Catalyzed CO.sub.2-transport membrane on high surface area inorganic support
Abstract
Disclosed are membranes and methods for making the same, which membranes provide improved permeability, stability, and cost-effective manufacturability, for separating CO.sub.2 from gas streams such as flue gas streams. High CO.sub.2 permeation flux is achieved by immobilizing an ultra-thin, optionally catalyzed fluid layer onto a meso-porous modification layer on a thin, porous inorganic substrate such as a porous metallic substrate. The CO.sub.2-selective liquid fluid blocks non-selective pores, and allows for selective absorption of CO.sub.2 from gas mixtures such as flue gas mixtures and subsequent transport to the permeation side of the membrane. Carbon dioxide permeance levels are in the order of 1.0.times.10.sup.-6 mol/(m.sup.2sPa) or better. Methods for making such membranes allow commercial scale membrane manufacturing at highly cost-effective rates when compared to conventional commercial-scale CO.sub.2 separation processes and equipment for the same and such membranes are operable on an industrial use scale.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1130954
- Patent Number(s):
- 8715392
- Application Number:
- 12/901,119
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Liu, Wei. Catalyzed CO.sub.2-transport membrane on high surface area inorganic support. United States: N. p., 2014.
Web.
Liu, Wei. Catalyzed CO.sub.2-transport membrane on high surface area inorganic support. United States.
Liu, Wei. Tue .
"Catalyzed CO.sub.2-transport membrane on high surface area inorganic support". United States. https://www.osti.gov/servlets/purl/1130954.
@article{osti_1130954,
title = {Catalyzed CO.sub.2-transport membrane on high surface area inorganic support},
author = {Liu, Wei},
abstractNote = {Disclosed are membranes and methods for making the same, which membranes provide improved permeability, stability, and cost-effective manufacturability, for separating CO.sub.2 from gas streams such as flue gas streams. High CO.sub.2 permeation flux is achieved by immobilizing an ultra-thin, optionally catalyzed fluid layer onto a meso-porous modification layer on a thin, porous inorganic substrate such as a porous metallic substrate. The CO.sub.2-selective liquid fluid blocks non-selective pores, and allows for selective absorption of CO.sub.2 from gas mixtures such as flue gas mixtures and subsequent transport to the permeation side of the membrane. Carbon dioxide permeance levels are in the order of 1.0.times.10.sup.-6 mol/(m.sup.2sPa) or better. Methods for making such membranes allow commercial scale membrane manufacturing at highly cost-effective rates when compared to conventional commercial-scale CO.sub.2 separation processes and equipment for the same and such membranes are operable on an industrial use scale.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {5}
}
Works referenced in this record:
Air Electrodes for High-Energy Metal Air Batteries and Methods of Making the Same
patent-application, July 2012
- Zhang, Ji-Guang; Xiao, Jie; Xu, Wu
- US Patent Application 13/414641; 20120180945
Stabilization of Metal Nanoparticles in Cubic Mesostructured Silica and Its Application in Regenerable Deep Desulfurization of Warm Syngas
journal, November 2009
- Li, Liyu; King, David L.; Liu, Jun
- Chemistry of Materials, Vol. 21, Issue 22
Conductive membrane for carbon dioxide separation
patent-application, May 2008
- Lee, Shiwoo; Woo, Sang Kuk; Yu, JI Haeng
- US Patent Application 11/984736; 20080115667
Battery venting system
patent-application, December 2004
- Smith, Roger Q.; Liu, Xiao Ping
- US Patent Application 10/453836; 20040247996
Carbon Dioxide-Oxygen Separation: Facilitated Transport of Carbon Dioxide across a Liquid Film
journal, June 1967
- Ward, W. J.; Robb, W. L.
- Science, Vol. 156, Issue 3781
Supported Absorption of CO2 by Tetrabutylphosphonium Amino Acid Ionic Liquids
journal, May 2006
- Zhang, Jianmin; Zhang, Suojiang; Dong, Kun
- Chemistry - A European Journal, Vol. 12, Issue 15
Guide to CO 2 Separations in Imidazolium-Based Room-Temperature Ionic Liquids
journal, March 2009
- Bara, Jason E.; Carlisle, Trevor K.; Gabriel, Christopher J.
- Industrial & Engineering Chemistry Research, Vol. 48, Issue 6
Development of cesium-incorporated carbon membranes for CO2 separation under humid conditions
journal, October 2009
- Kai, Teruhiko; Kazama, Shingo; Fujioka, Yuichi
- Journal of Membrane Science, Vol. 342, Issue 1-2, p. 14-21
Facilitated transport of CO2 and SO2 through Supported Ionic Liquid Membranes (SILMs)
journal, September 2009
- Luis, P.; Neves, L. A.; Afonso, C. A. M.
- Desalination, Vol. 245, Issue 1-3, p. 485-493
Air Electrodes for High-Energy Metal Air Batteries and Methods of Making the Same
patent-application, March 2011
- Zhang, Ji-Guang; Xiao, JIe; Xu, Wu
- US Patent Application 12/557455; 20110059364
Adsorption of CO2 on the Rutile (110) Surface in Ionic Liquid. A Molecular Dynamics Simulation
journal, October 2009
- Yan, Tianying; Wang, Shu; Zhou, Yuan
- The Journal of Physical Chemistry C, Vol. 113, Issue 45, p. 19389-19392
Carbon Dioxide Capture Using a CO 2 -Selective Facilitated Transport Membrane
journal, February 2008
- Huang, Jin; Zou, Jian; Ho, W. S. Winston
- Industrial & Engineering Chemistry Research, Vol. 47, Issue 4
CO2 separation facilitated by task-specific ionic liquids using a supported liquid membrane
journal, April 2008
- Hanioka, Shoji; Maruyama, Tatsuo; Sotani, Tomohiro
- Journal of Membrane Science, Vol. 314, Issue 1-2, p. 1-4
Rechargeable Air Battery and Manufacturing Method
patent-application, February 2009
- Johnson, Lonnie G.; Tamirisa, Prabhakar A.; Zhang, Ji-Guang
- US Patent Application 11/843814; 20090053594
Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics
patent-application, December 2010
- Liu, Wei; Zhang, Jian
- US Patent Application 12/817694; 20100304953
Thin, Porous Metal Sheets and Methods for Making the Same
patent-application, June 2011
- Liu, Wei; Li, Xiaohong Shari; Canfield, Nathan L.
- US Patent Application 13/032,752; 2011/0155662 Al
Ionic Liquids-Based Catalysis with Solids: State of the Art
journal, April 2009
- Gu, Yanlong; Li, Guangxing
- Advanced Synthesis & Catalysis, Vol. 351, Issue 6, p. 817-847
The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane
journal, October 2001
- Morigami, Yoshio; Kondo, Masakazu; Abe, Jun
- Separation and Purification Technology, Vol. 25, Issue 1-3, p. 251-260
Enzymatic toxic gas sensor
patent, June 1985
- Campbell, Donald N.; Schmidt, John C.
- US Patent Document 4,525,704
Facilitated transport of CO2 in novel PVAm/PVA blend membrane
journal, September 2009
- Deng, Liyuan; Kim, Taek-Joong; Hägg, May-Britt
- Journal of Membrane Science, Vol. 340, Issue 1-2, p. 154-163
Parametric Study of CO 2 Fixed Carrier Facilitated Transport through Swollen Chitosan Membranes
journal, January 2009
- El-Azzami, Louei A.; Grulke, Eric A.
- Industrial & Engineering Chemistry Research, Vol. 48, Issue 2
Molten carbonate fuel cell
patent, January 1990
- Ohzu, Hideyuki; Akasaka, Yoshihiro; Tateishi, Hiroshi
- US Patent Document 4,895,774
Very fast CO2 response and hydrophobic properties of novel poly(ionic liquid)s
journal, January 2009
- Mineo, Placido G.; Livoti, Letizia; Giannetto, Marco
- Journal of Materials Chemistry, Vol. 19, Issue 46
Fixation and conversion of CO2 using ionic liquids
journal, June 2006
- Zhang, Suojiang; Chen, Yuhuan; Li, Fuwei
- Catalysis Today, Vol. 115, Issue 1-4, p. 61-69
Ether-Based Electrolytes for the Lithium/Oxygen Organic Electrolyte Battery
journal, January 2006
- Read, J.
- Journal of The Electrochemical Society, Vol. 153, Issue 1, p. A96-A100
Preparation of hydrophilic and acid-proof silicalite-1 zeolite membrane and its application to selective separation of water from water solutions of concentrated acetic acid by pervaporation
journal, July 2003
- Masuda, Takao; Otani, Shu-hei; Tsuji, Toshiro
- Separation and Purification Technology, Vol. 32, Issue 1-3, p. 181-189
Method of Manufacturing lithium secondary cell
patent-application, May 2002
- Noh, Hyung-Gon
- US Patent Application 09/852843; 20020050054
Rechargeable lithium intercalation battery with hybrid polymeric electrolyte
patent, March 1994
- Gozdz, Antoni S.; Schmutz, Caroline N.; Tarascon, Jean-Marie
- US Patent Document 5,296,318
Pervaporation and vapor permeation dehydration of Fischer–Tropsch mixed-alcohols by LTA zeolite membranes
journal, October 2007
- Li, Yanshuo; Chen, Hongliang; Liu, Jie
- Separation and Purification Technology, Vol. 57, Issue 1, p. 140-146
Pushing the limits on possibilities for large scale gas separation: which strategies?
journal, August 2000
- Koros, William J.; Mahajan, Rajiv
- Journal of Membrane Science, Vol. 175, Issue 2
Gas dehydration membrane with low oxygen and nitrogen permeability
patent, July 2000
- Valus, Ronald J.; Nichols, Randall W.; Davis, James C.
- US Patent Document 6,083,297
Battery
patent, June 2010
- Richards, Thomas C.; Gilicinski, Andrew G.; Pavlinsky, Robert
- US Patent Document 7,740,965
Composite hollow fiber membranes for CO2 capture
journal, January 2010
- Sandru, Marius; Haukebø, Siv Hustad; Hägg, May-Britt
- Journal of Membrane Science, Vol. 346, Issue 1, p. 172-186
Air Battery System and Methods for Using and Controlling Air Battery System
patent-application, July 2010
- Nakanishi, Shinji
- US Patent Application 12/669973; 20100190043
Zeolite membrane with a selectivity enhancing coating
patent, February 1998
- Deckman, Harry W.; Corcoran, Jr., Edward W.; McHenry, James Alexander
- US Patent Document 5,716,527
Air battery and method for producing air electrode for air battery
patent-application, July 2007
- Takamura, Koshi; Shimamura, Harunari
- US Patent Application 11/651601; 20070160898
Antimicrobial coated metal sheet
patent, August 2005
- Myers, Frederick Alan; Price, Leroy R.
- US Patent Document 6,929,705
Gas separation membranes
patent-application, August 2004
- Lyons, Arthur; Van Den Gross, Andrew
- US Patent Application 10/636294; 20040149127
Process of forming conductive oxide layers in solid oxide fuel cells
patent, January 1989
- Riley, Brian
- US Patent Document 4,799,936
Critical material and process issues for CO2 separation from coal-powered plants
journal, April 2009
- Liu, Wei; King, David; Liu, Jun
- JOM, Vol. 61, Issue 4
Hollow fiber membrane type artificial lung
patent, November 1988
- Fukasawa, Hiromichi; Katsura, Yoshiro; Hagiwara, Kazuhiko
- US Patent Document 4,781,889
Solid polymer electrolyte-based oxygen batteries
patent, April 1996
- Abraham, Kuzhikalail M.; Jiang, Zhiping
- US Patent Document 5,510,209
Applications of Pore-Expanded Mesoporous Silicas. 3. Triamine Silane Grafting for Enhanced CO 2 Adsorption
journal, April 2006
- Harlick, Peter J. E.; Sayari, Abdelhamid
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 9
Three-Dimensional Porous Copper-Tin Alloy Electrodes for Rechargeable Lithium Batteries
journal, April 2005
- Shin, H.-C.; Liu, M.
- Advanced Functional Materials, Vol. 15, Issue 4, p. 582-586
Experimental investigation of the permeability and selectivity of supported ionic liquid membranes for CO2/He separation at temperatures up to 125°C
journal, July 2007
- Ilconich, Jeffery; Myers, Christina; Pennline, Henry
- Journal of Membrane Science, Vol. 298, Issue 1-2, p. 41-47
Bulk-Fluid Solubility and Membrane Feasibility of Rmim-Based Room-Temperature Ionic Liquids
journal, August 2006
- Camper, Dean; Bara, Jason; Koval, Carl
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 18
Immobilized Fluid Membranes For Gas Separation
patent-application, November 2010
- Liu, Wei; Canfield, Nathan; Zhang, Jian
- US Patent Application 12/470294; 20100297531
Characterization of the Lithium/Oxygen Organic Electrolyte Battery
journal, January 2002
- Read, J.
- Journal of The Electrochemical Society, Vol. 149, Issue 9, p. A1190-A1195
Enhanced CO 2 Absorption of Poly(ionic liquid)s
journal, March 2005
- Tang, Jianbin; Sun, Weilin; Tang, Huadong
- Macromolecules, Vol. 38, Issue 6
Electrochemical cells with non-aqueous electrolytes containing macroheterocyclic compounds
patent, January 1979
- Soffer, Abraham
- US Patent Document 4,132,837
Carbonate fuel cell anodes
patent, April 1993
- Donado, Rafael A.; Hrdina, Kenneth Edward; Remick, Robert J.
- US Patent Document 5,206,095
Tubular ceramic-supported sol–gel silica-based membranes for flue gas carbon dioxide capture and sequestration
journal, September 2009
- Xomeritakis, G.; Tsai, C. Y.; Jiang, Y. B.
- Journal of Membrane Science, Vol. 341, Issue 1-2, p. 30-36
Secondary Li battery incorporating 12-Crown-4 ether
patent, May 1992
- Nagasubramanian, Ganesan; DiStefano, Salvador
- US Patent Document 5,110,694
Reaction kinetics between carbon dioxide and glycidyl methacrylate using trihexylamine immobilized ionic liquid on MCM41 catalyst
journal, November 2009
- Hwang, Kyu-Suk; Son, Young-Sik; Park, Sang-Wook
- Journal of Industrial and Engineering Chemistry, Vol. 15, Issue 6, p. 854-859
Low-pressure CO2 sorption in ammonium-based poly(ionic liquid)s
journal, December 2005
- Tang, Jianbin; Tang, Huadong; Sun, Weilin
- Polymer, Vol. 46, Issue 26, p. 12460-12467
Li-air batteries: A classic example of limitations owing to solubilities
journal, January 2007
- Kowalczk, Ian; Read, Jeffery; Salomon, Mark
- Pure and Applied Chemistry, Vol. 79, Issue 5
Surface functionalized mesoporous material and method of making same
patent, December 2001
- Feng, Xiangdong; Liu, Jun; Fryxell, Glen E.
- US Patent Document 6,326,326
Treatment of molecular sieves with silicon containing compounds
patent-application, January 2005
- Vaughn, Stephen N.; Ou, John Di-Yi; Kao, Jar-Lin
- US Patent Application 10/910813; 20050003957
Pushing the limits on possibilities for large scale gas separation: which strategies?
journal, January 2001
- Koros, William J.; Mahajan, Rajiv
- Journal of Membrane Science, Vol. 181, Issue 1
Cross-linked polybenzimidazole membrane for gas separation
patent, September 2005
- Jorgensen, Betty S.; Young, Jennifer; Espinoza, Brent F.
- US Patent Document 6,946,015
Membranes for Separation of Carbon Dioxide
patent-application, September 2008
- Ku, Anthony Yu-Chung; Ruud, James Anthony; Ramaswamy, VIdya
- US Patent Application 12/107148; 20080210087
Materials selection guidelines for membranes that remove CO2 from gas mixtures
journal, April 2005
- Lin, Haiqing; Freeman, Benny D.
- Journal of Molecular Structure, Vol. 739, Issue 1-3, p. 57-74
Solubilities of Carbon Dioxide and Densities of Aqueous Sodium Glycinate Solutions before and after CO 2 Absorption
journal, January 2009
- Harris, Faisal; Kurnia, Kiki Adi; Mutalib, M. Ibrahim A.
- Journal of Chemical & Engineering Data, Vol. 54, Issue 1
Synthesis of Defect-Free FAU-Type Zeolite Membranes and Separation for Dry and Moist CO2/N2 Mixtures
journal, February 2005
- Gu, Xuehong; Dong, Junhang; Nenoff, Tina M.
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 4, p. 937-944
Floating air breathing power source (FABPS)
patent, October 2002
- Leung, Fee Chan; Atwater, Terrill B.
- US Patent Document 6,464,742
Design of Task-Specific Ionic Liquids for Capturing CO 2 : A Molecular Orbital Study
journal, April 2006
- Yu, Guangren; Zhang, Suojiang; Yao, Xiaoqian
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 8
Selective separation of CO2 by using novel facilitated transport membrane at elevated temperatures and pressures
journal, March 2007
- Yegani, R.; Hirozawa, H.; Teramoto, M.
- Journal of Membrane Science, Vol. 291, Issue 1-2, p. 157-164
Dual Amino-Functionalised Phosphonium Ionic Liquids for CO2 Capture
journal, March 2009
- Zhang, Yanqiang; Zhang, Suojiang; Lu, Xingmei
- Chemistry - A European Journal, Vol. 15, Issue 12, p. 3003-3011
Influence of electrode structure on the performance of a direct methanol fuel cell
journal, April 2002
- Wei, Zhaobin; Wang, Suli; Yi, Baolian
- Journal of Power Sources, Vol. 106, Issue 1-2, p. 364-369
Hydrogen purification using room-temperature ionic liquids
journal, March 2007
- Yokozeki, A.; Shiflett, Mark B.
- Applied Energy, Vol. 84, Issue 3, p. 351-361
CO2-selective polymeric membranes containing amines in crosslinked poly(vinyl alcohol)
journal, December 2006
- Zou, Jian; Ho, W. S. Winston
- Journal of Membrane Science, Vol. 286, Issue 1-2, p. 310-321
Electrochemical device using multicomponent composite membrane film
patent, March 2006
- Lee, Seung Jin; Lee, Hyang Mok; Ahn, Soon-Ho
- US Patent Document 7,014,948
Carbon dioxide recovery from post-combustion processes: Can gas permeation membranes compete with absorption?
journal, May 2007
- Favre, Eric
- Journal of Membrane Science, Vol. 294, Issue 1-2, p. 50-59
Zeolite membrane for CO2 removal: Operating at high pressure
journal, April 2007
- Sebastian, V.; Kumakiri, I.; Bredesen, R.
- Journal of Membrane Science, Vol. 292, Issue 1-2
Membrane for selective transport of oxygen over water vapor and metal-air electrochemical cell including said membrane
patent, November 1999
- Reynolds, Thomas A.; Brose, Daniel J.; Golovin, Milton N.
- US Patent Document 5,985,475
Immobilized glycerol-based liquid membranes in hollow fibers for selective CO2 separation from CO2–N2 mixtures
journal, February 2001
- Chen, H.; Obuskovic, G.; Majumdar, S.
- Journal of Membrane Science, Vol. 183, Issue 1
Anode with an anode active material-retaining body having a number of pores distributed therein, a rechargeable battery, provided with said anode, and the process for the production of said anode
patent, December 1997
- Kawakami, Soichiro; Mishina, Shinya; Kobayashi, Naoya
- US Patent Document 5,698,339
Electrode for rechargeable lithium battery and rechargeable lithium battery including same
patent-application, February 2009
- Jeong, Goo-Jin; Choi, Nam-Soon; Lee, Sang-Min
- US Patent Application 12/155545; 20090053607
Membrane composed of a pure molecular sieve
patent, May 1991
- Haag, Werner O.; Tsikoyiannis, John G.
- US Patent Document 5,019,263
Facilitated transport of CO2 across a liquid membrane: Comparing enzyme, amine, and alkaline
journal, September 2006
- Bao, Lihong; Trachtenberg, Michael C.
- Journal of Membrane Science, Vol. 280, Issue 1-2, p. 330-334
Multicomponent hydrogen/hydrocarbon separation by MFI-type zeolite membranes
journal, October 2000
- Dong, Junhang; Lin, Y. S.; Liu, Wei
- AIChE Journal, Vol. 46, Issue 10, p. 1957-1966
Anodes for Lithium Ion Batteries
patent-application, May 2011
- Xu, Wu; Canfield, Nathan L.; Zhang, Ji-Guang
- US Patent Application 12/621410; 20110114254
HIGH-ENERGY METAL AIR BATTERIES
patent-application, March 2011
- Zhang, Ji-Guang; Xiao, Jie; Xu, Wu
- US Patent Application 12/557452; 20110059355
Ethylenediamine-Modified SBA-15 as Regenerable CO 2 Sorbent
journal, April 2005
- Zheng, Feng; Tran, Diana N.; Busche, Brad J.
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 9
Structure, interaction and property of amino-functionalized imidazolium ILs by molecular dynamics simulation and Ab initio calculation
journal, December 2007
- Yu, Guangren; Zhang, Suojiang; Zhou, Guohui
- AIChE Journal, Vol. 53, Issue 12, p. 3210-3221
Electrolyte solution sequestering agents for electrochemical cells having carbonaceous electrodes
patent, July 1992
- Wilkinson, David P.; Dahn, Jeffery R.
- US Patent Document 5,130,211
Self-assembled monolayer and method of making
patent, January 2005
- Fryxell, Glen E.; Zemanian, Thomas S.; Liu, Jun
- US Patent Document 6,846,554