Isomerization of sugars

Moliner-Marin, Manuel; Roman-Leshkov, Yuriy; Davis, Mark E; Nikolla, Eranda

Advanced Search OptionsAdvanced Search queries use a traditional Term Search. For more info, see our FAQ.

All Fields:

Patent Title:

Abstract:

Assignee:

Inventor(s):

Patent Number:

Patent Classification (CPC):

All Classifications
A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
E03 - water supply
E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
E21 - earth drilling
E99 - subject matter not otherwise provided for in this section
F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
G10 - musical instruments
G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
G99 - subject matter not otherwise provided for in this section
H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
H99 - subject matter not otherwise provided for in this section
Y - new / cross sectional technologies
Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

More Options ...

Title: Isomerization of sugars

Abstract

Disclosed are processes for isomerizing saccharides. Also disclosed are processes for converting saccharides to furan derivatives. Also disclosed are processes for converting starch to furan derivatives.

Inventors:: Moliner-Marin, Manuel; Roman-Leshkov, Yuriy; Davis, Mark E; Nikolla, Eranda

Issue Date:: 2014-05-20

Research Org.:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1132074

Patent Number(s):: 8729256

Application Number:: 13/007,389

Assignee:: California Institute of Technology (Pasadena, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07H - SUGARS

Show more

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C07D307/58 - One oxygen atom, e.g. butenolide

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07H - SUGARS
C07H1/00 - Processes for the preparation of sugar derivatives
C07H3/02 - Monosaccharides

Show less

DOE Contract Number:: SC0001004

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Jan 14

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Moliner-Marin, Manuel, Roman-Leshkov, Yuriy, Davis, Mark E, and Nikolla, Eranda. Isomerization of sugars.  United States: N. p., 2014. 
        Web.

Copy to clipboard


                    Moliner-Marin, Manuel, Roman-Leshkov, Yuriy, Davis, Mark E, & Nikolla, Eranda. Isomerization of sugars.  United States.

Copy to clipboard


                    Moliner-Marin, Manuel, Roman-Leshkov, Yuriy, Davis, Mark E, and Nikolla, Eranda. Tue .  
        "Isomerization of sugars".  United States.  https://www.osti.gov/servlets/purl/1132074.

Copy to clipboard


                    
@article{osti_1132074,

  title        = {Isomerization of sugars},

  author       = {Moliner-Marin, Manuel and Roman-Leshkov, Yuriy and Davis, Mark E and Nikolla, Eranda},

  abstractNote = {Disclosed are processes for isomerizing saccharides. Also disclosed are processes for converting saccharides to furan derivatives. Also disclosed are processes for converting starch to furan derivatives.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {5}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Process for the isomerization of glucose
patent, February 1983

Neuzil, Richard W.; Priegnitz, James W.
US Patent Document 4,373,025
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4373025

Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
patent, October 1983

Taramasso, Marco; Perego, Giovanni; Notari, Bruno
US Patent Document 4,410,501
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4410501

Catalytic process for producing furan derivatives in a biphasic reactor
patent, August 2009

Dumesic, James A.; Rom{acute over (α)}n-Leshkov, Yuriy; Chheda, Juben Nemchand
US Patent Document 7,572,925
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7572925

Method to bind enzyme to carrier using cationic copolymers and produced thereby
patent-application, June 2004

Scheels, Norman E.
US Patent Application 10/472717; 20040121437
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040121437

Mesoporous material with active metals
patent-application, September 2005

Shan, Zhiping; Jansen, Jacobus Cornelius; Yeh, Chuen Y.
US Patent Application 11/101858; 20050201920
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050201920

Zeolite-catalyzed preparation of alpha-hydroxy carboxylic acids and esters thereof
patent-application, May 2010

Taarning, Esben; Shunmugavel, Saravanamurugan; Holm, Martin
US Patent Application 12/614251; 20100121096
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100121096

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

Moliner, M.; Roman-Leshkov, Y.; Davis, M. E.
Proceedings of the National Academy of Sciences, Vol. 107, Issue 14, p. 6164-6168
https://doi.org/10.1073/pnas.1002358107

Isomerization of d-glucose to d-fructose over metallosilicate solid bases
journal, April 2008

Lima, Sérgio; Dias, Ana S.; Lin, Zhi
Applied Catalysis A: General, Vol. 339, Issue 1, p. 21-27
https://doi.org/10.1016/j.apcata.2007.12.030

Dehydrogenation of Propane over Platinum Containing CIT-6
journal, June 2004

Andy, P.; Davis, M. E.
Industrial & Engineering Chemistry Research, Vol. 43, Issue 12
https://doi.org/10.1021/ie030357m

Synthesis, Characterization, and Catalytic Activity of Ti-MCM-41 Structures
journal, September 1995

Blasco, T.; Corma, A.; Navarro, M. T.
Journal of Catalysis, Vol. 156, Issue 1
https://doi.org/10.1006/jcat.1995.1232

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction)
journal, April 2002

Corma, Avelino; Domine, Marcelo E.; Nemeth, Laszlo
Journal of the American Chemical Society, Vol. 124, Issue 13, p. 3194-3195
https://doi.org/10.1021/ja012297m

Lewis acidic Sn(IV) centers—grafted onto MCM-41—as catalytic sites for the Baeyer–Villiger oxidation with hydrogen peroxide
journal, October 2003

Corma, Avelino; Navarro, Marı́a Teresa; Renz, Michael
Journal of Catalysis, Vol. 219, Issue 1, p. 242-246
https://doi.org/10.1016/S0021-9517(03)00190-8

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

Corma, Avelino; Nemeth, Laszlo T.; Renz, Michael
Nature, Vol. 412, Issue 6845
https://doi.org/10.1038/35086546

Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite
journal, July 2009

Corma, Avelino; Llabrés i Xamena, Francesc X.; Prestipino, Carmelo
The Journal of Physical Chemistry C, Vol. 113, Issue 26, p. 11306-11315
https://doi.org/10.1021/jp902375n

Lewis Acids: From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis
journal, November 2003

Corma, Avelino; García, Hermenegildo
Chemical Reviews, Vol. 103, Issue 11
https://doi.org/10.1021/cr030680z

Effective Gene Silencing by Multilayered siRNA-Coated Gold Nanoparticles
journal, December 2010

Lee, Seung Koo; Han, Myung Shin; Asokan, Subashini
Small, Vol. 7, Issue 3
https://doi.org/10.1002/smll.201001314

Five Years of siRNA Delivery: Spotlight on Gold Nanoparticles
journal, June 2011

Lytton-Jean, Abigail K. R.; Langer, Robert; Anderson, Daniel G.
Small, Vol. 7, Issue 14
https://doi.org/10.1002/smll.201100761

Zeolite-Catalyzed Isomerization of Triose Sugars
journal, July 2009

Taarning, Esben; Saravanamurugan, Shunmugavel; Spangsberg Holm, Martin
ChemSusChem, Vol. 2, Issue 7, p. 625-627
https://doi.org/10.1002/cssc.200900099

Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently
journal, November 2012

Bermejo-Deval, Ricardo; Gounder, Rajamani; Davis, Mark E.
ACS Catalysis, Vol. 2, Issue 12
https://doi.org/10.1021/cs300474x

Beyond shape selective catalysis with zeolites: Hydrophobic void spaces in zeolites enable catalysis in liquid water
journal, January 2013

Gounder, Rajamani; Davis, Mark E.
AIChE Journal, Vol. 59, Issue 9, p. 3349-3358
https://doi.org/10.1002/aic.14016

Tin-catalyzed conversion of trioses to alkyl lactates in alcohol solution
journal, January 2005

Hayashi, Yukiko; Sasaki, Yoshiyuki
Chemical Communications, Issue 21
https://doi.org/10.1039/B501964H

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
journal, April 2010

Holm, Martin Spangsberg; Saravanamurugan, Shunmugavel; Taarning, Esben
Science, Vol. 328, Issue 5978, p. 602-605
https://doi.org/10.1126/science.1183990

Synthesis and physicochemical properties of zeolites containing framework titanium
journal, June 1994

Dartt, C. B.; Khouw, C. B.; Li, H.-X.
Microporous Materials, Vol. 2, Issue 5, p. 425-437
https://doi.org/10.1016/0927-6513(94)00009-3

Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water
journal, October 2010

Román-Leshkov, Yuriy; Moliner, Manuel; Labinger, Jay A.
Angewandte Chemie International Edition, Vol. 49, Issue 47, p. 8954-8957
https://doi.org/10.1002/anie.201004689

Similar Records in DOE Patents and OSTI.GOV collections:

Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen

Patent Werpy, Todd A [West Richland, WA]; Zacher, Alan H [Kennewick, WA]; Miller, Dennis J [Okemos, MI]

Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.
Full Text Available
Methods for dehydration of sugars and sugar alcohols

Patent Holladay, Johnathan E [Kennewick, WA]; Hu, Jianli [Kennewick, WA]; Zhang, Xinjie [Burlington, MA]; ...

The invention includes a method of dehydration of a sugar using a dehydration catalyst and a co-catalyst within a reactor. A sugar is introduced and H.sub.2 is flowed through the reactor at a pressure of less than or equal to about 300 psig to convert at least some of the sugar into an anhydrosugar product. The invention includes a process for producing isosorbide. A starting material comprising sorbitol is flowed into a reactor. H.sub.2 is counter flowed through the reactor. The starting material is exposed to a catalyst in the presence of a co-catalyst which comprises at least one metal.more » « less
Full Text Available
Converting sugars to sugar alcohols by aqueous phase catalytic hydrogenation

Patent Elliott, Douglas C [Richland, WA]; Werpy, Todd A [West Richland, WA]; Wang, Yong [Richland, WA]; ...

The present invention provides a method of converting sugars to their corresponding sugar alcohols by catalytic hydrogenation in the aqueous phase. It has been found that surprisingly superior results can be obtained by utilizing a relatively low temperature (less than 120.degree. C.), selected hydrogenation conditions, and a hydrothermally stable catalyst. These results include excellent sugar conversion to the desired sugar alcohol, in combination with long life under hydrothermal conditions.
Full Text Available
Hydrogenolysis Of 5-Carbon Sugars, Sugar Alcohols And Compositions For Reactions Involving Hydrogen

Patent Werpy, Todd A [West Richland, WA]; Frye, Jr., John G. (Richland, WA); Zacher, Alan H [Kennewick, WA]; ...

Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.
Full Text Available
Hydrogenolysis of 5-carbon sugars, sugar alcohols, and methods of making propylene glycol

Patent Werpy, Todd A [West Richland, WA]; Zacher, Alan H [Kennewick, WA]; Miller, Dennis J [Okemos, MI]

Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.
Full Text Available

Similar Records

Title: Isomerization of sugars

Abstract

Citation Formats

Process for the isomerization of glucose patent, February 1983

Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides patent, October 1983

Catalytic process for producing furan derivatives in a biphasic reactor patent, August 2009

Method to bind enzyme to carrier using cationic copolymers and produced thereby patent-application, June 2004

Mesoporous material with active metals patent-application, September 2005

Zeolite-catalyzed preparation of alpha-hydroxy carboxylic acids and esters thereof patent-application, May 2010

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water journal, March 2010

Isomerization of d-glucose to d-fructose over metallosilicate solid bases journal, April 2008

Dehydrogenation of Propane over Platinum Containing CIT-6 journal, June 2004

Synthesis, Characterization, and Catalytic Activity of Ti-MCM-41 Structures journal, September 1995

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction) journal, April 2002

Lewis acidic Sn(IV) centers—grafted onto MCM-41—as catalytic sites for the Baeyer–Villiger oxidation with hydrogen peroxide journal, October 2003

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations journal, July 2001

Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite journal, July 2009

Lewis Acids: From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis journal, November 2003

Effective Gene Silencing by Multilayered siRNA-Coated Gold Nanoparticles journal, December 2010

Five Years of siRNA Delivery: Spotlight on Gold Nanoparticles journal, June 2011

Zeolite-Catalyzed Isomerization of Triose Sugars journal, July 2009

Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently journal, November 2012

Beyond shape selective catalysis with zeolites: Hydrophobic void spaces in zeolites enable catalysis in liquid water journal, January 2013

Tin-catalyzed conversion of trioses to alkyl lactates in alcohol solution journal, January 2005

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts journal, April 2010

Synthesis and physicochemical properties of zeolites containing framework titanium journal, June 1994

Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water journal, October 2010

Process for the isomerization of glucose
patent, February 1983

Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides
patent, October 1983

Catalytic process for producing furan derivatives in a biphasic reactor
patent, August 2009

Method to bind enzyme to carrier using cationic copolymers and produced thereby
patent-application, June 2004

Mesoporous material with active metals
patent-application, September 2005

Zeolite-catalyzed preparation of alpha-hydroxy carboxylic acids and esters thereof
patent-application, May 2010

Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water
journal, March 2010

Isomerization of d-glucose to d-fructose over metallosilicate solid bases
journal, April 2008

Dehydrogenation of Propane over Platinum Containing CIT-6
journal, June 2004

Synthesis, Characterization, and Catalytic Activity of Ti-MCM-41 Structures
journal, September 1995

Al-Free Sn-Beta Zeolite as a Catalyst for the Selective Reduction of Carbonyl Compounds (Meerwein−Ponndorf−Verley Reaction)
journal, April 2002

Lewis acidic Sn(IV) centers—grafted onto MCM-41—as catalytic sites for the Baeyer–Villiger oxidation with hydrogen peroxide
journal, October 2003

Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations
journal, July 2001

Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite
journal, July 2009

Lewis Acids: From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis
journal, November 2003

Effective Gene Silencing by Multilayered siRNA-Coated Gold Nanoparticles
journal, December 2010

Five Years of siRNA Delivery: Spotlight on Gold Nanoparticles
journal, June 2011

Zeolite-Catalyzed Isomerization of Triose Sugars
journal, July 2009

Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently
journal, November 2012

Beyond shape selective catalysis with zeolites: Hydrophobic void spaces in zeolites enable catalysis in liquid water
journal, January 2013

Tin-catalyzed conversion of trioses to alkyl lactates in alcohol solution
journal, January 2005

Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts
journal, April 2010

Synthesis and physicochemical properties of zeolites containing framework titanium
journal, June 1994

Mechanism of Glucose Isomerization Using a Solid Lewis Acid Catalyst in Water
journal, October 2010