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Title: Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.
Inventors:
;
Issue Date:
OSTI Identifier:
1129065
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM) LANL
Patent Number(s):
8,685,364
Application Number:
13/850,959
Contract Number:
AC52-06NA25396
Resource Relation:
Patent File Date: 2013 Mar 26
Research Org:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Works referenced in this record:

Ammonia Borane Hydrogen Release in Ionic Liquids
journal, October 2009
  • Himmelberger, Daniel W.; Alden, Laif R.; Bluhm, Martin E.
  • Inorganic Chemistry, Vol. 48, Issue 20, p. 9883-9889
  • DOI: 10.1021/ic901560h

Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
journal, October 2008
  • Dietrich, Brandon L.; Goldberg, Karen I.; Heinekey, D. Michael
  • Inorganic Chemistry, Vol. 47, Issue 19, p. 8583-8585
  • DOI: 10.1021/ic801161g

Efficient synthesis and NMR data of N- or B-substituted borazines
journal, January 2000

B–N compounds for chemical hydrogenstorage
journal, January 2009
  • Hamilton, Charles W.; Baker, R. Tom; Staubitz, Anne
  • Chem. Soc. Rev., Vol. 38, Issue 1, p. 279-293
  • DOI: 10.1039/B800312M

Iridium-Catalyzed Dehydrocoupling of Primary Amine-Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron-Nitrogen Analogues of Polyolefins
journal, August 2008
  • Staubitz, Anne; Presa Soto, Alejandro; Manners, Ian
  • Angewandte Chemie, Vol. 120, Issue 33, p. 6308-6311
  • DOI: 10.1002/ange.200801197