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Title: Devices and process for high-pressure magic angle spinning nuclear magnetic resonance

A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.
Inventors:
; ; ; ;
Issue Date:
OSTI Identifier:
1129164
Assignee:
Battelle Memorial Institute (Richland, WA) PNNL
Patent Number(s):
8,692,548
Application Number:
13/193,172
Contract Number:
AC05-76RLO1830
Resource Relation:
Patent File Date: 2011 Jul 28
Research Org:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING

Works referenced in this record:

The use of supercritical fluids as solvents for NMR spectroscopy
journal, October 2005
  • Yonker, Clement R.; Linehan, John C.
  • Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 47, Issue 1-2, p. 95-109
  • DOI: 10.1016/j.pnmrs.2005.08.002

Design and performance of a high pressure insert for use in a standard magic angle spinning NMR probe
journal, December 2006
  • Deuchande, Teresa; Breton, Olivier; Haedelt, Josefin
  • Journal of Magnetic Resonance, Vol. 183, Issue 2, p. 178-182
  • DOI: 10.1016/j.jmr.2006.08.007

High-pressure magic angle spinning nuclear magnetic resonance
journal, October 2011
  • Hoyt, David W.; Turcu, Romulus V. F.; Sears, Jesse A.
  • Journal of Magnetic Resonance, Vol. 212, Issue 2, p. 378-385
  • DOI: 10.1016/j.jmr.2011.07.019

Nuclear Induction
journal, February 1946
  • Bloch, F.; Hansen, W. W.; Packard, Martin
  • Physical Review, Vol. 69, Issue 3-4, p. 127-127
  • DOI: 10.1103/PhysRev.69.127

Resonance Absorption by Nuclear Magnetic Moments in a Solid
journal, January 1946
  • Purcell, E. M.; Torrey, H. C.; Pound, R. V.
  • Physical Review, Vol. 69, Issue 1-2, p. 37-38
  • DOI: 10.1103/PhysRev.69.37

Free Induction Decays of Rotating Solids
journal, April 1959

13C High-Pressure CPMAS NMR Characterization of the Molecular Motion of Polystyrene Plasticized by CO2 Gas
journal, October 1997
  • Miyoshi, Toshikazu; Takegoshi, K.; Terao, Takehiko
  • Macromolecules, Vol. 30, Issue 21, p. 6582-6585
  • DOI: 10.1021/ma961891r

Effects of Xe Gas on Segmental Motion in a Polymer Blend As Studied by 13C and 129Xe High-Pressure MAS NMR
journal, January 2002
  • Miyoshi, Toshikazu; Takegoshi, K.; Terao, Takehiko
  • Macromolecules, Vol. 35, Issue 1, p. 151-154
  • DOI: 10.1021/ma0115287

Chemistry in superacids. 12. Carbonic acid and its mono- and diprotonation: NMR, ab initio, and IGLO investigation
journal, March 1993
  • Rasul, Golam; Reddy, V. Prakash; Zdunek, Leszek Z.
  • Journal of the American Chemical Society, Vol. 115, Issue 6, p. 2236-2238
  • DOI: 10.1021/ja00059a020

Metal Carbonation of Forsterite in Supercritical CO2 and H2O Using Solid State 29Si, 13C NMR Spectroscopy
journal, February 2010
  • Kwak, Ja Hun; Hu, Jian Zhi; Hoyt, David W.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 9, p. 4126-4134
  • DOI: 10.1021/jp1001308

Microcoil High-Resolution Magic Angle Spinning NMR Spectroscop
June 2006
  • Janssen, Hans; Brinkmann, Andreas; van Eck, Ernst R. H.
  • Journal of the American Chemical Society, Vol. 128, Issue 27, p. 8722-8723
  • DOI: 10.1021/ja061350+

High-resolution, high-sensitivity NMR of nanolitre anisotropic samples by coil spinning
journal, June 2007
  • Sakellariou, D.; Goff, G. Le; Jacquinot, J.-F.
  • Nature, Vol. 447, Issue 7145, p. 694-697
  • DOI: 10.1038/nature05897

129Xe n.m.r. study of free volume and phase separation of the polystyrene/poly(vinyl methyl ether) blend
journal, October 1997

A new high pressure sapphire nuclear magnetic resonance cell
journal, January 1996
  • Bai, Shi; Taylor, Craig M.; Mayne, Charles L.
  • Review of Scientific Instruments, Vol. 67, Issue 1, p. 240-243
  • DOI: 10.1063/1.1146578