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Title: Functionalized boron nitride nanotubes

Abstract

A plasma treatment has been used to modify the surface of BNNTs. In one example, the surface of the BNNT has been modified using ammonia plasma to include amine functional groups. Amine functionalization allows BNNTs to be soluble in chloroform, which had not been possible previously. Further functionalization of amine-functionalized BNNTs with thiol-terminated organic molecules has also been demonstrated. Gold nanoparticles have been self-assembled at the surface of both amine- and thiol-functionalized boron nitride Nanotubes (BNNTs) in solution. This approach constitutes a basis for the preparation of highly functionalized BNNTs and for their utilization as nanoscale templates for assembly and integration with other nanoscale materials.

Inventors:
; ;
Issue Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1129390
Patent Number(s):
8,703,023
Application Number:
13/527,369
Assignee:
The Regents of the University of California (Oakland, CA)
DOE Contract Number:  
AC02-05CH11231
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Jun 19
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats

Sainsbury, Toby, Ikuno, Takashi, and Zettl, Alexander K. Functionalized boron nitride nanotubes. United States: N. p., 2014. Web.
Sainsbury, Toby, Ikuno, Takashi, & Zettl, Alexander K. Functionalized boron nitride nanotubes. United States.
Sainsbury, Toby, Ikuno, Takashi, and Zettl, Alexander K. Tue . "Functionalized boron nitride nanotubes". United States. https://www.osti.gov/servlets/purl/1129390.
@article{osti_1129390,
title = {Functionalized boron nitride nanotubes},
author = {Sainsbury, Toby and Ikuno, Takashi and Zettl, Alexander K},
abstractNote = {A plasma treatment has been used to modify the surface of BNNTs. In one example, the surface of the BNNT has been modified using ammonia plasma to include amine functional groups. Amine functionalization allows BNNTs to be soluble in chloroform, which had not been possible previously. Further functionalization of amine-functionalized BNNTs with thiol-terminated organic molecules has also been demonstrated. Gold nanoparticles have been self-assembled at the surface of both amine- and thiol-functionalized boron nitride Nanotubes (BNNTs) in solution. This approach constitutes a basis for the preparation of highly functionalized BNNTs and for their utilization as nanoscale templates for assembly and integration with other nanoscale materials.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {4}
}

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Works referenced in this record:

Low Temperature Growth of Boron Nitride Nanotubes on Substrates
journal, December 2005

  • Wang, Jiesheng; Kayastha, Vijaya K.; Yap, Yoke Khin
  • Nano Letters, Vol. 5, Issue 12
  • DOI: 10.1021/nl051859n

Covalent Functionalization: Towards Soluble Multiwalled Boron Nitride Nanotubes
journal, December 2005

  • Zhi, Chunyi; Bando, Yoshio; Tang, Chengchun
  • Angewandte Chemie International Edition, Vol. 44, Issue 48, p. 7932-7935
  • DOI: 10.1002/anie.200502846

Mass-production of boron nitride double-wall nanotubes and nanococoons
journal, January 2000


Hydrophobic Anchoring of Monolayer-Protected Gold Nanoclusters to Carbon Nanotubes
journal, March 2003

  • Ellis, A. V.; Vijayamohanan, K.; Goswami, R.
  • Nano Letters, Vol. 3, Issue 3
  • DOI: 10.1021/nl025824o

Amine-functionalized boron nitride nanotubes
journal, June 2007

  • Ikuno, T.; Sainsbury, T.; Okawa, D.
  • Solid State Communications, Vol. 142, Issue 11, p. 643-646
  • DOI: 10.1016/j.ssc.2007.04.010

Self-Assembly of Gold Nanoparticles at the Surface of Amine- and Thiol-Functionalized Boron Nitride Nanotubes
journal, September 2007

  • Sainsbury, Toby; Ikuno, Takashi; Okawa, David
  • The Journal of Physical Chemistry C, Vol. 111, Issue 35, p. 12992-12999
  • DOI: 10.1021/jp072958n

Packing C60 in Boron Nitride Nanotubes
journal, April 2003


Solubilization of boron nitride nanotubes
journal, January 2005

  • Xie, Su-Yuan; Wang, Wei; Fernando, K. A. Shiral
  • Chemical Communications, Issue 29
  • DOI: 10.1039/b505330g

Perfectly Dissolved Boron Nitride Nanotubes Due to Polymer Wrapping
journal, November 2005

  • Zhi, Chunyi; Bando, Yoshio; Tang, Chengchun
  • Journal of the American Chemical Society, Vol. 127, Issue 46
  • DOI: 10.1021/ja053917c