroyasu. Tue . "Gas sensor incorporating a porous framework". United States. https://www.osti.gov/servlets/purl/1132801.
@article{osti_1132801,
title = {Gas sensor incorporating a porous framework},
author = {Yaghi, Omar M and Czaja, Alexander U and Wang, Bo and Galatsis, Kosmas and Wang, Kang L and Furukawa, Hiroyasu},
abstractNote = {The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {5}
}

Patent:

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Works referenced in this record:

Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
  • https://doi.org/10.1021/ja042802q

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008


Reticular Chemistry of Metal–Organic Polyhedra
journal, June 2008


Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0
journal, September 2008


Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009

  • Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
  • https://doi.org/10.1039/b817735j

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009

  • Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571
  • https://doi.org/10.1021/ja8096256

Crystalline Covalent Organic Frameworks with Hydrazone Linkages
journal, August 2011

  • Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481
  • https://doi.org/10.1021/ja204728y

Synthesis of Metal−Organic Complex Arrays
journal, February 2011

  • Vairaprakash, Pothiappan; Ueki, Hisanori; Tashiro, Kentaro
  • Journal of the American Chemical Society, Vol. 133, Issue 4, p. 759-761
  • https://doi.org/10.1021/ja1097644

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks
journal, January 2008


Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007


Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008


Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008


Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry
journal, June 2000


Reticular synthesis and the design of new materials
journal, June 2003


Metal–organic Frameworks: A tale of two entanglements
journal, February 2007


Reticular Chemistry and Metal-Organic Frameworks for Clean Energy
journal, September 2009


A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers
journal, July 2005


Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
journal, February 2007


Metal-organic frameworks—New materials for hydrogen storage
journal, April 2007


Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007


Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
journal, November 2007


Combinatorial Material Libraries on the Microgram Scale with an Example of Hydrothermal Synthesis
journal, December 1998


A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008


Parallel Synthesis of ZSM-5 Zeolite Films from Clear Organic-Free Solutions
journal, January 2001


A metal–organic framework replete with ordered donor–acceptor catenanes
journal, January 2010


The pervasive chemistry of metal–organic frameworks
journal, January 2009


Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009


Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833
  • https://doi.org/10.1021/jp1044139

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005


Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008

  • Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627
  • https://doi.org/10.1021/ja805222x

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010


Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011


Non-carboxylate based metal-organic frameworks (MOFs) and related aspects
journal, June 2009


Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005


A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010


The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008


Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010


Synthesis and Characterization of Zirconogermanates
journal, September 2003


Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003


Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005


Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004

  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667
  • https://doi.org/10.1021/ja049408c

Construction of Microporous Materials from Molecular Building Blocks
book, January 2002


Metal–organic frameworks: a new class of porous materials
journal, August 2004


Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005


Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
journal, August 2005


Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910
  • https://doi.org/10.1021/ja0542690

Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal−Organic Frameworks
journal, July 2007


Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction
journal, January 2006


NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5
journal, March 2006


High-Throughput Synthesis of Phosphonate-Based Inorganic–Organic Hybrid Compounds under Hydrothermal Conditions
journal, January 2004


Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997

  • Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
  • Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651
  • https://doi.org/10.1021/ja9715760

Polycatenation, polythreading and polyknotting in coordination network chemistry
journal, November 2003


Tertiary Building Units:  Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1)
October 2001


Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate)
journal, November 2000


Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007


Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures
journal, August 2001


20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001


Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000


Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework
journal, June 1999


Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999


An Open-Framework Germanate with Polycubane-Like Topology
journal, March 1999


Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998


Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86
journal, August 1998


Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998


Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate)
journal, March 1998


Rotaxanes as ligands: from molecules to materials
journal, January 2007


Frameworks for Extended Solids: Geometrical Design Principles
journal, June 2000


A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
journal, December 2001


Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1
journal, May 2000


A Microporous Lanthanide-Organic Framework
journal, September 1999


From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999


Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks
journal, January 2002


Metal–organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units
journal, November 2001


Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks
journal, March 2006


Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids
journal, August 1998


A Molecular Railroad with Large Pores:  Synthesis and Structure of Ni(4,4‘-bpy)2.5(H2O)2(ClO4)2·1.5(4,4‘-bpy)·2H2O
journal, September 1997


Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion
journal, May 1997


Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
journal, March 1997


Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
journal, January 1996


T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3
journal, January 1996


Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels
journal, October 1995


Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4
journal, July 1995


Mutually Interpenetrating Sheets and Channels in the Extended Structure of [Cu(4,4′-bpy)Cl]
journal, February 1995


Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks
journal, January 1995


Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
journal, February 2001


Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999


Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006


Combinatorial Approach to the Hydrothermal Synthesis of Zeolites
journal, March 1998


High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
journal, March 2009


Azulene based metal–organic frameworks for strong adsorption of H2
journal, January 2010


Tailored Porous Materials
journal, October 1999


Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010


1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal–organic frameworks
journal, November 2001


Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009


Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
  • https://doi.org/10.1021/ja8036096

Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework
journal, August 2005


High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005


A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
journal, February 2006


A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
journal, January 2006


Combinatorial Methods for the Synthesis of Aluminophosphate Molecular Sieves
journal, October 1999


Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework
journal, August 2011


A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002


Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005


Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

  • Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915
  • https://doi.org/10.1021/ja0751781

Industrial applications of metal–organic frameworks
journal, January 2009


Three-periodic nets and tilings: regular and quasiregular nets
journal, December 2002


Three-periodic nets and tilings: semiregular nets
journal, October 2003


Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
journal, March 2005


What do we know about three-periodic nets?
journal, August 2005


Three-periodic nets and tilings: edge-transitive binodal structures
journal, August 2006


Taxonomy of periodic nets and the design of materials
journal, January 2007


Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010


Robust dynamics
journal, May 2010


Isoreticular Metalation of Metal−Organic Frameworks
journal, July 2009

  • Doonan, Christian J.; Morris, William; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 27, p. 9492-9493
  • https://doi.org/10.1021/ja903251e

Exceptional ammonia uptake by a covalent organic framework
journal, February 2010


Design of New Materials for Methane Storage
journal, March 2004


Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000


Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001


Positronium formation in porous materials for antihydrogen production
journal, April 2010


Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal–organic frameworks
journal, January 2007


Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra
journal, September 2008


Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009


Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010


MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011


A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005


Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008


Zeolite A imidazolate frameworks
journal, May 2007


Selective binding and removal of guests in a microporous metal–organic framework
journal, December 1995


A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004


Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002