Gas sensor incorporating a porous framework

Yaghi, Omar M; Czaja, Alexander U; Wang, Bo; Galatsis, Kosmas; Wang, Kang L; Furukawa, Hiroyasu

Title: Gas sensor incorporating a porous framework

Abstract

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Inventors:: Yaghi, Omar M; Czaja, Alexander U; Wang, Bo; Galatsis, Kosmas; Wang, Kang L; Furukawa, Hiroyasu

Issue Date:: 2014-05-27

Research Org.:: Univ. of California, Oakland, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1132801

Patent Number(s):: 8735161

Application Number:: 13/936,315

Assignee:: The Regents of the University of California (Oakland, CA); BASF SE (Ludwigshafen, DE)

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES

Show more

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/25875 - Gaseous sample or with change of physical state

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N33/004 - {for CO, CO2}
G01N27/125 - {Composition of the body, e.g. the composition of its sensitive layer}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/204998 - Inorganic carbon compounds

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/226 - {Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/11 - Automated chemical analysis

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N33/50 - Chemical analysis of biological material, e.g. blood, urine

Show less

DOE Contract Number:: FG02-08ER15935

Resource Type:: Patent

Resource Relation:: Patent File Date: 2013 Jul 08

Country of Publication:: United States

Language:: English

Subject:: 47 OTHER INSTRUMENTATION

Citation Formats


                    Yaghi, Omar M, Czaja, Alexander U, Wang, Bo, Galatsis, Kosmas, Wang, Kang L, and Furukawa, Hiroyasu. Gas sensor incorporating a porous framework.  United States: N. p., 2014. 
        Web.

Copy to clipboard


                    Yaghi, Omar M, Czaja, Alexander U, Wang, Bo, Galatsis, Kosmas, Wang, Kang L, & Furukawa, Hiroyasu. Gas sensor incorporating a porous framework.  United States.

Copy to clipboard


                    Yaghi, Omar M, Czaja, Alexander U, Wang, Bo, Galatsis, Kosmas, Wang, Kang L, and Furukawa, Hiroyasu. Tue .  
        "Gas sensor incorporating a porous framework".  United States.  https://www.osti.gov/servlets/purl/1132801.

Copy to clipboard


                    
@article{osti_1132801,

  title        = {Gas sensor incorporating a porous framework},

  author       = {Yaghi, Omar M and Czaja, Alexander U and Wang, Bo and Galatsis, Kosmas and Wang, Kang L and Furukawa, Hiroyasu},

  abstractNote = {The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {5}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Design, Synthesis, Structure, and Gas (N₂, Ar, CO₂, CH₄, and H₂) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118
https://doi.org/10.1021/ja042802q

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008

Britt, D.; Tranchemontagne, D.; Yaghi, O. M.
Proceedings of the National Academy of Sciences, Vol. 105, Issue 33, p. 11623-11627
https://doi.org/10.1073/pnas.0804900105

Reticular Chemistry of Metal–Organic Polyhedra
journal, June 2008

Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael
Angewandte Chemie International Edition, Vol. 47, Issue 28, p. 5136-5147
https://doi.org/10.1002/anie.200705008

Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0
journal, September 2008

Tranchemontagne, David J.; Hunt, Joseph R.; Yaghi, Omar M.
Tetrahedron, Vol. 64, Issue 36, p. 8553-8557
https://doi.org/10.1016/j.tet.2008.06.036

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009

Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
https://doi.org/10.1039/b817735j

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009

Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571
https://doi.org/10.1021/ja8096256

Crystalline Covalent Organic Frameworks with Hydrazone Linkages
journal, August 2011

Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481
https://doi.org/10.1021/ja204728y

Synthesis of Metal−Organic Complex Arrays
journal, February 2011

Vairaprakash, Pothiappan; Ueki, Hisanori; Tashiro, Kentaro
Journal of the American Chemical Society, Vol. 133, Issue 4, p. 759-761
https://doi.org/10.1021/ja1097644

Metal–organic frameworks with designed chiral recognition sites
journal, January 2010

Valente, Cory; Choi, Eunwoo; Belowich, Matthew E.
Chemical Communications, Vol. 46, Issue 27, p. 4911-4913
https://doi.org/10.1039/c0cc00997k

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks
journal, January 2008

Walton, Krista S.; Millward, Andrew R.; Dubbeldam, David
Journal of the American Chemical Society, Vol. 130, Issue 2, p. 406-407
https://doi.org/10.1021/ja076595g

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007

Wang, Zhenqiang; Cohen, Seth M.
Journal of the American Chemical Society, Vol. 129, Issue 41, p. 12368-12369
https://doi.org/10.1021/ja074366o

Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

Wang, Zhenqiang; Cohen, Seth M.
Angewandte Chemie International Edition, Vol. 47, Issue 25, p. 4699-4702
https://doi.org/10.1002/anie.200800686

Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008

Wang, Bo; Côté, Adrien P.; Furukawa, Hiroyasu
Nature, Vol. 453, Issue 7192, p. 207-211
https://doi.org/10.1038/nature06900

Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry
journal, June 2000

Yaghi, O. M.; O'Keeffe, M.; Kanatzidis, M.
Journal of Solid State Chemistry, Vol. 152, Issue 1, p. 1-2
https://doi.org/10.1006/jssc.2000.8733

Reticular synthesis and the design of new materials
journal, June 2003

Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
Nature, Vol. 423, Issue 6941, p. 705-714
https://doi.org/10.1038/nature01650

Metal–organic Frameworks: A tale of two entanglements
journal, February 2007

Yaghi, Omar M.
Nature Materials, Vol. 6, Issue 2, p. 92-93
https://doi.org/10.1038/nmat1824

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy
journal, September 2009

Yaghi, Omar M.; Li, Qiaowei
MRS Bulletin, Vol. 34, Issue 9, p. 682-690
https://doi.org/10.1557/mrs2009.180

A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers
journal, July 2005

Fei, Zhaofu; Geldbach, Tilmann J.; Zhao, Dongbin
Inorganic Chemistry, Vol. 44, Issue 15, p. 5200-5202
https://doi.org/10.1021/ic0504238

Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
journal, February 2007

Huang, B. L.; Ni, Z.; Millward, A.
International Journal of Heat and Mass Transfer, Vol. 50, Issue 3-4, p. 405-411
https://doi.org/10.1016/j.ijheatmasstransfer.2006.10.001

Metal-organic frameworks—New materials for hydrogen storage
journal, April 2007

Isaeva, V. I.; Kustov, L. M.
Russian Journal of General Chemistry, Vol. 77, Issue 4, p. 721-739
https://doi.org/10.1134/S1070363207040342

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007

El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
Science, Vol. 316, Issue 5822, p. 268-272
https://doi.org/10.1126/science.1139915

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5)
journal, November 2007

Kaye, Steven S.; Dailly, Anne; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 129, Issue 46, p. 14176-14177
https://doi.org/10.1021/ja076877g

Combinatorial Material Libraries on the Microgram Scale with an Example of Hydrothermal Synthesis
journal, December 1998

Klein, Jens; Lehmann, Christian W.; Schmidt, Hans-Werner
Angewandte Chemie International Edition, Vol. 37, Issue 24, p. 3369-3372
https://doi.org/10.1002/(SICI)1521-3773(19981231)37:24<3369::AID-ANIE3369>3.0.CO;2-H

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J.
Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680
https://doi.org/10.1002/anie.200705020

Parallel Synthesis of ZSM-5 Zeolite Films from Clear Organic-Free Solutions
journal, January 2001

Lai, Re; Kang, Beom Seok; Gavalas, George R.
Angewandte Chemie International Edition, Vol. 40, Issue 2
https://doi.org/10.1002/1521-3773(20010119)40:2<408::AID-ANIE408>3.0.CO;2-V

A metal–organic framework replete with ordered donor–acceptor catenanes
journal, January 2010

Li, Qiaowei; Zhang, Wenyu; Miljanić, Ognjen Š.
Chemical Communications, Vol. 46, Issue 3, p. 380-382
https://doi.org/10.1039/B919923C

The pervasive chemistry of metal–organic frameworks
journal, January 2009

Long, Jeffrey R.; Yaghi, Omar M.
Chemical Society Reviews, Vol. 38, Issue 5, p. 1213-1214
https://doi.org/10.1039/b903811f

Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009

Lu, Zheng; Knobler, Carolyn B.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 131, Issue 35, p. 12532-12533
https://doi.org/10.1021/ja905101s

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833
https://doi.org/10.1021/jp1044139

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005

Millward, Andrew R.; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999
https://doi.org/10.1021/ja0570032

Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008

Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627
https://doi.org/10.1021/ja805222x

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010

Morris, William; Leung, Belinda; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 132, Issue 32, p. 11006-11008
https://doi.org/10.1021/ja104035j

Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011

Morris, William; Doonan, Christian J.; Yaghi, Omar M.
Inorganic Chemistry, Vol. 50, Issue 15, p. 6853-6855
https://doi.org/10.1021/ic200744y

Non-carboxylate based metal-organic frameworks (MOFs) and related aspects
journal, June 2009

Natarajan, Srinivasan; Mahata, Partha
Current Opinion in Solid State and Materials Science, Vol. 13, Issue 3-4, p. 46-53
https://doi.org/10.1016/j.cossms.2009.05.002

Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005

Ni, Zheng; Yassar, Abderrahim; Antoun, Tarek
Journal of the American Chemical Society, Vol. 127, Issue 37, p. 12752-12753
https://doi.org/10.1021/ja052055c

A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010

Oisaki, Kounosuke; Li, Qiaowei; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 132, Issue 27, p. 9262-9264
https://doi.org/10.1021/ja103016y

The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008

O’Keeffe, Michael; Peskov, Maxim A.; Ramsden, Stuart J.
Accounts of Chemical Research, Vol. 41, Issue 12, p. 1782-1789
https://doi.org/10.1021/ar800124u

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010

Phan, Anh; Doonan, Christian J.; Uribe-Romo, Fernando J.
Accounts of Chemical Research, Vol. 43, Issue 1, p. 58-67
https://doi.org/10.1021/ar900116g

Synthesis and Characterization of Zirconogermanates
journal, September 2003

Plévert, Jacques; Sanchez-Smith, Rebeca; Gentz, Travis M.
Inorganic Chemistry, Vol. 42, Issue 19, p. 5954-5959
https://doi.org/10.1021/ic034298g

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed
Science, Vol. 300, Issue 5622, p. 1127-1129
https://doi.org/10.1126/science.1083440

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005

Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed
Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518
https://doi.org/10.1021/ja045123o

Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004

Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667
https://doi.org/10.1021/ja049408c

Construction of Microporous Materials from Molecular Building Blocks
book, January 2002

Yaghi, Omar M.; Pinnavaia, Thomas J.; Thorpe, M. F.
Access in Nanoporous Materials, p. 111-121
https://doi.org/10.1007/0-306-47066-7_8

Metal–organic frameworks: a new class of porous materials
journal, August 2004

Rowsell, Jesse L. C.; Yaghi, Omar M.
Microporous and Mesoporous Materials, Vol. 73, Issue 1-2, p. 3-14
https://doi.org/10.1016/j.micromeso.2004.03.034

Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005

Rowsell, Jesse L. C.; Yaghi, Omar M.
Angewandte Chemie International Edition, Vol. 44, Issue 30, p. 4670-4679
https://doi.org/10.1002/anie.200462786

Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
journal, August 2005

Rowsell, Jesse L. C.; Spencer, Elinor C.; Eckert, Juergen
Science, Vol. 309, Issue 5739, p. 1350-1354
https://doi.org/10.1126/science.1113247

Characterization of H₂ Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910
https://doi.org/10.1021/ja0542690

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

Rowsell, Jesse L. C.; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 128, Issue 4, p. 1304-1315
https://doi.org/10.1021/ja056639q

Raman Spectroscopic Investigation of CH₄ and N₂ Adsorption in Metal−Organic Frameworks
journal, July 2007

Siberio-Pérez, Diana Y.; Wong-Foy, Antek G.; Yaghi, Omar M.
Chemistry of Materials, Vol. 19, Issue 15, p. 3681-3685
https://doi.org/10.1021/cm070542g

Determination of the hydrogen absorption sites in Zn₄O(1,4-benzenedicarboxylate) by single crystal neutron diffraction
journal, January 2006

Spencer, Elinor C.; Howard, Judith A. K.; McIntyre, Garry J.
Chemical Communications, Vol. 0, Issue 3, p. 278-280
https://doi.org/10.1039/B511941C

NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5
journal, March 2006

Stallmach, Frank; Gröger, Stefan; Künzel, Volker
Angewandte Chemie International Edition, Vol. 45, Issue 13, p. 2123-2126
https://doi.org/10.1002/anie.200502553

High-Throughput Synthesis of Phosphonate-Based Inorganic–Organic Hybrid Compounds under Hydrothermal Conditions
journal, January 2004

Stock, Norbert; Bein, Thomas
Angewandte Chemie International Edition, Vol. 43, Issue 6, p. 749-752
https://doi.org/10.1002/anie.200351718

Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997

Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651
https://doi.org/10.1021/ja9715760

Polycatenation, polythreading and polyknotting in coordination network chemistry
journal, November 2003

Carlucci, Lucia; Ciani, Gianfranco; Proserpio, Davide M.
Coordination Chemistry Reviews, Vol. 246, Issue 1-2, p. 247-289
https://doi.org/10.1016/S0010-8545(03)00126-7

Tertiary Building Units: Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1)
October 2001

Chae, Hee K.; Eddaoudi, Mohamed; Kim, Jaheon
Journal of the American Chemical Society, Vol. 123, Issue 46, p. 11482-11483
https://doi.org/10.1021/ja011692+

Cu₂(ATC)·6H₂O: Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC: 1,3,5,7-Adamantane Tetracarboxylate)
journal, November 2000

Chen, Banglin; Eddaoudi, M.; Reineke, T. M.
Journal of the American Chemical Society, Vol. 122, Issue 46, p. 11559-11560
https://doi.org/10.1021/ja003159k

Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007

Han, Sang Soo; Deng, Wei-Qiao; Goddard, William A.
Angewandte Chemie International Edition, Vol. 46, Issue 33, p. 6289-6292
https://doi.org/10.1002/anie.200700303

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures
journal, August 2001

Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.
Journal of the American Chemical Society, Vol. 123, Issue 34, p. 8239-8247
https://doi.org/10.1021/ja010825o

20 Å Cd₄In₁₆S₃₅^14- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001

Li, Hailian; Kim, Jaheon; Groy, T. L.
Journal of the American Chemical Society, Vol. 123, Issue 20, p. 4867-4868
https://doi.org/10.1021/ja010413f

Ge₂ZrO₆F₂·(H₂DAB)H₂O:¹ A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000

Li, Hailian; Eddaoudi, Mohamed; Plévert, Jacques
Journal of the American Chemical Society, Vol. 122, Issue 49, p. 12409-12410
https://doi.org/10.1021/ja003228v

Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework
journal, June 1999

Li, Hailian; Eddaoudi, Mohamed; Laine, Aaron
Journal of the American Chemical Society, Vol. 121, Issue 25, p. 6096-6097
https://doi.org/10.1021/ja990410r

Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999

Li, Hailian; Laine, Aaron; O'Keefe, M.
Science, Vol. 283, Issue 5405, p. 1145-1147
https://doi.org/10.1126/science.283.5405.1145

An Open-Framework Germanate with Polycubane-Like Topology
journal, March 1999

Li, Hailian; Eddaoudi, Mohamed; Yaghi, Omar M.
Angewandte Chemie International Edition, Vol. 38, Issue 5, p. 653-655
https://doi.org/10.1002/(SICI)1521-3773(19990301)38:5<653::AID-ANIE653>3.0.CO;2-C

Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998

Li, Hailian; Yaghi, O. M.
Journal of the American Chemical Society, Vol. 120, Issue 40, p. 10569-10570
https://doi.org/10.1021/ja982384n

Porous Germanates: Synthesis, Structure, and Inclusion Properties of Ge₇O_14.5F₂·[(CH₃)₂NH₂]₃(H₂O)_0.86
journal, August 1998

Li, Hailian; Eddaoudi, M.; Richardson, D. A.
Journal of the American Chemical Society, Vol. 120, Issue 33, p. 8567-8568
https://doi.org/10.1021/ja9813919

Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998

Li, Hailian; Eddaoudi, Mohamed; Groy, Thomas L.
Journal of the American Chemical Society, Vol. 120, Issue 33, p. 8571-8572
https://doi.org/10.1021/ja981669x

Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn₃(BDC)₃·6CH₃OH (BDC = 1,4-Benzenedicarboxylate)
journal, March 1998

Li, Hailian; Davis, Charles E.; Groy, Thomas L.
Journal of the American Chemical Society, Vol. 120, Issue 9, p. 2186-2187
https://doi.org/10.1021/ja974172g

Rotaxanes as ligands: from molecules to materials
journal, January 2007

Loeb, Stephen J.
Chemical Society Reviews, Vol. 36, Issue 2, p. 226-235
https://doi.org/10.1039/B605172N

Frameworks for Extended Solids: Geometrical Design Principles
journal, June 2000

O'Keeffe, M.; Eddaoudi, M.; Li, Hailian
Journal of Solid State Chemistry, Vol. 152, Issue 1, p. 3-20
https://doi.org/10.1006/jssc.2000.8723

Germanate Zeolites: Contrasting the Behavior of Germanate and Silicate Structures Built from Cubic T₈O₂₀ Units (T=Ge or Si)
journal, October 1999

O'Keeffe, M.; Yaghi, O. M.
Chemistry - A European Journal, Vol. 5, Issue 10, p. 2796-2801
https://doi.org/10.1002/(SICI)1521-3765(19991001)5:10<2796::AID-CHEM2796>3.0.CO;2-6

A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
journal, December 2001

Plévert, Jacques; Gentz, Travis M.; Laine, Aaron
Journal of the American Chemical Society, Vol. 123, Issue 50, p. 12706-12707
https://doi.org/10.1021/ja016996a

Large Free Volume in Maximally Interpenetrating Networks: The Role of Secondary Building Units Exemplified by Tb₂(ADB)₃[(CH₃)₂SO]₄·16[(CH₃)₂SO]¹
journal, May 2000

Reineke, Theresa M.; Eddaoudi, Mohamed; Moler, David
Journal of the American Chemical Society, Vol. 122, Issue 19, p. 4843-4844
https://doi.org/10.1021/ja000363z

A Microporous Lanthanide-Organic Framework
journal, September 1999

Reineke, Theresa M.; Eddaoudi, Mohamed; O'Keeffe, M.
Angewandte Chemie International Edition, Vol. 38, Issue 17, p. 2590-2594
https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2590::AID-ANIE2590>3.0.CO;2-H

From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999

Reineke, Theresa M.; Eddaoudi, Mohamed; Fehr, Michael
Journal of the American Chemical Society, Vol. 121, Issue 8, p. 1651-1657
https://doi.org/10.1021/ja983577d

Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks
journal, January 2002

Rosi, Nathaniel L.; Eddaoudi, Mohamed; Kim, Jaheon
Angewandte Chemie, Vol. 114, Issue 2, p. 294-297
https://doi.org/10.1002/1521-3757(20020118)114:2<294::AID-ANGE294>3.0.CO;2-6

Advances in the chemistry of metal–organic frameworks
journal, January 2002

Rosi, Nathaniel L.; Eddaoudi, Mohamed; Kim, Jaheon
CrystEngComm, Vol. 4, Issue 68, p. 401-404
https://doi.org/10.1039/B203193K

Metal–organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units
journal, November 2001

Vodak, David T.; Braun, Matthew E.; Kim, Jaheon
Chemical Communications, Vol. 0, Issue 24, p. 2534-2535
https://doi.org/10.1039/b108684g

Exceptional H₂ Saturation Uptake in Microporous Metal−Organic Frameworks
journal, March 2006

Wong-Foy, Antek G.; Matzger, Adam J.; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 128, Issue 11, p. 3494-3495
https://doi.org/10.1021/ja058213h

Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids^†
journal, August 1998

Yaghi, Omar M.; Li, Hailian; Davis, Charles
Accounts of Chemical Research, Vol. 31, Issue 8, p. 474-484
https://doi.org/10.1021/ar970151f

Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
journal, January 1997

Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian
Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384
https://doi.org/10.1039/a702287e

A Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4‘-bpy)_2.5(H₂O)₂(ClO₄)₂·1.5(4,4‘-bpy)·2H₂O
journal, September 1997

Yaghi, O. M.; Li, Hailian; Groy, Thomas L.
Inorganic Chemistry, Vol. 36, Issue 20, p. 4292-4293
https://doi.org/10.1021/ic970423a

Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion
journal, May 1997

Yaghi, O. M.; Li, Guangming; Li, Hailian
Chemistry of Materials, Vol. 9, Issue 5, p. 1074-1076
https://doi.org/10.1021/cm970069e

Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
journal, March 1997

Yaghi, O. M.; Davis, Charles E.; Li, Guangming
Journal of the American Chemical Society, Vol. 119, Issue 12, p. 2861-2868
https://doi.org/10.1021/ja9639473

Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
journal, January 1996

Yaghi, O. M.; Li, Hailian; Groy, T. L.
Journal of the American Chemical Society, Vol. 118, Issue 38, p. 9096-9101
https://doi.org/10.1021/ja960746q

T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO₃
journal, January 1996

Yaghi, O. M.; Li, Hailian
Journal of the American Chemical Society, Vol. 118, Issue 1, p. 295-296
https://doi.org/10.1021/ja953438l

Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels
journal, October 1995

Yaghi, O. M.; Li, Hailian
Journal of the American Chemical Society, Vol. 117, Issue 41, p. 10401-10402
https://doi.org/10.1021/ja00146a033

Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of Cu^II(1,4-C₄H₄N₂)(C₄O₄)(OH₂)₄
journal, July 1995

Yaghi, O. M.; Li, Guangming; Groy, T. L.
Journal of Solid State Chemistry, Vol. 117, Issue 2, p. 256-260
https://doi.org/10.1006/jssc.1995.1271

Mutually Interpenetrating Sheets and Channels in the Extended Structure of [Cu(4,4′-bpy)Cl]
journal, February 1995

Yaghi, O. M.; Li, Guangming
Angewandte Chemie International Edition in English, Vol. 34, Issue 2, p. 207-209
https://doi.org/10.1002/anie.199502071

Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C₄O₄^2–) molecules, chains and sheets to three-dimensional cage networks
journal, January 1995

Yaghi, Omar M.; Li, Guangming; Groy, Thomas L.
Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 5, p. 727-732
https://doi.org/10.1039/DT9950000727

Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores
journal, February 2001

Chen, Banglin; Eddaoudi, M.; Hyde, S. T.
Science, Vol. 291, Issue 5506, p. 1021-1023
https://doi.org/10.1126/science.1056598

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
Nature, Vol. 402, Issue 6759, p. 276-279
https://doi.org/10.1038/46248

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

Park, K. S.; Ni, Z.; Cote, A. P.
Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
https://doi.org/10.1073/pnas.0602439103

Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks
journal, January 1994

Yaghi, Omar M.; Richardson, D. A.; Li, G.
MRS Proceedings, Vol. 371
https://doi.org/10.1557/PROC-371-15

Combinatorial Approach to the Hydrothermal Synthesis of Zeolites
journal, March 1998

Akporiaye, Duncan E.; Dahl, Ivar M.; Karlsson, Arne
Angewandte Chemie International Edition, Vol. 37, Issue 5, p. 609-611
https://doi.org/10.1002/(SICI)1521-3773(19980316)37:5<609::AID-ANIE609>3.0.CO;2-X

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO₂ Capture
journal, February 2008

Banerjee, Rahul; Phan, Anh; Wang, Bo
Science, Vol. 319, Issue 5865, p. 939-943
https://doi.org/10.1126/science.1152516

Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
journal, March 2009

Banerjee, Rahul; Furukawa, Hiroyasu; Britt, David
Journal of the American Chemical Society, Vol. 131, Issue 11, p. 3875-3877
https://doi.org/10.1021/ja809459e

Azulene based metal–organic frameworks for strong adsorption of H₂
journal, January 2010

Barman, Samir; Furukawa, Hiroyasu; Blacque, Olivier
Chemical Communications, Vol. 46, Issue 42, p. 7981-7983
https://doi.org/10.1039/c0cc02589e

Tailored Porous Materials
journal, October 1999

Barton, Thomas J.; Bull, Lucy M.; Klemperer, Walter G.
Chemistry of Materials, Vol. 11, Issue 10, p. 2633-2656
https://doi.org/10.1021/cm9805929

Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010

Bloch, Eric D.; Britt, David; Lee, Chain
Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384
https://doi.org/10.1021/ja106935d

1,4-Benzenedicarboxylate derivatives as links in the design of paddle-wheel units and metal–organic frameworks
journal, November 2001

Braun, Matthew E.; Steffek, Cory D.; Kim, Jaheon
Chemical Communications, Vol. 0, Issue 24, p. 2532-2533
https://doi.org/10.1039/b108031h

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
journal, November 2009

Britt, D.; Furukawa, H.; Wang, B.
Proceedings of the National Academy of Sciences, Vol. 106, Issue 49, p. 20637-20640
https://doi.org/10.1073/pnas.0909718106

Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008

Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
https://doi.org/10.1021/ja8036096

Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework
journal, August 2005

Centrone, Andrea; Siberio-Pérez, Diana Y.; Millward, Andrew R.
Chemical Physics Letters, Vol. 411, Issue 4-6, p. 516-519
https://doi.org/10.1016/j.cplett.2005.06.069

High H₂ Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005

Chen, Banglin; Ockwig, Nathan W.; Millward, Andrew R.
Angewandte Chemie International Edition, Vol. 44, Issue 30, p. 4745-4749
https://doi.org/10.1002/anie.200462787

A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
journal, February 2006

Chen, Banglin; Liang, Chengdu; Yang, Jun
Angewandte Chemie International Edition, Vol. 45, Issue 9, p. 1390-1393
https://doi.org/10.1002/anie.200502844

A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
journal, January 2006

Cho, So-Hye; Ma, Baoqing; Nguyen, SonBinh T.
Chem. Commun., Vol. 0, Issue 24, p. 2563-2565
https://doi.org/10.1039/B600408C

Combinatorial Methods for the Synthesis of Aluminophosphate Molecular Sieves
journal, October 1999

Choi, Kwangwook; Gardner, David; Hilbrandt, Nicole
Angewandte Chemie International Edition, Vol. 38, Issue 19, p. 2891-2894
https://doi.org/10.1002/(SICI)1521-3773(19991004)38:19<2891::AID-ANIE2891>3.0.CO;2-X

Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework
journal, August 2011

Choi, Kyung Min; Jeon, Hyung Joon; Kang, Jeung Ku
Journal of the American Chemical Society, Vol. 133, Issue 31, p. 11920-11923
https://doi.org/10.1021/ja204818q

A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst
journal, August 2002

Corma, Avelino; Díaz-Cabañas, María J.; Martínez-Triguero, Joaquín
Nature, Vol. 418, Issue 6897, p. 514-517
https://doi.org/10.1038/nature00924

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005

Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
Science, Vol. 310, Issue 5751, p. 1166-1170
https://doi.org/10.1126/science.1120411

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915
https://doi.org/10.1021/ja0751781

Industrial applications of metal–organic frameworks
journal, January 2009

Czaja, Alexander U.; Trukhan, Natalia; Müller, Ulrich
Chemical Society Reviews, Vol. 38, Issue 5, p. 1284-1293
https://doi.org/10.1039/b804680h

Three-periodic nets and tilings: regular and quasiregular nets
journal, December 2002

Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 1, p. 22-27
https://doi.org/10.1107/S0108767302018494

Three-periodic nets and tilings: semiregular nets
journal, October 2003

Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 6, p. 515-525
https://doi.org/10.1107/S0108767303017100

Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
journal, March 2005

Ockwig, Nathan W.; Delgado-Friedrichs, Olaf; O'Keeffe, Michael
Accounts of Chemical Research, Vol. 38, Issue 3, p. 176-182
https://doi.org/10.1021/ar020022l

What do we know about three-periodic nets?
journal, August 2005

Delgado-Friedrichs, Olaf; Foster, Martin D.; O’Keeffe, Michael
Journal of Solid State Chemistry, Vol. 178, Issue 8, p. 2533-2554
https://doi.org/10.1016/j.jssc.2005.06.037

Three-periodic nets and tilings: edge-transitive binodal structures
journal, August 2006

Delgado-Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 5, p. 350-355
https://doi.org/10.1107/S0108767306022707

Taxonomy of periodic nets and the design of materials
journal, January 2007

Delgado-Friedrichs, Olaf; O’Keeffe, Michael; Yaghi, Omar M.
Phys. Chem. Chem. Phys., Vol. 9, Issue 9, p. 1035-1043
https://doi.org/10.1039/B615006C

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010

Deng, H.; Doonan, C. J.; Furukawa, H.
Science, Vol. 327, Issue 5967, p. 846-850
https://doi.org/10.1126/science.1181761

Robust dynamics
journal, May 2010

Deng, Hexiang; Olson, Mark A.; Stoddart, J. Fraser
Nature Chemistry, Vol. 2, Issue 6, p. 439-443
https://doi.org/10.1038/nchem.654

Isoreticular Metalation of Metal−Organic Frameworks
journal, July 2009

Doonan, Christian J.; Morris, William; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 131, Issue 27, p. 9492-9493
https://doi.org/10.1021/ja903251e

Exceptional ammonia uptake by a covalent organic framework
journal, February 2010

Doonan, Christian J.; Tranchemontagne, David J.; Glover, T. Grant
Nature Chemistry, Vol. 2, Issue 3, p. 235-238
https://doi.org/10.1038/nchem.548

Design of New Materials for Methane Storage
journal, March 2004

Düren, Tina; Sarkisov, Lev; Yaghi, Omar M.
Langmuir, Vol. 20, Issue 7, p. 2683-2689
https://doi.org/10.1021/la0355500

Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
journal, February 2000

Eddaoudi, Mohamed; Li, Hailian; Yaghi, O. M.
Journal of the American Chemical Society, Vol. 122, Issue 7, p. 1391-1397
https://doi.org/10.1021/ja9933386

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001

Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
https://doi.org/10.1021/ar000034b

Positronium formation in porous materials for antihydrogen production
journal, April 2010

Ferragut, R.; Calloni, A.; Dupasquier, A.
Journal of Physics: Conference Series, Vol. 225, Issue 1, Article No. 012007
https://doi.org/10.1088/1742-6596/225/1/012007

Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal–organic frameworks
journal, January 2007

Furukawa, Hiroyasu; Miller, Michael A.; Yaghi, Omar M.
Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3197-3204
https://doi.org/10.1039/b703608f

Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra
journal, September 2008

Furukawa, Hiroyasu; Kim, Jaheon; Ockwig, Nathan W.
Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11650-11661
https://doi.org/10.1021/ja803783c

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
journal, July 2009

Furukawa, Hiroyasu; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8875-8883
https://doi.org/10.1021/ja9015765

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

Furukawa, H.; Ko, N.; Go, Y. B.
Science, Vol. 329, Issue 5990, p. 424-428
https://doi.org/10.1126/science.1192160

MOF-74 building unit has a direct impact on toxic gas adsorption
journal, January 2011

Grant Glover, T.; Peterson, Gregory W.; Schindler, Bryan J.
Chemical Engineering Science, Vol. 66, Issue 2, p. 163-170
https://doi.org/10.1016/j.ces.2010.10.002

A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials
journal, November 2005

Forster, Paul M.; Stock, Norbert; Cheetham, Anthony K.
Angewandte Chemie International Edition, Vol. 44, Issue 46, p. 7608-7611
https://doi.org/10.1002/anie.200501766

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008

Han, Sang Soo; Furukawa, Hiroyasu; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11580-11581
https://doi.org/10.1021/ja803247y

Zeolite A imidazolate frameworks
journal, May 2007

Hayashi, Hideki; Côté, Adrien P.; Furukawa, Hiroyasu
Nature Materials, Vol. 6, Issue 7, p. 501-506
https://doi.org/10.1038/nmat1927

Selective binding and removal of guests in a microporous metal–organic framework
journal, December 1995

Yaghi, O. M.; Li, Guangming; Li, Hailian
Nature, Vol. 378, Issue 6558, p. 703-706
https://doi.org/10.1038/378703a0

A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004

Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
Nature, Vol. 427, Issue 6974, p. 523-527
https://doi.org/10.1038/nature02311

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
Science, Vol. 295, Issue 5554, p. 469-472
https://doi.org/10.1126/science.1067208

Similar Records in DOE Patents and OSTI.GOV collections:

Gas sensor incorporating a porous framework

Patent Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; ...

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.
Full Text Available
Optical sensing elements for nitrogen dioxide (NO.sub.2) gas detection, a sol-gel method for making the sensing elements and fiber optic sensors incorporating nitrogen dioxide gas optical sensing elements

Patent Mechery, Shelly John [Mississippi State, MS]; Singh, Jagdish P [Starkville, MS]

A sensing element, a method of making a sensing element, and a fiber optic sensor incorporating the sensing element are described. The sensor can be used for the quantitative detection of NO.sub.2 in a mixture of gases. The sensing element can be made by incorporating a diazotizing reagent which reacts with nitrous ions to produce a diazo compound and a coupling reagent which couples with the diazo compound to produce an azo dye into a sol and allowing the sol to form an optically transparent gel. The sensing element changes color in the presence of NO.sub.2 gas. The temporal responsemore » « less
Full Text Available
Emissive sensors and devices incorporating these sensors

Patent Swager, Timothy M; Zhang, Shi-Wei

The present invention generally relates to luminescent and/or optically absorbing compositions and/or precursors to those compositions, including solid films incorporating these compositions/precursors, exhibiting increased luminescent lifetimes, quantum yields, enhanced stabilities and/or amplified emissions. The present invention also relates to sensors and methods for sensing analytes through luminescent and/or optically absorbing properties of these compositions and/or precursors. Examples of analytes detectable by the invention include electrophiles, alkylating agents, thionyl halides, and phosphate ester groups including phosphoryl halides, cyanides and thioates such as those found in certain chemical warfare agents. The present invention additionally relates to devices and methods for amplifying emissions,more » « less
Full Text Available
Non-contact current and voltage sensor having detachable housing incorporating multiple ferrite cylinder portions

Patent Carpenter, Gary D.; El-Essawy, Wael; Ferreira, Alexandre Peixoto; ...

A detachable current and voltage sensor provides an isolated and convenient device to measure current passing through a conductor such as an AC branch circuit wire, as well as providing an indication of an electrostatic potential on the wire, which can be used to indicate the phase of the voltage on the wire, and optionally a magnitude of the voltage. The device includes a housing formed from two portions that mechanically close around the wire and that contain the current and voltage sensors. The current sensor is a ferrite cylinder formed from at least three portions that form the cylindermore » « less
Full Text Available
Moisture sensor based on evanescent wave light scattering by porous sol-gel silica coating

Patent Tao, Shiquan; Singh, Jagdish P.; Winstead, Christopher B.

An optical fiber moisture sensor that can be used to sense moisture present in gas phase in a wide range of concentrations is provided, as well techniques for making the same. The present invention includes a method that utilizes the light scattering phenomenon which occurs in a porous sol-gel silica by coating an optical fiber core with such silica. Thus, a porous sol-gel silica polymer coated on an optical fiber core forms the transducer of an optical fiber moisture sensor according to an embodiment. The resulting optical fiber sensor of the present invention can be used in various applications, includingmore » « less
Full Text Available

Similar Records

Title: Gas sensor incorporating a porous framework

Abstract

Citation Formats

Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra journal, May 2005

Metal-organic frameworks with high capacity and selectivity for harmful gases journal, August 2008

Reticular Chemistry of Metal–Organic Polyhedra journal, June 2008

Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 journal, September 2008

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks journal, January 2009

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework journal, April 2009

Crystalline Covalent Organic Frameworks with Hydrazone Linkages journal, August 2011

Synthesis of Metal−Organic Complex Arrays journal, February 2011

Metal–organic frameworks with designed chiral recognition sites journal, January 2010

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks journal, January 2008

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework journal, October 2007

Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal, June 2008

Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs journal, May 2008

Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry journal, June 2000

Reticular synthesis and the design of new materials journal, June 2003

Metal–organic Frameworks: A tale of two entanglements journal, February 2007

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy journal, September 2009

A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers journal, July 2005

Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement journal, February 2007

Metal-organic frameworks—New materials for hydrogen storage journal, April 2007

Designed Synthesis of 3D Covalent Organic Frameworks journal, April 2007

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) journal, November 2007

Combinatorial Material Libraries on the Microgram Scale with an Example of Hydrothermal Synthesis journal, December 1998

A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal, January 2008

Parallel Synthesis of ZSM-5 Zeolite Films from Clear Organic-Free Solutions journal, January 2001

A metal–organic framework replete with ordered donor–acceptor catenanes journal, January 2010

The pervasive chemistry of metal–organic frameworks journal, January 2009

Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra journal, September 2009

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment journal, October 2010

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal, December 2005

Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks journal, September 2008

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks journal, August 2010

Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake journal, August 2011

Non-carboxylate based metal-organic frameworks (MOFs) and related aspects journal, June 2009

Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links journal, September 2005

A Metal−Organic Framework with Covalently Bound Organometallic Complexes journal, July 2010

The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets journal, December 2008

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks journal, January 2010

Synthesis and Characterization of Zirconogermanates journal, September 2003

Hydrogen Storage in Microporous Metal-Organic Frameworks journal, May 2003

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units journal, February 2005

Hydrogen Sorption in Functionalized Metal−Organic Frameworks journal, May 2004

Construction of Microporous Materials from Molecular Building Blocks book, January 2002

Metal–organic frameworks: a new class of porous materials journal, August 2004

Strategies for Hydrogen Storage in Metal-Organic Frameworks journal, July 2005

Gas Adsorption Sites in a Large-Pore Metal-Organic Framework journal, August 2005

Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering journal, October 2005

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks journal, February 2006

Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal−Organic Frameworks journal, July 2007

Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction journal, January 2006

NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5 journal, March 2006

High-Throughput Synthesis of Phosphonate-Based Inorganic–Organic Hybrid Compounds under Hydrothermal Conditions journal, January 2004

Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching journal, November 1997

Polycatenation, polythreading and polyknotting in coordination network chemistry journal, November 2003

Tertiary Building Units: Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1) October 2001

Cu2(ATC)·6H2O: Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC: 1,3,5,7-Adamantane Tetracarboxylate) journal, November 2000

Improved Designs of Metal-Organic Frameworks for Hydrogen Storage journal, July 2007

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures journal, August 2001

20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks journal, May 2001

Ge2ZrO6F2·(H2DAB)H2O:1 A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings journal, December 2000

Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework journal, June 1999

Supertetrahedral Sulfide Crystals with Giant Cavities and Channels journal, February 1999

An Open-Framework Germanate with Polycubane-Like Topology journal, March 1999

Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets journal, October 1998

Porous Germanates: Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86 journal, August 1998

Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) journal, August 1998

Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate) journal, March 1998

Rotaxanes as ligands: from molecules to materials journal, January 2007

Frameworks for Extended Solids: Geometrical Design Principles journal, June 2000

Germanate Zeolites: Contrasting the Behavior of Germanate and Silicate Structures Built from Cubic T8O20 Units (T=Ge or Si) journal, October 1999

A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density journal, December 2001

Large Free Volume in Maximally Interpenetrating Networks: The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1 journal, May 2000

A Microporous Lanthanide-Organic Framework journal, September 1999

From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites journal, March 1999

Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks journal, January 2002

Advances in the chemistry of metal–organic frameworks journal, January 2002

Metal–organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units journal, November 2001

Design, Synthesis, Structure, and Gas (N₂, Ar, CO₂, CH₄, and H₂) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
journal, May 2005

Metal-organic frameworks with high capacity and selectivity for harmful gases
journal, August 2008

Reticular Chemistry of Metal–Organic Polyhedra
journal, June 2008

Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0
journal, September 2008

Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009

Crystalline Covalent Organic Frameworks with Hydrazone Linkages
journal, August 2011

Synthesis of Metal−Organic Complex Arrays
journal, February 2011

Metal–organic frameworks with designed chiral recognition sites
journal, January 2010

Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks
journal, January 2008

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007

Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008

Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008

Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry
journal, June 2000

Reticular synthesis and the design of new materials
journal, June 2003

Metal–organic Frameworks: A tale of two entanglements
journal, February 2007

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy
journal, September 2009

A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers
journal, July 2005

Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
journal, February 2007

Metal-organic frameworks—New materials for hydrogen storage
journal, April 2007

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5)
journal, November 2007

Combinatorial Material Libraries on the Microgram Scale with an Example of Hydrothermal Synthesis
journal, December 1998

A Crystalline Mesoporous Coordination Copolymer with High Microporosity
journal, January 2008

Parallel Synthesis of ZSM-5 Zeolite Films from Clear Organic-Free Solutions
journal, January 2001

A metal–organic framework replete with ordered donor–acceptor catenanes
journal, January 2010

The pervasive chemistry of metal–organic frameworks
journal, January 2009

Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
journal, October 2010

Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005

Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010

Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake
journal, August 2011

Non-carboxylate based metal-organic frameworks (MOFs) and related aspects
journal, June 2009

Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005

A Metal−Organic Framework with Covalently Bound Organometallic Complexes
journal, July 2010

The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010

Synthesis and Characterization of Zirconogermanates
journal, September 2003

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005

Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004

Construction of Microporous Materials from Molecular Building Blocks
book, January 2002

Metal–organic frameworks: a new class of porous materials
journal, August 2004

Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005

Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
journal, August 2005

Characterization of H₂ Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
journal, October 2005

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

Raman Spectroscopic Investigation of CH₄ and N₂ Adsorption in Metal−Organic Frameworks
journal, July 2007

Determination of the hydrogen absorption sites in Zn₄O(1,4-benzenedicarboxylate) by single crystal neutron diffraction
journal, January 2006

NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5
journal, March 2006

High-Throughput Synthesis of Phosphonate-Based Inorganic–Organic Hybrid Compounds under Hydrothermal Conditions
journal, January 2004

Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997

Polycatenation, polythreading and polyknotting in coordination network chemistry
journal, November 2003

Tertiary Building Units: Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1)
October 2001

Cu₂(ATC)·6H₂O: Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC: 1,3,5,7-Adamantane Tetracarboxylate)
journal, November 2000

Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures
journal, August 2001

20 Å Cd₄In₁₆S₃₅^14- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks
journal, May 2001

Ge₂ZrO₆F₂·(H₂DAB)H₂O:¹ A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings
journal, December 2000

Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework
journal, June 1999

Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999

An Open-Framework Germanate with Polycubane-Like Topology
journal, March 1999

Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998

Porous Germanates: Synthesis, Structure, and Inclusion Properties of Ge₇O_14.5F₂·[(CH₃)₂NH₂]₃(H₂O)_0.86
journal, August 1998

Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998

Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn₃(BDC)₃·6CH₃OH (BDC = 1,4-Benzenedicarboxylate)
journal, March 1998

Rotaxanes as ligands: from molecules to materials
journal, January 2007

Frameworks for Extended Solids: Geometrical Design Principles
journal, June 2000

Germanate Zeolites: Contrasting the Behavior of Germanate and Silicate Structures Built from Cubic T₈O₂₀ Units (T=Ge or Si)
journal, October 1999

A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
journal, December 2001

Large Free Volume in Maximally Interpenetrating Networks: The Role of Secondary Building Units Exemplified by Tb₂(ADB)₃[(CH₃)₂SO]₄·16[(CH₃)₂SO]¹
journal, May 2000

A Microporous Lanthanide-Organic Framework
journal, September 1999

From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites
journal, March 1999

Infinite Secondary Building Units and Forbidden Catenation in Metal-Organic Frameworks
journal, January 2002

Advances in the chemistry of metal–organic frameworks
journal, January 2002

Metal–organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units
journal, November 2001

Exceptional H₂ Saturation Uptake in Microporous Metal−Organic Frameworks
journal, March 2006

Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids^†
journal, August 1998

Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
journal, January 1997