Catalyzed CO.sub.2-transport membrane on high surface area inorganic support

Liu, Wei

Title: Catalyzed CO.sub.2-transport membrane on high surface area inorganic support

Abstract

Disclosed are membranes and methods for making the same, which membranes provide improved permeability, stability, and cost-effective manufacturability, for separating CO.sub.2 from gas streams such as flue gas streams. High CO.sub.2 permeation flux is achieved by immobilizing an ultra-thin, optionally catalyzed fluid layer onto a meso-porous modification layer on a thin, porous inorganic substrate such as a porous metallic substrate. The CO.sub.2-selective liquid fluid blocks non-selective pores, and allows for selective absorption of CO.sub.2 from gas mixtures such as flue gas mixtures and subsequent transport to the permeation side of the membrane. Carbon dioxide permeance levels are in the order of 1.0.times.10.sup.-6 mol/(m.sup.2sPa) or better. Methods for making such membranes allow commercial scale membrane manufacturing at highly cost-effective rates when compared to conventional commercial-scale CO.sub.2 separation processes and equipment for the same and such membranes are operable on an industrial use scale.

Inventors:: Liu, Wei

Issue Date:: 2014-05-06

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1130954

Patent Number(s):: 8715392

Application Number:: 12/901,119

Assignee:: Battelle Memorial Institute (Richland, WA)

DOE Contract Number:: AC06-76RL01830

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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                    Liu, Wei. Catalyzed CO.sub.2-transport membrane on high surface area inorganic support.  United States: N. p., 2014. 
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                    Liu, Wei. Catalyzed CO.sub.2-transport membrane on high surface area inorganic support.  United States.

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                    Liu, Wei. Tue .  
        "Catalyzed CO.sub.2-transport membrane on high surface area inorganic support".  United States.  https://www.osti.gov/servlets/purl/1130954.

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@article{osti_1130954,

  title        = {Catalyzed CO.sub.2-transport membrane on high surface area inorganic support},

  author       = {Liu, Wei},

  abstractNote = {Disclosed are membranes and methods for making the same, which membranes provide improved permeability, stability, and cost-effective manufacturability, for separating CO.sub.2 from gas streams such as flue gas streams. High CO.sub.2 permeation flux is achieved by immobilizing an ultra-thin, optionally catalyzed fluid layer onto a meso-porous modification layer on a thin, porous inorganic substrate such as a porous metallic substrate. The CO.sub.2-selective liquid fluid blocks non-selective pores, and allows for selective absorption of CO.sub.2 from gas mixtures such as flue gas mixtures and subsequent transport to the permeation side of the membrane. Carbon dioxide permeance levels are in the order of 1.0.times.10.sup.-6 mol/(m.sup.2sPa) or better. Methods for making such membranes allow commercial scale membrane manufacturing at highly cost-effective rates when compared to conventional commercial-scale CO.sub.2 separation processes and equipment for the same and such membranes are operable on an industrial use scale.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {5}

}

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Fryxell, Glen E.; Zemanian, Thomas S.; Liu, Jun
US Patent Document 6,846,554
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6846554

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Title: Catalyzed CO.sub.2-transport membrane on high surface area inorganic support

Abstract

Citation Formats

Air Electrodes for High-Energy Metal Air Batteries and Methods of Making the Same patent-application, July 2012

Stabilization of Metal Nanoparticles in Cubic Mesostructured Silica and Its Application in Regenerable Deep Desulfurization of Warm Syngas journal, November 2009

Conductive membrane for carbon dioxide separation patent-application, May 2008

Battery venting system patent-application, December 2004

Carbon Dioxide-Oxygen Separation: Facilitated Transport of Carbon Dioxide across a Liquid Film journal, June 1967

Supported Absorption of CO2 by Tetrabutylphosphonium Amino Acid Ionic Liquids journal, May 2006

Guide to CO 2 Separations in Imidazolium-Based Room-Temperature Ionic Liquids journal, March 2009

Development of cesium-incorporated carbon membranes for CO2 separation under humid conditions journal, October 2009

Facilitated transport of CO2 and SO2 through Supported Ionic Liquid Membranes (SILMs) journal, September 2009

Air Electrodes for High-Energy Metal Air Batteries and Methods of Making the Same patent-application, March 2011

Adsorption of CO2 on the Rutile (110) Surface in Ionic Liquid. A Molecular Dynamics Simulation journal, October 2009

Carbon Dioxide Capture Using a CO 2 -Selective Facilitated Transport Membrane journal, February 2008

CO2 separation facilitated by task-specific ionic liquids using a supported liquid membrane journal, April 2008

Rechargeable Air Battery and Manufacturing Method patent-application, February 2009

Radon removal system and process patent, March 1993

Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics patent-application, December 2010

Thin, Porous Metal Sheets and Methods for Making the Same patent-application, June 2011

Ionic Liquids-Based Catalysis with Solids: State of the Art journal, April 2009

The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane journal, October 2001

Enzymatic toxic gas sensor patent, June 1985

Facilitated transport of CO2 in novel PVAm/PVA blend membrane journal, September 2009

Parametric Study of CO 2 Fixed Carrier Facilitated Transport through Swollen Chitosan Membranes journal, January 2009

Molten carbonate fuel cell patent, January 1990

Fixation and conversion of CO2 using ionic liquids journal, June 2006

Ether-Based Electrolytes for the Lithium/Oxygen Organic Electrolyte Battery journal, January 2006

Preparation of hydrophilic and acid-proof silicalite-1 zeolite membrane and its application to selective separation of water from water solutions of concentrated acetic acid by pervaporation journal, July 2003

Method of Manufacturing lithium secondary cell patent-application, May 2002

Rechargeable lithium intercalation battery with hybrid polymeric electrolyte patent, March 1994

Pervaporation and vapor permeation dehydration of Fischer–Tropsch mixed-alcohols by LTA zeolite membranes journal, October 2007

Pushing the limits on possibilities for large scale gas separation: which strategies? journal, August 2000

Gas dehydration membrane with low oxygen and nitrogen permeability patent, July 2000

Battery patent, June 2010

Composite hollow fiber membranes for CO2 capture journal, January 2010

Air Battery System and Methods for Using and Controlling Air Battery System patent-application, July 2010

Zeolite membrane with a selectivity enhancing coating patent, February 1998

Air battery and method for producing air electrode for air battery patent-application, July 2007

Antimicrobial coated metal sheet patent, August 2005

Gas separation membranes patent-application, August 2004

Process of forming conductive oxide layers in solid oxide fuel cells patent, January 1989

Critical material and process issues for CO2 separation from coal-powered plants journal, April 2009

Hollow fiber membrane type artificial lung patent, November 1988

Solid polymer electrolyte-based oxygen batteries patent, April 1996

Applications of Pore-Expanded Mesoporous Silicas. 3. Triamine Silane Grafting for Enhanced CO 2 Adsorption journal, April 2006

Three-Dimensional Porous Copper-Tin Alloy Electrodes for Rechargeable Lithium Batteries journal, April 2005

Experimental investigation of the permeability and selectivity of supported ionic liquid membranes for CO2/He separation at temperatures up to 125°C journal, July 2007

Bulk-Fluid Solubility and Membrane Feasibility of Rmim-Based Room-Temperature Ionic Liquids journal, August 2006

Immobilized Fluid Membranes For Gas Separation patent-application, November 2010

Characterization of the Lithium/Oxygen Organic Electrolyte Battery journal, January 2002

Enhanced CO 2 Absorption of Poly(ionic liquid)s journal, March 2005

Electrochemical cells with non-aqueous electrolytes containing macroheterocyclic compounds patent, January 1979

Carbonate fuel cell anodes patent, April 1993

Tubular ceramic-supported sol–gel silica-based membranes for flue gas carbon dioxide capture and sequestration journal, September 2009

Secondary Li battery incorporating 12-Crown-4 ether patent, May 1992

Reaction kinetics between carbon dioxide and glycidyl methacrylate using trihexylamine immobilized ionic liquid on MCM41 catalyst journal, November 2009

Low-pressure CO2 sorption in ammonium-based poly(ionic liquid)s journal, December 2005

Li-air batteries: A classic example of limitations owing to solubilities journal, January 2007

Surface functionalized mesoporous material and method of making same patent, December 2001

Treatment of molecular sieves with silicon containing compounds patent-application, January 2005

Pushing the limits on possibilities for large scale gas separation: which strategies? journal, January 2001

Cross-linked polybenzimidazole membrane for gas separation patent, September 2005

Membranes for Separation of Carbon Dioxide patent-application, September 2008

Materials selection guidelines for membranes that remove CO2 from gas mixtures journal, April 2005

Solubilities of Carbon Dioxide and Densities of Aqueous Sodium Glycinate Solutions before and after CO 2 Absorption journal, January 2009

Synthesis of Defect-Free FAU-Type Zeolite Membranes and Separation for Dry and Moist CO2/N2 Mixtures journal, February 2005

Floating air breathing power source (FABPS) patent, October 2002

Design of Task-Specific Ionic Liquids for Capturing CO 2 : A Molecular Orbital Study journal, April 2006

Selective separation of CO2 by using novel facilitated transport membrane at elevated temperatures and pressures journal, March 2007

Dual Amino-Functionalised Phosphonium Ionic Liquids for CO2 Capture journal, March 2009

Influence of electrode structure on the performance of a direct methanol fuel cell journal, April 2002

Hydrogen purification using room-temperature ionic liquids journal, March 2007

CO2-selective polymeric membranes containing amines in crosslinked poly(vinyl alcohol) journal, December 2006

Electrochemical device using multicomponent composite membrane film patent, March 2006

Carbon dioxide recovery from post-combustion processes: Can gas permeation membranes compete with absorption? journal, May 2007

Zeolite membrane for CO2 removal: Operating at high pressure journal, April 2007

Membrane for selective transport of oxygen over water vapor and metal-air electrochemical cell including said membrane patent, November 1999

Immobilized glycerol-based liquid membranes in hollow fibers for selective CO2 separation from CO2–N2 mixtures journal, February 2001

Anode with an anode active material-retaining body having a number of pores distributed therein, a rechargeable battery, provided with said anode, and the process for the production of said anode patent, December 1997

Air Electrodes for High-Energy Metal Air Batteries and Methods of Making the Same
patent-application, July 2012

Stabilization of Metal Nanoparticles in Cubic Mesostructured Silica and Its Application in Regenerable Deep Desulfurization of Warm Syngas
journal, November 2009

Conductive membrane for carbon dioxide separation
patent-application, May 2008

Battery venting system
patent-application, December 2004

Carbon Dioxide-Oxygen Separation: Facilitated Transport of Carbon Dioxide across a Liquid Film
journal, June 1967

Supported Absorption of CO2 by Tetrabutylphosphonium Amino Acid Ionic Liquids
journal, May 2006

Guide to CO ₂ Separations in Imidazolium-Based Room-Temperature Ionic Liquids
journal, March 2009

Development of cesium-incorporated carbon membranes for CO₂ separation under humid conditions
journal, October 2009

Facilitated transport of CO₂ and SO₂ through Supported Ionic Liquid Membranes (SILMs)
journal, September 2009

Air Electrodes for High-Energy Metal Air Batteries and Methods of Making the Same
patent-application, March 2011

Adsorption of CO₂ on the Rutile (110) Surface in Ionic Liquid. A Molecular Dynamics Simulation
journal, October 2009

Carbon Dioxide Capture Using a CO ₂ -Selective Facilitated Transport Membrane
journal, February 2008

CO₂ separation facilitated by task-specific ionic liquids using a supported liquid membrane
journal, April 2008

Rechargeable Air Battery and Manufacturing Method
patent-application, February 2009

Radon removal system and process
patent, March 1993

Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics
patent-application, December 2010

Thin, Porous Metal Sheets and Methods for Making the Same
patent-application, June 2011

Ionic Liquids-Based Catalysis with Solids: State of the Art
journal, April 2009

The first large-scale pervaporation plant using tubular-type module with zeolite NaA membrane
journal, October 2001

Enzymatic toxic gas sensor
patent, June 1985

Facilitated transport of CO₂ in novel PVAm/PVA blend membrane
journal, September 2009

Parametric Study of CO ₂ Fixed Carrier Facilitated Transport through Swollen Chitosan Membranes
journal, January 2009

Molten carbonate fuel cell
patent, January 1990

Fixation and conversion of CO₂ using ionic liquids
journal, June 2006

Ether-Based Electrolytes for the Lithium/Oxygen Organic Electrolyte Battery
journal, January 2006

Preparation of hydrophilic and acid-proof silicalite-1 zeolite membrane and its application to selective separation of water from water solutions of concentrated acetic acid by pervaporation
journal, July 2003

Method of Manufacturing lithium secondary cell
patent-application, May 2002

Rechargeable lithium intercalation battery with hybrid polymeric electrolyte
patent, March 1994

Pervaporation and vapor permeation dehydration of Fischer–Tropsch mixed-alcohols by LTA zeolite membranes
journal, October 2007

Pushing the limits on possibilities for large scale gas separation: which strategies?
journal, August 2000

Gas dehydration membrane with low oxygen and nitrogen permeability
patent, July 2000

Battery
patent, June 2010

Composite hollow fiber membranes for CO₂ capture
journal, January 2010

Air Battery System and Methods for Using and Controlling Air Battery System
patent-application, July 2010

Zeolite membrane with a selectivity enhancing coating
patent, February 1998

Air battery and method for producing air electrode for air battery
patent-application, July 2007

Antimicrobial coated metal sheet
patent, August 2005

Gas separation membranes
patent-application, August 2004

Process of forming conductive oxide layers in solid oxide fuel cells
patent, January 1989

Critical material and process issues for CO2 separation from coal-powered plants
journal, April 2009

Hollow fiber membrane type artificial lung
patent, November 1988

Solid polymer electrolyte-based oxygen batteries
patent, April 1996

Applications of Pore-Expanded Mesoporous Silicas. 3. Triamine Silane Grafting for Enhanced CO ₂ Adsorption
journal, April 2006

Three-Dimensional Porous Copper-Tin Alloy Electrodes for Rechargeable Lithium Batteries
journal, April 2005

Experimental investigation of the permeability and selectivity of supported ionic liquid membranes for CO₂/He separation at temperatures up to 125°C
journal, July 2007

Bulk-Fluid Solubility and Membrane Feasibility of Rmim-Based Room-Temperature Ionic Liquids
journal, August 2006

Immobilized Fluid Membranes For Gas Separation
patent-application, November 2010

Characterization of the Lithium/Oxygen Organic Electrolyte Battery
journal, January 2002

Enhanced CO ₂ Absorption of Poly(ionic liquid)s
journal, March 2005

Electrochemical cells with non-aqueous electrolytes containing macroheterocyclic compounds
patent, January 1979

Carbonate fuel cell anodes
patent, April 1993

Tubular ceramic-supported sol–gel silica-based membranes for flue gas carbon dioxide capture and sequestration
journal, September 2009

Secondary Li battery incorporating 12-Crown-4 ether
patent, May 1992

Reaction kinetics between carbon dioxide and glycidyl methacrylate using trihexylamine immobilized ionic liquid on MCM41 catalyst
journal, November 2009

Low-pressure CO₂ sorption in ammonium-based poly(ionic liquid)s
journal, December 2005

Li-air batteries: A classic example of limitations owing to solubilities
journal, January 2007

Surface functionalized mesoporous material and method of making same
patent, December 2001

Treatment of molecular sieves with silicon containing compounds
patent-application, January 2005

Pushing the limits on possibilities for large scale gas separation: which strategies?
journal, January 2001

Cross-linked polybenzimidazole membrane for gas separation
patent, September 2005

Membranes for Separation of Carbon Dioxide
patent-application, September 2008

Materials selection guidelines for membranes that remove CO₂ from gas mixtures
journal, April 2005

Solubilities of Carbon Dioxide and Densities of Aqueous Sodium Glycinate Solutions before and after CO ₂ Absorption
journal, January 2009

Synthesis of Defect-Free FAU-Type Zeolite Membranes and Separation for Dry and Moist CO₂/N₂ Mixtures
journal, February 2005

Floating air breathing power source (FABPS)
patent, October 2002

Design of Task-Specific Ionic Liquids for Capturing CO ₂ : A Molecular Orbital Study
journal, April 2006

Selective separation of CO₂ by using novel facilitated transport membrane at elevated temperatures and pressures
journal, March 2007

Dual Amino-Functionalised Phosphonium Ionic Liquids for CO₂ Capture
journal, March 2009

Influence of electrode structure on the performance of a direct methanol fuel cell
journal, April 2002

Hydrogen purification using room-temperature ionic liquids
journal, March 2007

CO₂-selective polymeric membranes containing amines in crosslinked poly(vinyl alcohol)
journal, December 2006

Electrochemical device using multicomponent composite membrane film
patent, March 2006

Carbon dioxide recovery from post-combustion processes: Can gas permeation membranes compete with absorption?
journal, May 2007

Zeolite membrane for CO2 removal: Operating at high pressure
journal, April 2007

Membrane for selective transport of oxygen over water vapor and metal-air electrochemical cell including said membrane
patent, November 1999

Immobilized glycerol-based liquid membranes in hollow fibers for selective CO2 separation from CO2–N2 mixtures
journal, February 2001

Anode with an anode active material-retaining body having a number of pores distributed therein, a rechargeable battery, provided with said anode, and the process for the production of said anode
patent, December 1997

Electrode for rechargeable lithium battery and rechargeable lithium battery including same
patent-application, February 2009

Membrane composed of a pure molecular sieve
patent, May 1991

Facilitated transport of CO₂ across a liquid membrane: Comparing enzyme, amine, and alkaline
journal, September 2006